Dye-sensitized solar cells (DSSCs) suffer from efficiency limitations due to interfacial charge recombination at the TiO₂/dye/electrolyte interface. In this study, aminopropyltrimethoxysilane (APS) was introduced onto nanoporous TiO₂ photoelectrodes via a dip-coating process with controlled coating times to investigate the effect of silanization time on interfacial charge transport behavior. Unlike concentration-driven structural modification, this work focuses on the evolution of the APS-modified interface governed by reaction time. The DSSC with 30 min APS treatment exhibited the highest power conversion efficiency of 5.34%, representing a 19% enhancement compared to the untreated device (4.49%), mainly due to increased short-circuit current density and open-circuit voltage. However, prolonged coating times (2 h and 24 h) resulted in a significant decrease in photocurrent density, leading to reduced device performance despite partial improvement in recombination resistance. These results are attributed to the time-dependent evolution of the APS interfacial layer. At moderate coating time, APS provides effective surface functionalization, enhancing dye adsorption and suppressing interfacial recombination. In contrast, prolonged coating is expected to induce increased surface coverage and silane condensation, which can hinder electron injection and increase charge transport resistance. Therefore, the photovoltaic performance is governed by a trade-off between recombination suppression and charge injection efficiency, controlled by the silanization time. This study highlights the critical role of interfacial reaction kinetics in determining charge transport behavior and provides an effective strategy for optimizing DSSC performance through time-dependent interface engineering.
Dye adsorption is one of the most time-consuming processes in the fabrication of dye-sensitized solar cells (DSSCs), typically requiring approximately 24 h at room temperature. In this study, the effect of adsorption temperature and time on photovoltaic performance of DSSCs was investigated in order to reduce processing time and improve device productivity. Nanoporous TiO2 photoelectrodes were immersed in N719 dye solution at 60°C for 3 h, 10 h, 17 h, and 24 h, and their performance was compared with that of cells sensitized at room temperature for 24 h. Photovoltaic characterization under AM 1.5 illumination showed that DSSCs sensitized at 60°C exhibited improved performance compared to those sensitized at room temperature. The device sensitized at 60°C for 3 h showed comparable or higher conversion efficiency than the reference cell sensitized for 24 h at room temperature. The improvement in device performance is attributed to enhanced dye adsorption kinetics resulting from increased reaction rate between the carboxyl groups of N719 dye molecules and hydroxyl groups on the TiO2 surface. Electrochemical impedance spectroscopy analysis revealed reduced recombination resistance at the TiO2/dye/electrolyte interface for cells sensitized at elevated temperature. UV–Vis absorption analysis confirmed increased dye loading on the TiO2 surface for the 60°C condition. These results demonstrate that elevated temperature dye adsorption significantly reduces processing time while maintaining photovoltaic performance, providing an effective strategy for improving manufacturing efficiency of DSSCs.
The direct utilization of steelmaking by-product gases in solid oxide fuel cells (SOFCs) offers a promising pathway to improve energy efficiency and reduce carbon emissions in the steel industry. In this study, a Sr-deficient and Ni-doped double perovskite oxide, Sr1.95Fe1.35Ni0.15Mo0.5O6-δ (SFNM), was investigated as an anode material for direct Linz-Donawitz converter gas (LDG)-fueled SOFCs. A single-phase double perovskite structure was successfully obtained after calcination at 1,200°C for 12 h, while exsolved metallic Ni nanoparticles were generated on the SFNM surface after reduction at 800°C. Electrochemical performance was evaluated using H2, simulated-LDG, and CO/CO2 (85:15) fuels at 800°C. The maximum power densities achieved were 1.23, 0.70, and 0.40 W cm-2 for H2, simulated-LDG, and CO/CO2 fuels, respectively. Although CO-containing fuels exhibited lower opencircuit voltages and power outputs than H2, the SFNM anode maintained stable operation and appreciable performance under direct simulated-LDG utilization. Impedance analysis revealed that the increased polarization resistance in simulated-LDG and CO/CO2 atmospheres was mainly associated with fuel adsorption/desorption and gas diffusion, while interfacial charge-transfer resistance remained relatively small. The superior performance obtained with simulated-LDG compared to the CO/CO2 mixture was attributed to the presence of a small amount of H2, which facilitated anode reaction kinetics. These results demonstrate that SFNM is a promising mixed ionic-electronic conductor anode for the direct electrochemical conversion of CO-rich steelmaking by-product gases into electricity.
