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"Alloy"

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"Alloy"

Luminescence Properties of Cd-Free InZnP/ZnSe/ZnS Core/Shell Quantum Dots
Young-ki Lee, Min-Sang Lee, Jeong-mi Lee, Dae-Hee Won, Jong-man Kim
J Electr Electron Mater 2021;34(6):454-460.   Published online November 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.6.9
In this work, we synthesized alloy-core InZnP quantum dots, which are more efficient than single-core InP quantum dots, using a solution process method. The effect of synthesis conditions of alloy core on optical properties was investigated. We also investigated the conditions that make up the gradient shell to minimize defects caused by lattice mismatch between the InZnP core and ZnS is 7.7%. The stable synthesis temperature of the InZnP alloy core was 200℃. Quantum dots consisting of three layered ZnSe gradient shell and single layered ZnS exhibited the best optical property. The properties of quantum dots synthesized in 100 ml and in 2,000 ml flasks were almost equal.
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We fabricated plate typed shunt resistors composed of carbon nanotube (CNT) and metal alloy for measuring DC current. CNT plates were prepared from dispersed CNT/Urethane solution by squeezing method. Cu/Ni alloys were prepared from composition-designed alloy wires for adjusting the temperature coefficient of resistance (TCR) by pressing them. As well, we fabricated a hybrid resistor by squeezing the CNT/Urethane solution on the metal alloy plate directly. In order to confirm the composition ratio of the Cu/Ni alloy, we used an energy-dispersed X-ray spectroscopy (EDX). Cross-section and surface morphology were analyzed by using a scanning electron microscopy (SEM). Finally, we measured the initial resistance of 2.35 Ω at 25℃ for the CNT paper resistor, 7.56 mΩ for the alloy resistor, and 7.38 mΩ for the hybrid resistor. The TCR was also measured to be -778.72 ppm/℃ at the temperature range between 25℃ to 125℃ for the CNT paper resistor, 824.06 ppm/℃ for the alloy resistor, and 17.61 ppm/℃ for the hybrid resistor. Some of the hybrid resistors showed a near-zero TCR of 1.38, -2.77, 2.66, and 5.49 ppm/℃, which might be the world best-value ever reported. Consequently, we could expect an error-free measurement of the DC current using this resistor.
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Evaluation of Breaking Performance of New Contact Material for the Vacuum Interrupter
Young-kwang Cha, Il-hoi Lee, Heung-jin Ju, Tae-yong Shin, Kyong-tae Park
J Electr Electron Mater 2021;34(1):50-55.   Published online January 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.1.9
Copper-chromium alloys have been used as contact materials of vacuum interrupters in circuit breakers, but new materials with highly stable performance are required to break the high voltage and high current barrier due to the recent increase in breaking capacity. In this paper, a new contact material was fabricated from a ternary alloy instead of existing Cu-Cr alloys. Its breaking performance and endurance were verified from a synthetic test and compared with that of various contact materials. The test results verified that the breaking performance of the new contact material was excellent.
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The Formation of Anodic Oxide Film by Anodizing Voltage and Time of 6061 Aluminum Alloy
Youngju Park, Chanyoung Jeong
J Electr Electron Mater 2021;34(1):68-72.   Published online January 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.1.12
Aluminum is a lightweight metal and has excellent properties with regard to conductivity, workability, and strength. It has been used in various industries owing to its economic benefits. To improve upon the mechanical properties and processability by adding various alloying elements to aluminum, improving the corrosion resistance and heat resistance by electrochemically forming a porous anodic film having a thickness and hardness on the surface of the aluminum alloy is crucial. In this study, the aluminum 6061 alloy was controlled by an anodization process in a 0.3M oxalic acid electrolyte at room temperature to investigate the oxide film parameters such as porosity and thickness depending on the modulating applied voltage and time. The anodizing experiment was performed by increasing the time from 1 h to 9 h at 2-h intervals at applied voltages of 50 V and 60 V.
