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Volume 29(3); March 2016

Regular Paper : Study on Chip on Chip Technology for Minimizing LED Driver Ics
Ey Goo Kang
J Electr Electron Mater 2016;29(3):131-134.   Published online March 1, 2016
This research was analyzed thermal characteristics that was appointed disadvantage when smart LED driver ICs was packaged and we applied extracted thermal characteristics for optimal layout design. We confirmed reliability of smart LED driver ICs package without additional heat sink. If the package is not heat sink, we are possible to minimize package. For extracting thermal loss due to overshoot current, we increased driver current by two and three times. As a result of experiment, we obtained 22 mW and 49.5 mW thermal loss. And we obtained optimal data of 350 mA driver current. It is important to distance between power MOSFET and driver ICs. If thhe distance was increased, the temperature of package was decreased. And so we obtained optimal data of 3.7 mm distance between power MOSFET and driver ICs. Finally, we fabricated real package and we analyzed the electrical characteristics. We obtained constant 35 V output voltage and 80% efficiency.
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Regular Paper : Fabrication of PMMA-HfOx Organic-Inorganic Hybrid Resistive Switching Memory
Il Jin Baek, Won Ju Cho
J Electr Electron Mater 2016;29(3):135-140.   Published online March 1, 2016
In this study, we developed the solution-processed PMMA-HfOx hybrid ReRAM devices to overcome the respective drawbacks of organic and inorganic materials. The performances of PMMA-HfOx hybrid ReRAM were compared to those of PMMA- and HfOx-based ReRAMs. Bipolar resistive switching behavior was observed from these ReRAMs. The PMMA-HfOx hybrid ReRAMs showed a larger operation voltage margin and memory window than PMMA-based and HfOx-based ReRAMs. The reliability and electrical instability of ReRAMs were remarkably improved by blending the HfOx into PMMA. An Ohmic conduction path was commonly generated in the LRS (low resistance state). In HRS (high resistance state), the PMMA-based ReRAM showed SCLC (space charge limited conduction). the PMMA-HfOx hybrid ReRAM and HfOx-based ReRAM revealed the Pool-Frenkel conduction. As aresult of flexibility test, serious defects were generated in HfOx film deposited on PI (polyimide) substrate. On the other hand, the PMMA and PMMA-HfOx films showed an excellent flexibility without defect generation.
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Regular Paper : Design and Fabrication of Digital Water Meter Using a Variable Capacitor
Keun Hyung Park
J Electr Electron Mater 2016;29(3):141-146.   Published online March 1, 2016
The AMR(automatic meter reading) system has been increasingly and widely used for its efficient and intelligent management, which is a technology that automatically collects consumption data from a water meter or energy metering device. The digital meter instead of the mechanical meter should be used in the system. Up to now, various types of sensor to measure the water flow rate have been used in the digital water meter, for example, reed switch, photo IR approximate sensor, ultrasonic sensor, electromagnetic sensor, etc. In this paper, a new sensing technology, where a variable capacitor and digital circuit were used for sensing the water flow rate, was proposed. The circuit was designed and verified by Pspice simulation. And a PCB board for the circuit was fabricated. After then, a prototype of digital water meter using a variable capacitor to measure the water flow rate was fabricated. The function tests of the fabricated digital water meter were performed, and it was found that the meter worked properly. Since the new technology has much better properties in terms of cost and power consumption compared to conventional technologies, it should be one of the majordigital water meter technologies in the future.
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Regular Paper : Characterization of Hot Electron Transistors Using Graphene at Base
Hyung Gyoo Lee, Sung Jin Kim, Il Suk Kang, Gi Sung Lee, Ki Nam Kim, Jin Won Koh
J Electr Electron Mater 2016;29(3):147-151.   Published online March 1, 2016
Graphene has a monolayer crystal structure formed with C-atoms and has been used as a base layer of HETs (hot electron transistors). Graphene HETs have exhibited the operation at THz frequencies and higher current on/off ratio than that of Graphene FETs. In this article, we report on the preliminary results of current characteristics from the HETs which are fabricated utilizing highly doped Si collector, graphene base, and 5 nm thin Al2O3 tunnel layers between the base and Ti emitter. We have observed E-B forward currents are inherited to tunneling through Al2O3 layers, but have not noticed the Schottky barrier blocking effect on B-C forward current at the base/collector interface. At the common-emitter configuration, under a constant VBE between,0~1.2V, Ic has increased linearly with VCE forVCE<VCE indicating the saturation region. As the VCE increases further, a plateau of Ic vs. VCE has appeared slightly at VCE-VBE, denoting forward-active region. With further increase of, has kept increasing probably due to tunneling through thin Schottky barrier between B/C. Thus the current on/off ration has exhibited to be 50. To improve hot electron effects, we propose the usage of low doped Si substrate, insertion of barrier layer between B/C, or substrates with low electron affinity.