The development of a large-area solution process for CuO nanowires, which are promising p-type thin film transistors (TFT) channel materials, is required. To overcome the limitations of the existing high-vacuum and high-cost deposition process, a large-area Cu nanowire network was formed on the substrate using the Mayer rod coating method, and a CuO channel was implemented by subsequent thermal annealing. Consequently, p-type TFT with an on/off current ratio of 1.4×104 and a field-effect mobility µFE≈10-4 cm2/(V⋅s). was fabricated and optimized. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses showed that the sample annealed at 200°C exhibited an incomplete oxidation state with a mixed Cu/Cu2O phase and a high fraction of M-OH species (58.78%), resulting in a low on/off current ratio (≈1.2). In contrast, annealing at 450°C leads to a CuOdominant phase, where the fraction of lattice oxygen(O1) increases to 31.11% and the oxygen vacancy (VO) component increases to 7.15%, indicating a significant improvement in hole concentration and charge transport. These phase transitions and surface chemical changes are identified as the key mechanisms for the enhanced TFT switching characteristics. The low-cost, large-area Mayer rodbased solution process proposed in this study provides a basic process platform for p-type TFTs applicable to flexible wearables and display technologies and suggests the possibility of commercialization through additional optimization of bias stability in the future.
The characteristics of each address discharge were investigated when the voltages of the scan and common electrodes were lowered simultaneously during an address period under the same address voltage conditions in an AC plasma display panel. It was confirmed that the delay time of address discharge shortened as the voltage decreased. However, the background light increased because the low scanning voltage generated more discharge between the electrodes of the upper and lower plates in the reset period. To lower the background light, a positive voltage was applied to the address electrode of the lower panel during the period when the rising ramp wave was applied, and a floating voltage was applied to the address electrode during the period when the falling ramp wave was applied during the reset period. As a result, the background light could be lowered by about 30%.
Beom Jin Kim, Pil Hong Jeong, Jae Min Lee, Dong Hwan Won, Jeong Ho Lee, Heon Min Lee, Ku Yun Jeong, Keon Park, Kawan Anil, Soon Jae Yu, Yeon Sik Chae, Sung Bae Park
J Electr Electron Mater 2025;38(3):272-277. Published online May 1, 2025
SMD-type 660 nm wavelength semiconductor laser diode device is fabricated using silicon resin molding technology and fabricated a BT resin printed circuit board. BT resin electrode structure printed circuit boards with soldering electrode pads and through holes for heat dissipation were fabricated. The SMD process is an injection molding technique in which the chip is molded from silicon material and then cut by a dicing process to complete the beam emission surface. The fabricated SMD-type semiconductor laser diode exhibits a good near-field beam pattern with no scattering/dispersion caused by the printed circuit board or silicon molding in the emitted laser beam, or reflections around the chip. It was also confirmed that the heat generated at 20 mA operation has good heat dissipation characteristics through the through-hole heat dissipation structure.