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Electrical Characteristics of and Temperature Distribution in Chalcogenide Phase Change Memory Devices Having a Self-Aligned Structure
Hye Ryeon Yoon, Young Sam Park, Seung-yun Lee
J Electr Electron Mater 2019;32(6):448-453.   Published online November 1, 2019
This work reports the electrical characteristics of and temperature distribution in chalcogenide phase change memory (PCM) devices that have a self-aligned structure. GST (Ge-Sb-Te) chalcogenide alloy films were formed in a self-aligned manner by interdiffusion between sputter-deposited Ge and Sb2Te3 films during thermal annealing. A transmission electron microscopy-energy dispersive X-ray spectroscopy (TEM-EDS) analysis demonstrated that the local composition of the GST alloy differed significantly and that a Ge2Sb2Te5 intermediate layer was formed near the Ge/Sb2Te3 interface. The programming current and threshold switching voltage of the PCM device were much smaller than those of a control device; this implies that a phase transition occurred only in the Ge2Sb2Te5 intermediate layer and not in the entire thickness of the GST alloy. It was confirmed by computer simulation, that the localized phase transition and heat loss suppression of the GST alloy promoted a temperature rise in the PCM device.
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Bandgap Control of (AlxGa1-x)2O3 Epilayers by Controlling Aqueous Precursor Mixing Ratio in Mist Chemical Vapor Deposition System
Kyoung-ho Kim, Yun-ji Shin, Seong-min Jeong, Si-young Bae
J Electr Electron Mater 2019;32(6):528-533.   Published online November 1, 2019
We investigated the growth of AlxGa1-x)2O3 thin films on c-plane sapphire substrates that were grown by mist chemical vapor deposition (mist CVD). The precursor solution was prepared by mixing and dissolving source materials such as gallium acetylacetonate and aluminum acetylacetonate in deionized water. The [Al]/[Ga] mixing ratio (MR) of the precursor solution was adjusted in the range of 0~4.0. The Al contents of (AlxGa1-x)2O3 thin films were increased from 8 to 13% with the increase of the MR of Al. As a result, the optical bandgap of the grown thin films changed from 5.18 to 5.38 eV. Therefore, it was determined that the optical bandgap of grown (AlxGa1-x)2O3 thin films could be effectively engineered by controlling Al content.
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Design of a Miniature Fuse with High Breaking Capacity and Load Life Using a Ceramic Powder of Extinguishing an Electric Arc
Chang Yong Kang, Sang Jun Jin, Ye Ji Lee, Jae Seo Youn, Seong Yeo Noh
J Electr Electron Mater 2019;32(4):327-332.   Published online July 1, 2019
Recently, inverter control systems have attracted immense attention to increase the energy efficiency. However, such systems use repeated on/off high currents for linear operation control, instead of the prevalent step variable current control method. Hence, there arise concerns of personal and property damage, especially due to the durability, explosive characteristics, and operating speed of the fuse, which is responsible for safety and is one of the internal components using current control. Therefore, in this paper, we propose an IEC60127-4 SMD sub-miniature fuse, consisting of Ag-Cu alloys and ceramic powder for arc soothing. The IEC60127-4 SMD sub-miniature fuse has high durability and cut-off capacity, and operates safely in dangerous circumstances caused by the inverter control system.
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Crystallization Behavior and Electrochemical Properties of Si50Al30Fe20 Amorphous Alloys as Anode for Lithium Secondary Batteries Prepared by Rapidly Solidification Process
Deok-ho Seo, Hyang-yeon Kim, Sung-soo Kim
J Electr Electron Mater 2019;32(4):341-348.   Published online July 1, 2019
This paper reports the microstructure and electrochemical properties of Si-Al-Fe ternary amorphous alloys prepared by rapid solidification as an anode for lithium secondary batteries. The microstructure was analyzed using XRD and HR-TEM with EDS mapping. In accordance with DSC analysis, annealing was performed to crystallize the active nano-Si in the amorphous alloy. Thus, nano-Si forms (~80 nm) embedded in the matrix alloy, such as Fe2Al3Si3, FeSi2, and Fe0.42Si2.67, were successfully synthesized. The electrode based on the Si-Al-Fe ternary alloy delivered an initial discharge capacity of approximately 700 mAh g-1, and exhibited a high Coulombic efficiency of 99.0~99.6% from the 2nd to 70th cycles.
