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"ITO"

Multilayer Ceramic Capacitors for AI Servers and Data Centers: Challenges, Reliability Issues, and Future Technology Directions
Jung Rag Yoon, Seok No Seo, Min-woo Ha, Moon-taek Cho
J Electr Electron Mater 2026;39(1):34-51.   Published online January 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.1.5
The rapid proliferation of artificial intelligence (AI) servers and high-performance computing systems has significantly elevated the technical and reliability requirements for multilayer ceramic capacitors (MLCCs). In such systems, MLCCs are critical passive components that must deliver high capacitance, fast transient response, and robust insulation performance under high temperature, voltage, and current density. This review examines the material, structural, and process innovations that underpin MLCC performance in AI applications. Key topics include the development of ultrathin dielectric layers (<0.5 μm), rare-earth doped BaTiO₃-based dielectrics with enhanced DC bias stability, and core-shell microstructures designed for temperature and field resilience. The paper also explores insulation degradation mechanisms―such as vacancydriven conduction and demixing―and advanced reliability assessment methodologies, including HALT, TSDC, and the tipping point framework. Comparisons with automotive-grade MLCCs highlight the unique requirements of AI systems, such as ultraminiaturization, high volumetric efficiency, and ppm-level field failure rates. Finally, the review discusses emerging trends in MLCC technology, including particle engineering, interface stabilization, and advanced lamination techniques, and provides insight into the future direction of capacitor development tailored to AI data center environments.
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Electrical Properties Based on the Number of Stacked Layers for the Optimal Design of BaTiO-Based MLCCs for MIL-PRF-32535 Compliance
Change-ho Lee, Hong Sun Lee, Seok No Seo, Jung Rag Yoon
J Electr Electron Mater 2025;38(5):513-520.   Published online September 1, 2025
DOI: https://doi.org/10.4313/JEEM.2025.38.5.6
Multilayer ceramic capacitors (MLCCs) are essential for high-capacitance, miniaturized, and reliable electronic applications. This study examines the impact of layer stacking on the dielectric and electrical properties of MLCCs using a BaTiO₃-based dielectric with MgO, Mn₃O₄, Yb₂O₃, V₂O5, and (BaCa)SiO₃ glass additives. MLCCs with 10 um-thick dielectric layers and varying Ni electrode layers (10, 30, 50, and 100 layers) were fabricated. The dielectric constant increases significantly up to 30 layers due to compressive stress and sintering densification but it becomes linear beyond 30 layers. Dissipation factor and ESR decrease with higher stacking due to improved sinterability, while breakdown voltage declines exponentially from defect accumulation and thermal stress. Insulation resistance decreases but stabilizes relative to capacitance. C-V results show stress-induced polarization suppression, which reduces the dielectric constant under high voltage. Optimized stacking and sintering conditions are crucial for MIL-PRF-32535 compliant MLCC designs.
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A Study on the Development of an Uninterruptible Diagnosis Determination Method for Molded Transformers Using Multiple Diagnosis Sensors
Seok Myung Bae, Yong Moo Chang, Hyo Jin Kim
J Electr Electron Mater 2025;38(5):573-579.   Published online September 1, 2025
DOI: https://doi.org/10.4313/JEEM.2025.38.5.14
With the rapid development of digital technologies such as IoT, AI, and big data, electrical energy consumption is rapidly increasing. Electrical facilities that supply electrical energy are operated with high reliability and stability for end-of-life time. In addition, depending on the type of electrical load that consumes electrical energy in various forms, electrical insulation systems deteriorate due to electrical and thermal stress, which reduces electrical and mechanical insulation strength. Due to such continuous stress and electrical transient phenomena, electrical facilities may experience electrical accidents due to electrical insulation breakdown before the expected design lifetime. In addition, periodic inspections according to related regulations must be conducted to prevent unexpected electrical accidents, but this leads to problems in which the electrical facilities cannot be turned off. Therefore, it is believed that an uninterruptible diagnostic judgment technique that determines compliance with related regulations such as electrical facility technology standards, internal wiring regulations, and inspection regulations without turning off the electrical facilities and at the same time detects abnormal conditions of the facilities early, it is possible to prevent electrical accidents and improve the efficiency of electrical facilities. In this paper, we propose an uninterruptible power diagnosis judgment technique that can prevent or reduce electrical accidents in cast-iron transformers by applying judgment criteria of diagnostic sensors for various types of measurement parameters that can diagnose and evaluate the presence or absence of abnormalities in electrical equipment, including partial discharge, and AI algorithms learned from data of diagnostic sensors.