The transparent electrode characteristics of the SnO₂/AgNi/SnO₂ (OMO) multilayer structures prepared by sputtering were investigated according to the annealing temperature. Ni-doped Ag of various compositions was selected as the metal layer and heat treatment was performed at 100~300℃ to evaluate the thermal stability of the metals. The manufactured OMO multilayer structures were heat treated for 6 hours at 400~600℃ in an N₂ atmosphere. The structural, electrical, and optical properties of the OMO structures before and after annealing were evaluated and analyzed using a UV-VIS spectrophotometer, 4-point probe, XPS, FE-SEM, etc. OMO with Ni-doped Ag shows improved performance due to the reduction of structural defects of Ag during annealing, but OMO structure with pure Ag shows degradation characteristics due to Ag diffusion into the oxide layer during high-temperature annealing. The figure of merit (FOM) of SnO₂/Ag/SnO₂ was highest at room temperature and gradually decreased as the heat treatment temperature increased. On the other hand, the FOM value of SnO₂/AgNi/SnO₂ mostly showed its maximum value at high temperature(~550℃). In particular, the FOM value of SnO₂/Ag-Ni (3.2 at%)/SnO₂ was estimated to be approximately 2.38×10-2 Ω-1. Compared to transparent electrodes made of other similar materials, the FOM value of the SnO₂/Ag-Ni (3.2 at%)/SnO₂ multilayer structure is competitive and is expected to be used as an alternative transparent conductive electrode in various devices.
In this paper, the electrical properties of liquid insulating oil were analyzed by changing the ambient temperature change at 10℃ in-tervals from 0℃ to 30℃ through an insulation breakdown experiment in order to analyze the insulation performance of liquid in-sulating oil that varies according to temperature changes. As a result, it was confirmed through experiments that the lower the am-bient temperature, the higher the insulation breakdown voltage, depending on both the electrode shape and the electrode interval, and it was determined that the lower the ambient temperature, the higher the insulation performance of the liquid insulating oil.
Ni-rich cathode materials have been developed as the most promising candidates for next-generation cathode materials for lithium-ion batteries because of their high capacity and energy density. In particular, the electrochemical performance of lithium-ion batteries could be enhanced by increasing the contents of nickel ion. However, there are still limitations, such as low structural stability, cation mixing, low capacity retention and poor rate capability. Herein, we have successfully developed the nanorod-type Ni-rich cathode materials by using co-precipitation method. Particularly, the nanorod-type primary particles of LiNi0.7Co0.15Mn0.15O2 could facilitate the electron transfer because of their longitudinal morphology. Moreover, there were holes at the center of secondary particles, resulting in high permeability of the electrolyte. Lithium-ion batteries using the prepared nanorod-type LiNi0.7Co0.15Mn0.15O2 achieved highly improved electrochemical performance with a superior rate capability during battery cycling.
This paper is a study on the optimal microdroplet generation conditions in indirect charging electrostatic spraying. Unlike the direct charging method, which applies power to the nozzle, the indirect charging method applies power to the discharge electrode between the nozzle and the collection electrode. Therefore, an electrically simplified system can be obtained by minimizing the insulation part a stable spray pattern can be obtained with a wide spray angle, and a stable spray pattern can be obtained with a wide spray angle. To conduct the study, an indirect charging type electrostatic spray visualization system was constructed and the static characteristics of the microdroplets were analyzed through image processing of the spray shape of the microdroplets. The total number of microdroplets and the number of microdroplets per power consumption are confirmed according to the changes in the distance between the discharge electrode and the collection electrode, the flow rate, and the applied voltage, which affect the generation of microdroplets, and using this, the optimal generation conditions are derived and the corresponding microdroplet size distribution was analyzed. As a result of the experiment, it was confirmed that the optimal generation condition was at a flow rate of 15 to 20 mL/min and a voltage of -22.5 to -25 kV in terms of the number of microdroplets, and at a flow rate of 15 to 20 mL/min and a voltage of -20 kV in terms of energy consumption efficiency.