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Electrical Properties of Plate Typed Shunt Resistors with Low TCR Property
Youngtaek Lim, Eun-min Kim, Sang-won Lee, Jeong-rae Ahn, Sunwoo Lee
J Electr Electron Mater 2019;32(3):219-222.   Published online May 1, 2019
In this study, we fabricated plate-type shunt resistors with thermal stability by parallelly connecting metal alloy plates with positive temperature coefficient of resistance (TCR) and carbon nanotube (CNT) plates with negative TCR. The metal alloy plates, which were prepared by alloying Cu and Mn with a composition of 91 wt% of Cu and 9 wt% of Mn, showed around 800 ppm/℃ of TCR, and the CNT plates prepared from the CNT solution by using the vacuum filtration method showed around -800 ppm/℃ of TCR. The shunt resistor that was fabricated by stacking metal alloy plates and CNT plates in this work showed about 46.93 ppm/℃ of TCR. Therefore, we conclude that a shunt resistor with low TCR can be realized by simply adjusting the TCR of the metal alloy only, because the TCR of the CNT plate has an identical value.
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A Study on the Electrical and Optical Properties of SnO2/Cu(Ni)/SnO2 Multi-Layer Structures Transparent Electrode According to Annealing Temperature
Ji-won Jeong, Heon Kong, Hyun-yong Lee
J Electr Electron Mater 2019;32(2):134-140.   Published online March 1, 2019
Oxide (SnO2)/metal alloy (Cu(Ni))/oxide (SnO2) multilayer films were fabricated using the magnetron sputtering technique. The oxide and metal alloy were SnO2 and Ni-doped Cu, respectively. The structural, optical, and electrical properties of the multilayer films were investigated using X-ray diffraction (XRD), ultraviolet-visible (UV-vis) spectrophotometry, and 4-point probe measurements, respectively. The properties of the SnO2/Cu(Ni)/SnO2 multilayer films were dependent on the thickness and Ni doping of the mid-layer film. Since Ni atoms inhibit the diffusion and aggregation of Cu atoms, the grain growth of Cu is delayed upon Ni addition. For 250℃, the Haccke’s figure of merit (FOM) of the SnO2 (30 nm)/Cu(Ni) (8 nm)/SnO2 (30 nm) multilayer film was evaluated to be 0.17×10-3 Ω-1.
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Design of Low-Melting Metal Fuse Elements of Current Sensing Type Protection Device for Large Capacity Secondary Battery Protection System
Eun Min Kim, Chang Yong Kang
J Electr Electron Mater 2018;31(6):427-432.   Published online September 1, 2018
High-capacity secondary batteries can cause explosion hazards owing to microcurrent variations or current surges that occur in short circuits. Consequently, complete safety cannot be achieved with general protection that is limited to a mere current fuse. Hence, in the case of secondary batteries, it is necessary for the protector to limit the inrush current in a short circuit, and to detect the current during microcurrent variations. To serve this purpose, a fuse can be employed for the secondary battery protection circuit with current detection. This study aims at designing a protection device that can stably operate in the hazardous circumstances associated with high-capacity secondary batteries. To achieve the said
objective
, a detecting fuse was designed from an alloy of low melting point elements for securing stability in abnormal current states. Experimental results show that the operating I-T and V-T characteristic constraints can be satisfied by employing the proposed current detecting self-contained low melting point fuse, and through the resistance of the heating resistor. These results thus verify that the proposed protection device can prevent the hazards of short circuit current surges and microcurrent variations of secondary batteries.