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Regular Paper : A Study on The Degradation Characteristics of MLCCs SAC305 Lead-Free Solder Joints and Growth IMCs by Thermal Shock Test
Sang Won Jung, Min Soo Kang, Yu Jea Jeon, Do Seok Kim, Young Eui Shin
J Electr Electron Mater 2016;29(3):152-158.   Published online March 1, 2016
The bonding characteristics of MLCCs (multi layer ceramic capacitor, C1608) lead-free solder (SAC305) joints were evaluated through thermal shock test (-40℃~125℃, total 1,800 cycle). After the test, IMCs( intermetallic compounds) growth and cracks were verified, also shear strengths were measured for degradation of solder joints. In addition, The thermal stress distributions at solder joints were analyzed to compare the solder joints changes before and after according to thermal shock test by FEA (finite elements analysis). We considered the effects of IMCs growth at solder joints. As results, the bonding characteristics degradation was occurred according to initial crack, crack propagations and thermal stress concentration at solder-IMCs interface, when the IMCs grown to solder inside.
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Regular Paper : Dielectric and Piezoelectric Properties of (Na,K,Li)(Nb,Ta,Sb)O3 Ceramics Manufactured Using Columbite Methods with Calcination Temperature
Cheol Min Ra, Ju Hyun Yoo
J Electr Electron Mater 2016;29(3):159-163.   Published online March 1, 2016
In this paper, in order to develop optimum composition ceramics with excellent piezoelectric properties, (Na0.525K0.443Li0.037)(Nb0.823Sb0.08Ta0.037)O3 + 0.3 wt%Bi2O3 + 0.4 wt%Fe2O3 lead-free piezoelectric ceramics were synthesized by conventional soild-state method. The calcination temperature of columbite precursors were fabricated at temperature range from 950℃ to 1,150℃ and sintering aids with low melting point were added to densify these ceramics. Effect of calcination temperature on dielectric and piezoelectric properties of ceramics were investigated. the ceramics with B-site columbite precursors at temperature of 1,100℃ obtained the optimal values of d33=272 [pC/N], kp=0.51, Qm=102, εr=978.
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Regular Paper : Dielectric Properties and Electrocaloric Effects of PLZT Ferroelectric Ceramics by Applying Electric Fields
You Seok Kim, Ju Hyun Yoo, Yeong Ho Jeong
J Electr Electron Mater 2016;29(3):164-167.   Published online March 1, 2016
In this study, in order to develop relaxor ferroelectric ceramics for refrigeration device application with large electrocaloric effect, PLZT(8/65/35) composition was fabricated using conventional solid-state method. The Curi temperature of this composition PLZT ceramics was 230℃, and the P-E hysteresis loops of the PLZT ceramics as a fuction of temperature became slim by degrees with higher temperatures. The maximum value of .T of 0.243°C in ambient temperature of 215°C with 30 kV/cm was appeared. It is considered that PLZT ceramics possess the possibility of refrigeration device application.
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Regular Paper : A Study on the Optical Characteristics of Multi-Layer Touch Panel Structure on Sapphire Glass
Young Hoon Kwak, Seong Cheol Moon, Ji Seon Lee, Seong Eui Lee
J Electr Electron Mater 2016;29(3):168-174.   Published online March 1, 2016
A conductive oxide-based sapphire glass indium tin oxide/metal electrode and the optical coating, through patterning process was studied in excellent optical properties and integrated touch panel has a high strength. Indium tin oxide conductive oxides of the sapphire glass to 0.3 A at DC magnetron sputtering method of 10 min, gas flow Ar 10 Sccm Ar, O2 1.0 Sccm the formation conditions of the thin film after annealing at 550℃ for 30min was achieved through a 86% transmittance. In addition, the coating 130 nm hollow silica sol-gel was to improve the optical transmittance of the indium tin oxide to 91%. For the measurement by the modeling hollow silica sol by Macleod simulation and calculated the average values of silica part to the presence or absence in analogy to actual. Refractive index value and the actual value of the material on the simulation the transmittance difference is it does not completely match the air region similar to the actual value (transmission) could be confirmed that the measurement is set to a value of between 5 nm and 10 nm
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Regular Paper : Optical Compensation of IPS-LCD for Symmetric-High-Contrast at Off-Axis Oblique View
Tae Hyeon Kim, Bong Sik Kim, Woo Sang Park
J Electr Electron Mater 2016;29(3):175-180.   Published online March 1, 2016
In this study, we proposed an optical compensation method to improve the symmetricity of contrast ratio for wide viewing angle IPS (in-plane switching) LCD. First, the phase retardation depending on the thickness of compensation film is calculated, and then the phase change is presented at the Poincare sphere. The phase retardation and the polarization state of the light passing through the optical elements are caculated by using the EJMM (extended Jones matrix method). In addition, the transmittance and the contrast countour are also calculated by using the Berremann``s 4x4 matrix method. The simulation is carried out for a IPS LC cell with positive A/C/A compensation film. From the standard deviation of the contrast ratio, we confirmed the symmetricity at each viewing angle is inversely proportional to the standard deviation and calculated the optimum design condition of the uniaxial compensation film for the IPS LCD.