This paper is an experimental study on the optimal operating conditions of direct charging type electrospray for particulate matter collection. To perform the research, a direct charging type electrospray visualization system was configured to photograph the spray shape of microdroplets, and experiments were performed with varying electrode distance, flow rate, and applied voltage, which are the main factors affecting the particulate matter collection efficacy. Through image processing, the total number of microdroplets according to each condition was analyzed, and the number of microdroplets with a diameter of 1.5 mm or less was confirmed. In addition, by calculating the number of microdroplets per power consumption according to the applied voltage, the optimal operating conditions were derived in terms of energy consumption efficacy, and the microdroplet size distribution was analyzed under the optimal operating conditions. As a result of the experiment, it was confirmed that the optimal operating condition was at a flow rate of 10 mL/min and a voltage of -20 kV in case of 5 mm electrode distance, and at a flow rate of 15 mL/min and a voltage of -30 kV in case of 100 mm electrode distance.
Flash lamp annealing (FLA) of metal nanoparticle (NP) ink has provided powerful strategies to fabricate highperformance electrodes on a flexible substrate because of its rapid processing capability (in milliseconds), low-temperature process, and compatibility with to roll-to-roll process. However, metal NPs [e.g., gold (Au), silver (Ag), copper (Cu), etc.] have limitations such as difficulty in synthesizing fine metal NPs (diameter less than 10 nm), high price, and degradation during ink storage and FLA processing. In this regard, organometallic ink has been proposed as a material that can replace metal NPs due to their low-cost (usually 1/100 times cheaper than metal nano inks), low-temperature processability, and high material stability. Despite these advantages, the fabrication of flexible electrodes through FLA treatment of organometallic compounds has not been extensively researched. In this paper, we experimentally guide how to determine the optimal conditions for forming electrodes on flexible substrates by considering material parameters, and flashlight processing parameters (energy density, pulse duration, etc) to minimize the difficulties that may arise during the FLA of organometallic ink.
Stretchable piezoelectric energy harvester (S-PEHs) based on composite materials are considered one of the potential candidates for realizing wearable self-powered devices for smart clothing and electronic skin. However, low energy conversion performance and expensive stretchable electrodes are major bottlenecks hindering the development and application of S-PEHs. Here, we fabricated the S-PEH by adopting the piezoelectric composites with enhanced stress transfer properties and kirigamipatterned textile electrodes. The optimum contents of piezoelectric BaTiO3 nanoparticles inside the carbon nanotube/ecoflex composite were selected as 30 wt% considering the trade-off between stretchability and energy harvesting performance of the device. The final S-PEH shows an output voltage and mechanical stability of ~5 V and ~3,000 cycles under repeated 150% of tensile strain, respectively. This work presents a cost-effective and scalable way to fabricate stretchable piezoelectric devices for self-powered wearable electronic systems.
Multilayer Ceramic Capacitors (MLCCs) are essential passive components in the electronics industry, known for their high capacitance due to the multilayer structure comprising inner electrodes and dielectric layers. Nickel electrodes are commonly used in MLCCs as the inner electrodes, and to prevent oxidation during the co-firing of the dielectric layers with nickel electrodes, reducing atmosphere is required. However, reducing atmosphere sintering can also induce a reduction of the dielectric, necessitating precise control of oxygen partial pressure. To explore the possibility of using oxide electrodes that do not require reducing atmosphere sintering, we analyze the electrical properties of nickel oxide (NiO) as a potential candidate. As a preliminary study on its use as an alternative inner electrode, the correlation between microstructure and electrical properties of bulk NiO under different sintering conditions was investigated to gain insights into the conduction mechanisms of the material.