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Behavior of the Temperature Coefficient of Resistance at Parallelly Connected Resistors
Sunwoo Lee
J Electr Electron Mater 2018;31(2):98-101.   Published online February 1, 2018
In this paper, we discuss the fabrication of metal alloy resistors. We connected them in parallel to estimate their resistance and temperature coefficient of resistance (TCR). The fabricated resistors have different resistances, 5 and 10 Ω and different TCRs, 50 and 200 ppm/℃. Each resistor was confirmed to have the correct atomic composition through the use of energy dispersive X-ray (EDX). The resistors’ electrical properties were confirmed by measuring resistance and TCR. The resistance and TCR of the resistors connected in parallel were estimated through the increase in resistance due to the increase in temperature, and were compared with the measured values. We are confident that this TCR estimation technique, which uses the increase in resistance due to temperature, will be very useful in designing and fabricating resistors with low and stable TCR.
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Fabrication of Alloy Target for Formation of Ti-Al-Si-N Composite Thin Film and Their Mechanical Properties
Han-chan Lee
J Electr Electron Mater 2016;29(10):665-670.   Published online October 1, 2016
Prevailing dissemination of machine tools and cutting technology have caused drastic developments of high speed dry machining with work materials of high hardness, and demands on the high-hardness-materials with high efficiency have become increasingly important in terms of productivity, cost reduction, as well as environment-friendly issue. Addition of Si to TiAlN has been known to form nano-composite coating with higher hardness of over 30 GPa and oxidation temperature over 1,000℃. However, it is not easy to add Si to TiAlN by using conventional PVD technologies. Therefore, Ti-Al-Si-N have been prepared by hybrid process of PVD with multiple target sources or PVD combined with PECVD of Si source gas. In this study, a single composite target of Ti-Al-Si was prepared by powder metallurgy of MA (mechanical alloying) and SPS (spark plasma sintering). Properties of he resulting alloying targets were examined. They revealed a microstructure with micro-sized grain of about 1~5 ㎛, and all the elements were distributed homogeneously in the alloying target. Hardness of the Ti-Al-Si-N target was about 1,127 Hv. Thin films of Ti-Al-Si-N were prepared by unbalanced magnetron sputtering method by using the home-made Ti-Al-Si alloying target. Composition of the resulting thin film of Ti-Al-Si-N was almost the same with that of the target. The thin film of Ti-Al-Si-N showed a hardness of 35 GPa and friction coefficient of 0.66.
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Thermal Property of Mo-5~20 wt%. Cu Alloys Synthesized by Planetary Ball Milling and Spark Plasma Sintering Method
Han Chan Lee, Kyoung Il Moon, Paik Kyun Shin
J Electr Electron Mater 2016;29(8):516-521.   Published online August 1, 2016
Mo-Cu alloys have been widely used for heat sink materials, vacuum technology, automobile, and many other applications due to their excellent physical and electric properties. Especially, Mo-Cu composites with 5 ~ 20 wt.% copper are widely used for the heavy duty service contacts due to their excellent properties like low coefficient of thermal expansion, wear resistance, high temperature strength, and prominent electrical and thermal conductivity. In most of the applications, highly-dense Mo-Cu materials with homogeneous microstructure are required for better performance. In this study, Mo-Cu alloys were prepared by PBM (planetary ball milling) and SPS (spark plasma sintering). The effect of Cu with contents of 5~20 wt.% on the microstructure and thermal properties of Mo-Cu alloys was investigated.