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Regular Paper : Vacuum Sealing Technology of the Flat Panel Display by using the Frit Glass Heatable in Vacuum
Sang Jik Kwon, In Sang Yoo
J Electr Electron Mater 2016;29(3):181-185.   Published online March 1, 2016
One of the important issues for fabricating the microelectronic display devices such as FED, PDP, and VFD is to obtain a high vacuum level inside the panel. In addition, sustaining the initial high vacuum level permanently is also very important. In the conventional packing technology using a tabulation method, it is not possible to obtain a satisfiable vacuum level for a proper operation. In case of FED, the poor vacuum level results in the increase of operating voltage for electron emission from field emitter tips and an arcing problem, resultantly shortening a life time. Furthermore, the reduction of a sealing process time in the PDP production is veryimportant in respect of commercial product. The most probable method for obtaining the initial high vacuum level inside the space with such a miniature and complex geometry is a vacuum in-line sealing which seals two glass plates within a high vacuum chamber. The critical solution for the vacuum sealing is to develop a frit glass to avoid the bubbling or crack problems during the sealing process at high temperature of about 400℃ under the vacuum environment. In this study, the suitable frit power was developed using a mixture of vitreous and crystalline type frit powders, and a vacuum sealed CNT FED with 2 inch diagonal size was fabricated and successfully operated.
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Regular Paper : Optical Properties of MgMoO4:Dy3+,Eu3+ Phosphors Prepared with Different Eu3+Molar Ratios
Jung Dae Kim, Shin Ho Cho
J Electr Electron Mater 2016;29(3):186-191.   Published online March 1, 2016
The effects of Eu3+ doping on the structural, morphological, and optical properties of MgMoO4:Dy3+,Eu3+ phosphors prepared by solid-state reaction technique were investigated. XRD patterns exhibited that all the synthesized phosphors showed a monoclinic system with a dominant (220) diffraction peak, irrespective of the content of Eu3+ ions. The surface morphology of MgMoO4:Dy3+,Eu3+ phosphors was studied using scanning electron microscopy and the grains showed a tendency to agglomerate as the content of Eu3+ ions increased. The excitation spectra of the phosphor powders were composed of a strong charge transfer band centered at 294 nm in the range of 230~340 nm and two intense peaks at 354 and 389 nm, respectively, arising from the 6H15/2→6P7/2 and 6H15/2→ 4M21/2 transitions of Dy3+ ions. The emission spectra of the Mg0.85MoO4:10 mol% Dy3+ phosphors without incorporating Eu3+ ions revealed a strong yellow band centered at 573 nm resulting from the 4F9/2→6H13/2 transitionof Dy3+. As the content of Eu3+ was increased, the intensity of the yellow emission was gradually decreased, while that of red emission band located at 614 nm began to appear, approached a maximum value at 10 mol%, and then decreased at 15 mol% of Eu3+. These results indicated that white light emission could be achieved by controlling the contents of the Dy3+ and Eu3+ ions incorporated into the MgMoO4 host crystal.
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Regular Paper : Synthesis and Characterization of an Organometallic Ruthenium Complex Bearing 4-Picolinic Acid Ligands for Dye-Sensitized Solar Cells (DSSCs)
Hye In Jung, Byeong Kwan An
J Electr Electron Mater 2016;29(3):192-197.   Published online March 1, 2016
A novel heteroleptic ruthenium(II) complex bearing a 4-picolinic acid unit as anchoring ligands (trans-dithiocyanato bis(4-picolinic acid)ruthenium(II) (trans-H1)) was synthesized and its chemical structure was identified by 1H-NMR, FT-IR and mass spectroscopy. The optical, thermal, electrochemical and dye adsorption properties of trans-H1 dye were investigated and compared with those of the gold standard ruthenium complex, Ru(4,4``-dicarboxy-2,2``-bipyridine)2cis(NCS)2 (N3). DSSCs based on trans-H1 dyes were examined under the illumination of AM 1.5 G, 100 mWcm-2 and exhibited typical photovoltaic properties with an open-circuit voltage (VOC) of 0.46 V, a short-circuit current (JSC) of 4.10 mA·cm-2, a fill factor (FF) of 60.4%, and a conversion efficiency (PCE) of 1.14%.
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