In this paper, in order to analyze high electrical insulation and cooling performance using mineral oil, the liquid insulating oil was changed in electrode shape and distance between electrodes to compare and analyze electrical characteristics according to equal electric field, quasi-equivalent electric field, and unequal electric field. As a result, the breakdown voltages were 36,875 V and 36,875 V in the form of sphere-sphere and plate-plate electrodes with equal electric fields. The breakdown voltage was 31,475 V in the sphere-plate electrode type, which is a quasi-equilibrium field, and the breakdown voltage was 28,592 V, 27,050 V, and 22,750 V in the needle-needle, sphere-needle, and needle-plate electrode types, which are unequal fields. Through this, it is possible to know the difference in breakdown voltage according to the type of electric field. The more equal the field, the higher the breakdown voltage, and the more unequal field, the lower the breakdown voltage. The difference in insulation breakdown voltage could be seen depending on the type of electric field, the insulation breakdown voltage was higher for the more equal electric field, and the insulation breakdown voltage was lower for the more unequal electric field. Also, it was confirmed that the closer the distance between the electrodes, the higher the insulation breakdown voltage, the higher the insulation breakdown current, and the insulation breakdown voltage and the insulation breakdown current were proportional.
Numerical simulation is a good way to predict the conversion efficiency of solar cells without a direct experimentation and to achieve low cost and high efficiency through optimizing each step of solar cell fabrication. TOPCon industrial solar cells fabricated with n-type silicon wafers on a larger area have achieved a higher efficiency than p-type TOPCon solar cells. Electrical and optical losses of the front surface are the main factors limiting the efficiency of the solar cell. In this work, an optimization of boron-doped emitter surface and front electrodes through numerical simulation using “Griddler” is reported. Through the analysis of the results of simulation, it was confirmed that the emitter sheet resistance of 150 Ω/sq along the front electrodes having a finger width of 20 μm, and the number of finger lines ~130 for silicon wafer of M6 size is an optimized technology for the front emitter surface of the n-type TOPCon solar cells that can be developed.
Laser-induced plasmonic sintering of metal nanoparticles (NPs) is a promising technology to fabricate flexible conducting electrodes, since it provides instantaneous, simple, and scalable manufacturing strategies without requiring costly facilities and complex processes. However, the metal NPs are quite expensive because complicated synthesis procedures are needed to achieve long-term reliability with regard to chemical deterioration and NP aggregation. Herein, we report laser-induced Ag NP self-generation and sequential sintering process based on low-cost Ag organometallic material for demonstrating highquality microelectrodes. Upon the irradiation of laser with 532 nm wavelength, pre-baked Ag organometallic film coated on a transparent polyimide substrate was transformed into a high-performance Ag conductor (resistivity of 2.2 × 10-4 Ω·cm). To verify the practical usefulness of the technology, we successfully demonstrated a wearable transparent heater by using Ag-mesh transparent electrodes, which exhibited a high transmittance of 80% and low sheet resistance of 7 Ω/square.
Electrohydrodynamic jet (e-jet) printing, a type of direct contactless microfabrication technology, is a versatile fabrication process that enables a wide range of micro/nanopattern arrays by applying a strong electric field between the nozzle and the substrate. In general, the morphology and the thickness of polymers/quantum dot micropatterns show a systematic dependence on the diameter of the nozzle and the ink composition with a fully automated printing machine. The purpose of this report is to provide typical examples of e-jet printed micropatterns of polymers/quantum dots to explain the effect of each process variable on the result of experiments. Here, we demonstrate several operating conditions that allow high-resolution printing of layers of polymers/quantum dots with a precise control over thickness and submicron lateral resolution.
Field-effect transistors (FETs) are the key elements of conventional electronics; hence, have drawn a lot of research and commercial interests. In recent years, metal halide perovskite materials have achieved a remarkable efficiency of 29.15% in the field of photovoltaics, and have drawn the scientific community’s attention to promote their use in the field of optoelectronics, such as FETs and phototransistors. The MAPbI3 (methylammonium lead iodide) perovskite TFT has achieved a record hole mobility of 21.41 ㎠/V-s in the year 2020. In this review, we will briefly discuss the physical structure of MAPbI3 perovskite and the essential factors that stimulate these devices, together with the role of defects, the ion migration concept, and the implication of both dielectric and electrode materials on the device’s performance.