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Electrical Properties of Cu/Mn Alloy Resistor with Low Resistance and Thermal Stability
Eun Min Kim, Sung Chul Kim, Sun Woo Lee
J Electr Electron Mater 2016;29(6):365-369.   Published online June 1, 2016
In this paper, we fabricated Cu/Mn alloy shunt resistor with low resistance and thermal stability for use of mobile electronic devices. We designed metal alloy composed of copper (Cu) and manganese (Mn) to embody in low resistance and low TCR which are conflict each other. Cu allows high electrical conductivity and Mn serves thermal stability in this Cu/Mn alloy system. We confirmed the elemental composition of the designed metal alloy system by using energy dispersive X-ray (EDX) analysis. We obtained low resistance below 10 mΩ and low temperature coefficient of resistance (TCR) below 100 ppm/℃ from the designed Cu/Mn alloy resistor. And in order to minimize resistance change caused by alternative frequency on circuit, shape design of the metal alloy wire is performed by rolling process. Finally, we conclude that design of the metal alloy system was successfully done by alloying Cu and 3 wt% of Mn, and the Cu/Mn alloy resistor has low resistance and thermal stability.
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Insulation Materials : Regular Paper ; Effect of PEO Process Conditions on Oxidized Surface Properties of Mg alloy, AZ31 and AZ91. 1. Applied Voltage and Time
Jae Ho Ham, Min Seok Jeon, Yong Nam Kim, Min Chul Shin, Kwang Youp Kim, Bae Yeon Kim
J Electr Electron Mater 2016;29(4):218-224.   Published online April 1, 2016
The surface of Mg alloy, AZ31 and AZ91, were treated by PEO (plasma electrolytic oxidation) in Na-P system electrolyte, with different applied voltage and time. Thickness, roughness and X-ray crystallographic analysis revealed several results. The more applied time and voltage of PEO treated, the thicker oxidized surface coating layer were covered. And surface roughness increased with the thickness of oxidized layer. It was thought that when oxide layer grew, resistivity and breakdown voltage increased with the thickness of layer, and then, the energy of micro plasma need to be higher then before. So, it made craters and pores of surface become greater, which were responsible for the coarse surface.
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Electromagnetic Wave Absorbing Properties of FeSiCr and Fe50Ni Flaky Powder-Polymer Composite Sheet
Seok Moon Lee, Sang Mun Kim
J Electr Electron Mater 2014;27(7):462-467.   Published online July 1, 2014
In this paper, we studied the magnetic composite sheets for electromagnetic wave noise absorber of quasi-microwave band by using soft magnetic FeSiCr and Fe50Ni flakes with the thickness of about 1 μm and polymer. The magnetic hysteresis curve including saturation magnetization and residual magnetization and the complex permeability characteristics of the composite sheets were investigated to clarify the mixing effect on electromagnetic wave absorption properties. The saturation magnetization was decreased about 10% while the residual magnetization was increased about 15% and the real parts of complex permeability at below 500 MHz were increased 0.6~4 while those values at above 500 MHz were decreased 0.4~2.5 according to the change of contents of FeSiCr and Fe50Nipowders. As a result, the reflection loss can be moved to the lower frequency from 2∼3 GHz to 1∼1.5GHz as the contents of Fe50Ni flaky powder into FeSiCr flaky powder was increased up to 50%.
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Study of the Non-polar Optical Phonon Scattering According to the Size of Unit Cell in an Alloy Semiconductor
Dae Myung Chun, Tae Hyun Kim, Sang Kook Chun
J Electr Electron Mater 2011;24(10):784-789.   Published online October 1, 2011
A linear spring model, where the interactions among atoms are assumed to be isotropic and elastic, is employed for the study of non-polar optical phonon scattering in the valence band of alloy semiconductors. The force equations of n atoms are used in the spring model for the consideration of the random distribution of constituent atoms in an alloy semiconductor. When the number of atoms in a unit cell is assumed to be two based on the experimental result, the optical deformation potent is valid for compound semiconductors as well as alloy semiconductors.