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Dielectric Characteristics of (BaCaSr)(TixZr1-x)O3 Dielectric Ceramic with Temperature Compensation Capacitor Characteristics
Yoo Jung Choi, Hong Sun Lee, Jung Rag Yoon
J Electr Electron Mater 2025;38(4):376-382.   Published online July 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.4.4
This study developed a dielectric composition for high-capacitance MLCCs with C0G and U2J temperature compensation characteristics (Class I) under reducing conditions. The potential application of this composition in highpermittivity class I MLCCs was examined. Using (Ba₀.₂₄Ca₀.₁₆Sr₀.₆)(TiₓZr₁₋ₓ)O₃. XRD analysis showed that secondary phases like Sr₂TiO₄ and TiO₂ formed at higher Ti content, affecting the stoichiometric balance. Adjusting the Ti/Zr molar ratio resulted in a dielectric constant of 41.2 ~ 105, a dielectric loss of 0.082 ~ 0.174%, and insulation resistance above 1.6 × 1013 ohms at 25℃. The TCC shifted from C0G to U2J as the Ti/Zr ratio increased, but the composition enabled the design of high-capacitance and high-voltage MLCCs with favorable dielectric and electrical properties.
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Challenges and Fabrication Strategies for MXene-Based Flexible Micro-Supercapacitors
Yonghee Lee, Jae Jeong Choi, Ye Eun Baek
J Electr Electron Mater 2025;38(4):347-357.   Published online July 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.4.1
Flexible micro-supercapacitors (MSCs) based on 2D MXenes offer strong potential for next-generation energy storage in wearable and integrated electronics, yet still face critical challenges such as limited energy density, mechanical reliability, and scalable large-area manufacturing. This review surveys recent strategies to address these limitations, with a particular focus on fabrication techniques and wafer-level integration approaches. Wafer-scale processing on both rigid and flexible substrates has emerged as a key milestone toward scalable, high-yield industrial production of flexible MSCs. By examining the strengths and drawbacks of current fabrication strategies, this review highlights essential directions for advancing MXene-based flexible MSCs toward practical and widespread application.
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This study examined the crystallinity and potential of BaTiO₃ powder, prepared by hydrothermal synthesis at 60 nm, as a dielectric material for automotive MLCCs under varying heat treatment temperatures. At temperatures above 850℃, the powder exhibited an orthorhombic structure, with crystallinity and particle size increasing as the temperature rose. In the range of 850~900℃, the powder displayed a uniform particle size distribution and minimal agglomeration, with particles ranging between 150~200 nm. Additionally, it was confirmed that the heat treatment temperature significantly impacts the properties of BaTiO₃ powder, which are critical for the dielectric performance required in X7R MLCCs used in automotive applications. Specifically, high-temperature treatment (above 850℃) was essential for enhancing the powder's crystallinity and forming a stable core-shell structure, which is crucial for achieving stable TCC (Temperature Coefficient of Capacitance) characteristics. It was confirmed that increased crystallinity at temperatures above 850℃ facilitated the development of the core-shell structure through interactions with additives, thereby achieving the necessary characteristics required for highly reliable automotive MLCCs.
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Low-Power LC-VCO Design Based on Si-NWFET Using Switched Capacitor Array
Seung Hyeok Choi, Han Jung Song
J Electr Electron Mater 2025;38(2):200-206.   Published online March 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.2.11
This paper presents a Si-NWFET-based LC-VCO design that includes an SCA, a P-type Si-NWFET varactor, a 1.2 nH LC tank, and a bias network to linearize the varactor’s C-V characteristics, enabling a wide oscillation frequency tuning range. The circuit achieves a 24 GHz oscillation frequency with a low power consumption of 16.8 μW at a control voltage (Vctrl) of 0.7 V. Phase noise simulations indicate an excellent -109.62 dBc/Hz at a 1 MHz offset, confirming its applicability for RFIC systems. Additionally, the proposed LC-VCO demonstrates stable performance in five major corner process analyses, ensuring robustness under extreme conditions. These results validate the durability of the design and highlight the potential of Si-NWFETbased LC-VCOs as a viable, low-power, highly integrated solution for RFIC applications. The findings underscore the suitability of Si-NWFET technology as a promising alternative to current FinFET and CMOS processes in advanced circuit design.
