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J Electr Electron Mater : Journal of Electrical and Electronic Materials

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Bi0.5Na0.5TiO3-BiFeO3-SrTiO3 삼성분계 무연 압전 세라믹스의 강유전체-완화형 강유전체 상전이 거동

이상섭, 이창헌, 즈엉짱안, 웬호앙티엔코이, 한형수, 이재신

Ferroelectric to Relaxor Transition Behavior in Lead-Free Ternary (Bi0.5Na0.5)TiO3-BiFeO3-SrTiO3 Piezoceramics

Sang Sub Lee, Chang-heon Lee, Trang An Duong, Hoang Thien Khoi Nguyen, Hyoung-su Han, Jae-shin Lee
J Electr Electron Mater 2021;34(1):1-7.
Published online: January 1, 2021
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This study investigated the structural, dielectric, ferroelectric, and strain properties of (0.98-x)Bi1/2Na1/2TiO3- 0.02BiFeO3-xSrTiO3 (BNT-BF-100xST, x=0.20, 0.22, 0.24, 0.26, and 0.28). All samples were successfully synthesized using the conventional solid-state reaction method and sintered at 1,175℃ for 2 h. The average grain size of the BNT-BF-100x ceramics decreased with increasing ST content. Furthermore, we observed that the ferroelectric- relaxor transition temperature (TF-R) decreased with increasing ST content, which eventually vanished in the BNT-BF-24ST ceramics. The results indicated that a ferroelectric to relaxor phase transition could be induced by ST modification. Consequently, a large electromechanical strain of 633 pm/V at 4 kV/mm was observed for the BNT-BF-26ST ceramics. These results imply that our materials have the competitive advantage of larger strain under lower operating field conditions compared with other BNT-based lead-free piezoelectric ceramics. We expect that BNT-BF-ST lead-free piezoelectric ceramics are promising candidates as a novel ternary BNT-based system and can find potential applications in actuators.

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Ferroelectric to Relaxor Transition Behavior in Lead-Free Ternary (Bi0.5Na0.5)TiO3-BiFeO3-SrTiO3 Piezoceramics
J Electr Electron Mater. 2021;34(1):1-7.   Published online January 1, 2021
Download Citation

Download a citation file in RIS format that can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Reference Manager.

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Ferroelectric to Relaxor Transition Behavior in Lead-Free Ternary (Bi0.5Na0.5)TiO3-BiFeO3-SrTiO3 Piezoceramics
J Electr Electron Mater. 2021;34(1):1-7.   Published online January 1, 2021
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