The dielectric and piezoelectric properties of the ferroelectric BaTiO₃ were measured and analyzed using both strong and weak electric field conditions. To measure the electric field induced polarizations and strains, a high voltage source and the measuring circuit were used and the dielectric constants were measured with an impedance analyzer. The spontaneous polarization of BaTiO₃ at room temperature was calculated as 17 μC/cm² based on the lattice structure and internal ion location, which is in good agreement with the experimental results. The polarization and strain hysteresis curve according to the electric field were analyzed in terms of lattice structure and ion position. The magnitude of remanent polarization is proportional to the offset distance of Ti⁴⁺ ion from the lattice center. The magnitude of dielectric permittivity is proportional to the degree to which Ti⁴⁺ ion can move freely inside the lattice. The magnitude of piezoelectric constant d₃₃ is proportional to how much Ti⁴⁺ ion distorts the lattice as it moves inside the lattice.

The changes in threshold voltage and DIBL were investigated for changes in remanent polarization P_r and coercive field E_c, which determine the characteristics of the P-E hysteresis curve of ferroelectric in NCFET (negative capacitance FET). The threshold voltage and DIBL (drain-induced barrier lowering) were observed for a junctionless double gate MOSFET using a gate oxide structure of MFMIS (metal-ferroelectric-metal-insulator-semiconductor). To obtain the threshold voltage, seriestype potential distribution and second derivative method were used. As a result, it can be seen that the threshold voltage increases when P_r decreases and E_c increases, and the threshold voltage is also maintained constant when the P_r/E_c is constant. However, as the drain voltage increases, the threshold voltage changes significantly according to P_r/E_c, so the DIBL greatly changes for P_r/E_c. In other words, when P_r/E_c=15 pF/cm, DIBL showed a negative value regardless of the channel length under the conditions of ferroelectric thickness of 10 nm and SiO₂ thickness of 1 nm. The DIBL value was in the negative or positive range for the channel length when the P_r/E_c is 25 pF/cm or more under the same conditions, so the condition of DIBL=0 could be obtained. As such, the optimal condition to reduce short channel effects can be obtained since the threshold voltage and DIBL can be adjusted according to the device dimension of NCFET and the P_r and E_c of ferroelectric.

Thermal batteries are used in military power sources that require robustness and long storage life for applications in missiles and torpedoes. FeS₂ powder is currently used as a cathode material because of its high specific energy density, environmental non-toxicity, and low cost. MS₂ (M = Fe, Ni, Co) cathodes have been explored as novel candidates for thermal batteries in many studies; however, the discharge characteristics (1, 2, 3 plateau) of single cells in thermal batteries with different cathodes have not been elucidated in detail. In this study, we independently analyzed the discharge voltage and calculated the total polarizations of single cells using MS₂ cathodes. Based on the results of this study, we propose NiS₂ as a potential cathode material for use in thermal batteries.

Ferroelectric Pb(Zr_0.52Ti_0.48)O₃ (PZT) films were deposited on SrTiO₃(100) substrate by using conductive SrRuO₃ films as underlayer and their structural and ferroelectric properties were investigated. PZT films were grown in (00l) orientation on well lattice-matched pseudo-cubic SrRuO₃ films. Thickness dependence of ferroelectric and electrical properties of PZT films was investigated. PZT film with 400 nm thickness showed a remanent polarization (P_r) of 29.0 μC/cm² and coercive field (E_c) of 83 kV/cm, and P_r decreased and E_c increased with thickness reduction. The dielectric constant for PZT films showed gradual decrease with thickness reduction. Breakdown field of PZT films did not show the thickness dependence and displayed as high value as 1 MV/cm.

Single-chamber solid oxide fuel cells (SC-SOFCs) consist of only one gas chamber, in which both the anode and the cathode are exposed to the same fuel-oxidant mixture. Thus, this configuration shows good thermal and mechanical resistance and allows rapid start-up and -down. In this study, the unit cell consisting of La_0.8Sr_0.2MnO₃ (cathode) / Zr_0.84Y_0.16O_2-x (electrolyte) / Ni-Zr_0.84Y _0.16O_2-x (anode) was fabricated and its electrochemical property was investigated as a function of temperature and the volume ratio of fuel and oxidant for SC-SOFCs. Impedance spectra were also investigated in order to figure out the electrical characteristics of the cell. As a result, the cell performance was governed by the polarization resistances of the electrodes. The cell exhibited an acceptable cell-performance of 86 mW/cm2 at 800℃ and stable performance for 3 hs under 0.7 V.

In this study, electrocaloric effects of Pb-free (Ba0.85Ca0.15)(Ti0.92Zr0.08)O3 ferroelectric ceramics were investigated and discussed using the characteristics of P-E hysteresis loops at wide temperature range from room temperature to 140℃. The remnant polarization Pr and coercive field Ec were decreased with increasing temperature. The temperature change ΔT by the electrcaloric effect was calculated by Maxwell`s relations, and reached the maximum of ∼0.15 at 120℃ under applied electric field of 30 kV/㎝.