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IoT Using Assemble Double Pipe System
Ji-min Lee, Chang-hyoung Lee, Min-cheol Oh, Sangjin Cho, Young Cho
J Electr Electron Mater 2025;38(1):84-88.   Published online January 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.1.11
Hazardous gas leakage incidents rank among the most serious safety accidents, leading to significant loss of life, extensive property damage, and severe environmental pollution. This paper describes an innovative IoT-based Assembly Double Pipe System (IADPS) designed for the prevention, early detection, and automated isolation of toxic gas leaks. The proposed system features a double-layered pipe design, with nitrogen charged between the inner and outer pipes, and gas detectors installed at strategic locations. This configuration is intended to prevent pipe corrosion, suppress ignition caused by escaping gas, and facilitate the early detection of gas leaks, thereby mitigating the risk of safety accidents. Furthermore, the system includes a comprehensive real-time monitoring system for pipe integrity and gas leakage, as well as an automated gas leakage detection and isolation system to quickly respond to any incidents.
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Electrical Properties of (Ba0.27CaSr)(Zr0.95Ti0.05)O₃ Dielectric Ceramic with C0G Temperature Characteristics
Hong Sun Lee, Jung Rag Yoon
J Electr Electron Mater 2024;37(6):662-667.   Published online November 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.6.13
In this study, the electrical properties of a C0G (class 1 ceramic) dielectric composition with internal reducibility, specifically (Ba0.27CaSr)(Zr0.95Ti0.05)O₃, were investigated by fixing Ba at the A site and varying the Ca/Sr molar ratio. The potential application of this composition in high-permittivity C0G MLCCs was examined. The powder was calcined at 1,150℃ for 2 hours, as determined by TG-DTA analysis, and the resulting powder was ground to achieve a particle size (D50) of 0.35 to 0.4 μm and a specific surface area (BET) of 4.5 to 5.0 g/m². With a Ca/Sr molar ratio of 0.3, the composition (Ba0.27Ca0.17Sr0.56) (Zr0.95Ti0.05)O₃ exhibited electrical properties with a permittivity of 41.9, a loss of less than 0.008%, and an insulation resistance exceeding 2.2×10¹³ Ω. The feasibility of using this composition for high-capacitance C0G MLCCs was confirmed.
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Effect on the Thermal Treatment for Improving Efficiency in Silicon Heterojunction Solar Cells
Hyeong Gi Park, Junsin Yi
J Electr Electron Mater 2024;37(4):439-444.   Published online July 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.4.12
This study investigates the post-thermal treatment effects on the efficiency of silicon heterojunction solar cells, specifically examining the influence of annealing on p-type microcrystalline silicon oxide and ITO thin films. By assessing changes in carrier concentration, mobility, resistivity, transmittance, and optical bandgap, we identified conditions that optimize these properties. Results reveal that appropriate annealing significantly enhances the fill factor and current density, leading to a notable improvement in overall solar cell efficiency. This research advances our understanding of thermal processing in siliconbased photovoltaics and provides valuable insights into the optimization of production techniques to maximize the performance of solar cells.
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Effects of Film Thickness and Post-Annealing Temperature on Properties of the High-Quality ITO Thin Films with RF Sputtering Without Oxygen
Jiha Seong, Hyungmin Kim, Seongmin Shin, Kyunghwan Kim, Jeongsoo Hong
J Electr Electron Mater 2024;37(3):253-260.   Published online May 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.3.3
In this study, ITO thin films were fabricated on a glass substrate at different thicknesses without introducing oxygen using RF sputtering system. The structural, electrical, and optical properties were evaluated at various thicknesses ranging from 50 to 300 mm. As the thickness of deposited ITO thin film become thicker from 50 to 100 mm, carrier concentration, mobility, and band gap energy also increased while the resistivity and transmittance decreased in the visible light region. When the film thickness increased from 100 to 300 mm, the carrier concentration, mobility, and band gap energy decreased while the resistivity and transmittance increased. The optimum electrical properties were obtained for the ITO film 100 nm. After optimizing the thickness, the ITO thin films were post-annealed at different temperatures ranging from 100 to 300℃. As the annealing temperature increased, the ITO crystal phase became clearer and the grain size also increased. In particular, the ITO thin film annealed at 300℃ indicated high carrier concentration (4.32 × 1021 cm-3), mobility (9.01 cm2/V·s) and low resistivity (6.22 × 10-4 Ω·cm). This means that the optimal post-annealing temperature is 300℃ and this ITO thin film is suitable for use in solar cells and display application.