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Regular Paper : Fabrication of the (Alnico, Sm-Co) Bonded Magnet and its Magnetic Properties
Jung Sik Kim
J Electr Electron Mater 2010;23(12):988-995.   Published online December 1, 2010
In this study the (Alnico, Sm-Co) bonded magnets were fabricated by mixing the Sm-Co added alnico alloy powders with epoxy resin and binder, appropriately. Also, the hybrid ring magnets of (Alnico, Sm-Co)/Sr-ferrite were fabricated by coupling the Sr-ferrite composite layer with an (Alnico, Sm-Co) magnet. The magnetic properties of (Alnico, Sm-Co) ring magnets were varied with the amount of Sm-Co powders. The addition of Sm-Co powders increased a remanent induction(Br) and coercive force(BHC), while decreasing a surface flux density and repulsive distance. The surface flux density and repulsive distance for the (Alnico, Sm-Co) ring magnet increased with a magnetizing voltage up to about 160 V and reached an apparent saturation point. Also, the measurements of temperature and moisture characteristics showed that the surface flux densities of N-S poles and repulsive distance decreased a little within 4% after 10 days passed.
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Fabrication of the Micromachined Transformer using High Permeability NiFe Core
Se Jun Cho, Doo Yeol Cha, Jai Hyuk Lee, Soo Jin Lee, Sung Pil Chang
J Electr Electron Mater 2010;23(3):194-198.   Published online March 1, 2010
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Surface Segregation and Order of FeCo Alloy
Wone Keun Han
J Electr Electron Mater 2010;23(3):240-244.   Published online March 1, 2010
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Energy-band-gap Variation of In(X)GaN(1-X) Thin Films with Indium Composition
Ki Cheol Park, Tae Young Ma
J Electr Electron Mater 2009;22(8):677-681.   Published online August 1, 2009
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Fabrication of ZnO Nanowires by Direct Melt Oxidation of Al-Zn Alloy
Geun Hyoung Lee, Il Soo Kim, Byoung Chul Shin, Won Jae Lee
J Electr Electron Mater 2008;21(11):995-999.   Published online November 1, 2008
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Thermal Stability Improvement of Ni-germanide using Ni-Co alloy for Ge-MOSFETs Technology
Kee Young Park, Soon Yen Jung, Ying Ying Zhang, In Shik Han, Shi Guang Li, Zhun Zhong, Hong Sik Shin, Yeong Cheol Kim, Jae Jun Kim, Ga Won Lee, Jin Suk Wang
J Electr Electron Mater 2008;21(8):733-737.   Published online August 1, 2008
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Thermal Stability Improvement of Ni-Suicide using Ni-Co alloy for Nano-scale CMOSFET
J Electr Electron Mater 2008;21(1):18-22.   Published online January 1, 2008
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Microstructure Characterization for Nano-thick Nickel Cobalt Composite Suicides from 10 nm-Ni(0.5)Co(0.5) Alloy Films
J Electr Electron Mater 2007;20(4):308-317.   Published online April 1, 2007
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Thermal Stability of Ta-Mo Alloy Film on Silicon Dioxide
Yeong Jin No, Chung Geun Lee, Sin Nam Hong
J Electr Electron Mater 2004;17(4):361-366.   Published online April 1, 2004
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Characteristics of Non-alloyed Mo Ohmic Contacts to Laser Activated p-type SiC
C. Y. Lee, J. H. Song, J. S. Choi, J. B. Lee, K. H. Kim, Y. S. Kim, K. H. Park, H. G. Lee
J Electr Electron Mater 2003;16(7):557-563.   Published online July 1, 2003
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Superconductor,Magnetic Materials : The Effects of Alloying-Element Additions to Ag Sheath on Thermal Conductivity and Properties of Bi-2223 Superconductor Tapes
Seok Hem Jang, Jung Ho Kim, Jun Hyung Lim, Kyu Tae Kim, Jin Ho Joo, Bong Ki Ji, John Slavko Volf, Hua Kun Liu, Miles Apperley
J Electr Electron Mater 2003;16(7):627-633.   Published online July 1, 2003
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