In this study, composite transparent electrodes were fabricated either from a conductive polymer poly(3,4- ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) or silver nanowire (AgNW). Three transparent electrodes such as PEDOT:PSS, PEDOT:PSS and AgNW mixture, and AgNW were fabricated. As for a transparent electrode, measured sheet resistance values were 89.6, 60.6 and 28.6 Ω/sq, and the transmittance values were 80.2, 82.0 and 83.8% while surface roughness (Rq) values were 4.1, 8.1, 20.4 nm for PEDOT:PSS, PEDOT:PSS and AgNW mixture, and AgNW, respectively. To verify the overall performance of these composite electrodes, we applied these electrodes to the top electrode of the solution-processed organic solar cells (OSCs). PEDOT:PSS provided the best performance with a fill factor (FF) of 51.2% and a photoconversion efficiency (PCE) of 2.2%, while traditional metal top electrode OSC provided FF of 60.5% and PCE of 3.1%.
Hazardous and noxious substance (HNS) detection sensors were fabricated using multi-walled carbon nanotubes (MWCNTs) and various binder materials for ion batteries. To obtain uniformly printed films, the printing precision according to the substrate cleaning method was monitored, and the printing paste mixing ratio was investigated. Binders were prepared using styrene butadiene rubber + carboxymethyl cellulose (SBR+CMC), polyvinylidene fluoride + n-methyl-2-pyrrolidene (PVDF+NMP), and mixed with MWCNTs. The surface morphology of the printed films was examined using an optical microscope and a scanning electron microscope, and their electrical properties are investigated using an I-V sourcemeter. Finally, sensing properties of MWCNT printed films were measured according to changes in the concentration of the chemical under the various applied voltages. In conclusion, the MWCNT printed films made of (SBR+CMC) were found to be feasible for application to the detection of hazardous and noxious chemicals spilled in seawater.
In this study, the sterilization property of E. coli was established using a plasma generator with a flexible electrode structure. The bacterial suspension was prepared based on the McFarland standard 0.50 (1.5×108 CFU/mL) concentration and a specific amount was inoculated on the plate medium. After the plasma was discharged 3 cm away from the plasma generator in the range of 30s to 5 min and the results compared to the control group, the observed colonies that were formed decreased significantly as the plasma discharge time increased.
In the Airport Railroad, the Yeongjong Bridge has a length of 4,420 m and connects Yeongjong Island with the mainland of Incheon City. The bridge is a two-level structure, consisting of a six-lane road at the upper level and a combination of a road and railroad at the lower level. The environmental conditions for the electric railway come mainly from the salt injury area and a heavy industry zone, and the maintenance cycles are determined differently depending on these conditions. This study analyzed the deterioration characteristics of long rod insulators produced with a movable ceramic bracket and polymer materials in the Yeongjong Bridge section of the Airport Railway operating in the salt injury area according to the material characteristics. Comparison of the corona measurements when the insulators were cleaned at the same time showed that the polymer insulator had a higher insulation performance than the ceramic insulator.
A shingled PV module is manufactured by dividing and bonding. In this method, the solar cell is divided by lasers and bonded using electrically conductive adhesives (ECAs). Consequently, the manufacturing cost increases because a process step is added. Therefore, we aim to reduce the production cost by reducing the amount of Ag paste used in the solar cell front. Various electrode structures were designed and simulated. The number of fingers was optimized by designing thinner fingers, and the number of fingers with the maximum power conversion efficiency was confirmed. The simulation confirmed the maximum efficiency in the 4-divided electrode pattern. The amount of Ag paste used for each electrode pattern was calculated and analyzed. The number of fingers was optimized by decreasing the width of the finger; this will not only reduce the amount of Ag paste required but also the increase the efficiency.