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High Energy Density Dielectric Ceramics Capacitors by Aerosol Deposition
Hyunseok Song, Geon Lee, Jiwon Ye, Ji Yun Jung, Dae-yong Jeong, Jungho Ryu
J Electr Electron Mater 2024;37(2):119-132.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.1
Dielectric ceramic capacitors present high output power density due to the fast energy charge and discharge nature of dielectric polarization. By forming dense ceramic films with nano-grains through the Aerosol Deposition (AD) process, dielectric ceramic capacitors can have high dielectric breakdown strength, high energy storage density, and leading to high power density. Dielectric capacitors fabricated by AD process are expected to meet the increasing demand in applications that require not only high energy density but also high power output in a short time. This article reviews the recent progress on the dielectric ceramic capacitors with improved energy storage properties through AD process, including energy storage capacitors based on both leadbased and lead-free dielectric ceramics.
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A Brief Review on Piezoelectrics-Based Paint Sensors
Hyoung-su Han, Trang An Duong, Chang Won Ahn, Byeong Woo Kim, Jae-shin Lee
J Electr Electron Mater 2023;36(5):433-441.   Published online September 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.5.2
Piezoelectric ceramics play an important role in electrical and electronic devices such as sensors, actuators, and microelectronic devices. However, traditional ceramics are difficult to be used in various process industries due to their high brittleness and low flexibility. Therefore, piezoelectric paint sensors have been designed for application to the curved surfaces of complicated structures. Furthermore, recently, significant attention has been focused on the development of paint sensors that can be used as structure health monitoring sensors for vibration, impact, and acoustic emission. Several studies have successfully demonstrated the possibility that smart paint sensors can take the place of traditional ceramic sensors. In this review, we briefly introduce the concept of the piezoelectric paint sensors and the expected application field as well as their preparation and history.
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Nitrogen-doped graphene was synthesized by a hydrothermal method using graphene oxide (GO) as the raw material, urea as the reducing agent and nitrogen as the dopant. The morphology, structure, composition and electrochemical properties of the samples are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), nitrogen adsorptiondesorption analysis, electrical conductivity and electrochemical tests. The results show that urea can effectively reduce GO and achieve nitrogen doping under the hydrothermal conditions. By adjusting the mass ratio of raw materials to dopants, the graphene with different nitrogen doping contents can be obtained; the nitrogen content range is from 5.28~6.08% (atomic fraction percentage).When the ratio of dopant to urea is 1:30, the nitrogen doping content reaches a maximum of 6.08%.The supercapacitor performance test shows that the nitrogen content prepared by the ratio of 6.08% is the best at 0.1 A·g-1. The specific capacitance is 95.2 F·g-1.
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Analysis of Power Pattern According to Load Types
Mi-yong Hwang, Seung-joon Cho, Soon-hyung Lee, Yong-sung Choi
J Electr Electron Mater 2023;36(4):369-375.   Published online July 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.4.7
In this paper, we compared and analyzed the power load patterns of dormitory buildings and office buildings to use them as basic data (demand analysis and capacity design) for the design and operation of microgrids for multi-use facilities, and the following conclusions were got. During the daytime on regular weekdays, the power consumption load pattern of office buildings was relatively large at 264.0~332.3 kWh, and during the evening hours, the power consumption load pattern of dormitory buildings was relatively large at 233.0~258.3 kWh. In the case of vacation, during the daytime on weekdays, the power consumption load pattern of office buildings was relatively large at 279.1~407.4 kWh, and in the evening, the power consumption load pattern of dormitory buildings was relatively high at 280.1~394.1 kWh. During the daytime on regular weekends, the power consumption of dormitory-type buildings was relatively high at 133.5~201.6 kWh, and it was found that the power consumption of dormitory-type buildings appeared relatively high at 187.5~252.1 kWh. During a vacation in the daytime on weekends, the power consumption of dormitory-type buildings was found to be 186.5 kWh~ and 218.6 kWh. The increase in power consumption during a vacation (December-February) compared to normal (April-June) was thought to be due to an increase in electricity demand, and the reason for the higher power consumption in dormitory buildings during the vacation was due to reduced working hours in office buildings.
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Fiber Based Supercapacitors for Wearable Application
Jae Myeong Lee, Wonkyeong Son, Juwan Kim, Jun Ho Noh, Myoungeun Oh, Jin Hyeong Choi, Changsoon Choi
J Electr Electron Mater 2023;36(4):303-325.   Published online July 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.4.1
Flexible fiber- or yarn-based one-dimensional (1-D) energy storage devices are essential for developing wearable electronics and have thus attracted considerable attention in various fields including ubiquitous healthcare (U-healthcare) systems and textile platforms. 1-D supercapacitors (SCs), in particular, are recognized as one of the most promising candidates to power wearable electronics due to their unique energy storage and high adaptability for the human body. They can be woven into textiles or effectively designed into diverse architectures for practical use in day-to-day life. This review summarizes recent important development and advances in fiber-based supercapacitors, concerning the active materials, fiber configuration, and applications. Active materials intended to enhance energy storage capability including carbon nanomaterials, metal oxides, and conductive polymers, are first discussed. With their loading methods for fiber electrodes, a summary of the four main types of fiber SCs (e.g., coil, supercoil, buckle, and hybrid structures) is then provided, followed by demonstrations of some practical applications including wearability and power supplies. Finally, the current challenges and perspectives in this field are made for future works.
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Self-Supporting 3D-Graphene/MnO2 Composite Supercapacitors with High Stability
Zhaoyang Han, Sang-hee Son
J Electr Electron Mater 2023;36(2):175-185.   Published online March 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.2.11
A hybrid supercapacitor is a promising energy storage device in view of its excellent capacitive performance. Commercial three-dimensional foam nickel (Ni) can be used as an ideal framework due to an interconnected network structure. However, its application as an electrode material for supercapacitors is limited due to its low specific capacity. Herein, we report a successful growth of MnO2 on the surface of graphene by a one-step hydrothermal method; thus, forming a three-dimensional MnO2-graphene-Ni hybrid foam. Our results show that the mixed structure of MnO2 with nanoflowers and nanorods grown on the graphene/Ni foam as a hybrid electrode delivers the maximum specific capacitance of 193 F·g-1 at a current density 0.1 A·g-1. More importantly, the hybrid electrode retains 104% of its initial capacitance after 1,000 charge-discharge cycles at 1 A·g-1; thus, showing the potential application as a stable supercapacitor electrode.
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Furnace Annealing Effect on Ferroelectric Hf0.5Zr0.5O2 Thin Films
Min Kwan Cho, Jeong Gyu Yoo, Hye Ryeon Park, Jong Mook Kang, Taeho Gong, Yong Chan Jung, Jiyoung Kim, Si Joon Kim
J Electr Electron Mater 2023;36(1):88-92.   Published online January 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.1.14
The ferroelectricity in Hf0.5Zr0.5O2 (HZO) thin films is one of the most interesting topics for next-generation nonvolatile memory applications. It is known that a crystallization process is required at a temperature of 400℃ or higher to form an orthorhombic phase that results in the ferroelectric properties of the HZO film. However, to realize the integration of ferroelectric HZO films in the back-end-of-line, it is necessary to reduce the annealing temperature below 400℃. This study aims to comprehensively analyze the ferroelectric properties according to the annealing temperature (350-500℃) and time (1-5 h) using a furnace as a crystallization method for HZO films. As a result, the ferroelectric behaviors of the HZO films were achieved at a temperature of 400℃ or higher regardless of the annealing time. At the annealing temperature of 350℃, the ferroelectric properties appeared only when the annealing time was sufficiently increased (4 h or more). Based on these results, it was experimentally confirmed that the optimization of the annealing temperature and time is very important for the ferroelectric phase crystallization of HZO films and the improvement of their ferroelectric properties.
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Dielectric Property Analysis of BaTiO3 Capacitor Manufactured by Inkjet Printing Process
Yu-jin Kim, Gyeong-yeong Lee, In-gon Lee, Ic-pyo Hong, Ji-hoon Kim
J Electr Electron Mater 2022;35(6):610-615.   Published online November 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.6.10
BaTiO3 is one of the ferroelectric materials with excellent dielectric properties such as high dielectric constant, low dielectric loss, and is widely used for the manufacturing of capacitors, piezoelectric converters, microsensors, and ferroelectric memories. Inkjet printing is a technology which uses digital and contactless methods which significantly improves flexibility associated with material and structural design, reducing manufacturing costs. Therefore, the top and bottom electrodes, BaTiO3 ink, and photocurable resin were all printed by an inkjet to produce a BaTiO3 capacitor. The properties of the printed thin film were analyzed. It was confirmed that the photocurable resin ink was well-infiltrated between the BaTiO3 powder particles printed by inkjet. The dielectric properties of the capacitor such as dielectric constant which varies in accordance with frequency, polarization and tunability that changes with voltage, were measured.