A multiple-electrode-type electronic paper film can implement a single color and control the transparency, as it has multiple electrodes in one cell. Therefore, it can be used as a transparent display. In this paper, we explain the structure and driving method of a transparent electronic paper display, and then propose a control method of transmittance. Subsequently, we verify the theory by measuring the transmittance via experiment. Thus, by changing the manner of applying the voltage to three lower electrodes and one upper electrode, transmittance in eight cases could be realized. It was confirmed that the transmittance derived from the experiment could be controlled from a minimum of 6.75% to a maximum of 71.18%.
Recently, the application field of solar panels is increasing. Accordingly, the demand for flexible devices is also steadily increasing. It is therefore necessary to develop TiO2 paste for low-temperature annealing for flexible DSSC fabrication. In this study, the TiO2 paste for low-temperature annealing with varying molar ratio of titanium isopropoxide (TTIP) was prepared, and DSSC was fabricated and its characteristics were compared. As a result, there was no deformation of the particles on the surface in the SEM data. However, the highest open circuit voltage, short circuit current, and fill factor were measured in the DSSC unit cell prepared by adding 0.5 mol of TTIP to the TiO2 paste, and the highest efficiency was 4.148%.
In this study, oxide/metal/oxide-type transparent electrodes based on Al and ZnO were investigated. Thin films of these materials were sputter-deposited at room temperature. To evaluate the thickness dependence of the oxide layers, the top and bottom ZnO layers were varied in the range of 5~80 nm and 2.5~20 nm, respectively. When the thicknesses of the top and bottom ZnO layers were fixed at 30 nm and 2.5 nm, a maximum transmitance of 66% and sheet resistance of 16.5 Ω/□ were achieved, which is significantly improved compared with the Al layer without top and bottom ZnO layers showing a maximum transmitance of 44.3% and sheet resistance of 44 Ω/□.
A multielectrode electronic paper film capable of expressing a single-color image was fabricated by injecting color electronic ink into an electronic paper panel; on the basis of its reflective or transparent properties, it is possible to control the expression of six single-color images and their transmittance. In this study, a single-color image was represented by driving a multielectrode electronic paper film; color coordinates were measured. The six capable single colors were yellowish pink (0.444, 0.354), white (0.355, 0.352), black (0.241, 0.241), orange (0.514, 0.360), reddish orange (0.606, 0.338), and reddish purple (0.469, 0.145). Color particles used in this paper were black and white, by which six colors are accomplished, but more single-color images can be combined by using cyan, magenta, and yellow particles.
The shingled photovoltaic module can be produced by joining divided solar cells into a string of busbarless structure and arranging them in series and parallel to produce a module, in order to produce a high output per unit area. This paper reports a study to optimize solar cell electrode structure for shingled photovoltaic module fabrication. The characteristics of each electrode structure were analyzed according to the simulation program as follow: 80.62% fill factor in the six-junction solar cell electrode structure and 19.23% efficiency in the five-junction electrode structure. Therefore, the split electrode structure optimized for high-density and high-output shingled module fabrication is the five-junction solar cell electrode structure.
The rod-shaped Ni0.5Zn0.5Fe2O4 particles were synthesized via a topotactic reaction, in which goethite (α-FeOOH) particles are the main constituents. The phases, microstructures and magnetic properties of these particles were studied using XRD, FE-SEM and VSM. The precursor solution consisted of NiSO4·xH2O, ZnSO4·xH2O, goethite and D.I. water werereacted at four different temperatures (50, 70, 90, 100℃) to generate four differently precipitated particles respectively. During the co-precipitation reaction, the pH of the solution was maintained at 8.0 using NaOH. The particles coprecipitated and calcined at a temperature of 700℃, exhibited a rod-shape similar to its original goethite, which means that the shape of Ni-Zn ferrite particles can be topotactically controlled by the goethite. The particles synthesized at 70 and 90℃ have a saturation magnetization of 29 and 35 emu/g respectively; representing better values than the ones synthesized at the 50 and 100℃, in which some second phases such as Fe2O3 were observed.