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Real-Time Soil Humidity Monitoring Based on Sensor Network Using IoT
Kyeong Heon Kim, Hee-dong Kim
J Electr Electron Mater 2022;35(5):459-465.   Published online September 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.5.6
This paper reports a method to use a wireless sensor network deployed in the field to real-time monitor soil moisture, warning when the moisture level reaches a specific value, and wirelessly controlling an additional device (LED or water supply system, etc.). In addition, we report all processes related to wireless irrigation system, including field deployment of sensors, real-time monitoring using a smartphone, data calibration, and control of additional devices deployed in the field by smartphone. A commercially available open-source Internet of Things (IoT) platform, NodeMCU, was used, which was combined with a 9V battery, LED and soil humidity sensor to be integrated into a portable prototype. The IoT-based soil humidity sensor prototype deployed in the field was installed next to a tree for on-site demonstration for the measurement of soil humidity in real-time for about 30 hours, and the measured data was successfully transmitted to a smartphone via Wifi. The measurement data were automatically transmitted via e-mail in the form of a text file, stored on the web, followed by analyses and calibrations. The user can check the humidity of the soil real-time through a personal smartphone. When the humidity of a soil reached a specific value, an additional device, an LED device, placed in the field was successfully controlled through the smartphone. This LED can be easily replaced by other electronic devices such as water supplies, which can also be controlled by smartphones. These results show that farmers can not only monitor the condition of the field real-time through a sensor monitoring system manufactured simply at a low cost but also control additional devices such as irrigation facilities from a distance, thereby reducing unnecessary energy consumption and helping improve agricultural productivity.
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Recent Progress in Dielectric-Based Ultrafast Charging/Discharging Devices
Hyunsu Choi, Jungho Ryu, Woon-ha Yoon, Geon-tae Hwang
J Electr Electron Mater 2022;35(4):322-332.   Published online July 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.4.2
Energy storage capacitors based on dielectric ceramics with superior polarization properties and dielectric constant can provide much higher output power density due to their very fast energy charging/discharging rates, which are particularly suitable for operating pulsed-power devices. For an outstanding energy storage performance of dielectric capacitor, a large recoverable energy density could be derived by introducing a slim polarization-electric field hysteresis loop into dielectric materials by various technical approaches. Many research teams have explored various dielectric capacitor technologies to demonstrate high output power density and ultrafast charging/discharging behavior. This article reviews the recent research progress in high-performance dielectric capacitors for pulsed-power electronic applications.
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Development of Humidity Sensor Based on Ceramic/Metal Halide Composite Films for Non-Contact Biological Signal Monitoring Applications
Tae-ung Park, Ik-soo Kim, Min-ji Kim, Chulhwan Park, Eui-kyoung Seo, Jong-min Oh
J Electr Electron Mater 2022;35(4):412-417.   Published online July 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.4.15
Capacitive-type humidity sensors with a high sensitivity and fast response/recovery times have attracted a great attention in non-contact respiration biological signal monitoring applications. However, complicated fabrication processes involving high-temperature heat treatment for the hygroscopic film is essential in the conventional ceramic-based humidity sensors. In this study, a non-toxic ceramic/metal halide (BaTiO3(BT)/NaCl) humidity sensor was prepared at room temperature using a solvent-free aerosol deposition process (AD) without any additional process. Currently prepared BT/NaCl humidity sensor shows an excellent sensitivity (245 pF/RH%) and superior response/recovery times (3s/4s) due to the NaCl ionization effect resulting in an immense interfacial polarization. Furthermore, the non-contact respiration signal variation using the BT/NaCl sensor was determined to be over 700% by maintaining the distance of 20 cm between the individual and the sensor. Through the AD-fabricated sensor in this study, we expect to develop a non-contact biological signal monitoring system that can be applied to various fields such as respiratory disease detection and management, infant respiratory signal observation, and touchless skin moisture sensing button.
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Development of Variable Vacuum Capacitor with Maximum Voltage of 12 kV and Capacitance of 50 to 500 pF
Youngkwang Cha, Ilhoi Lee, Kibeom Jeon, Jihoon Jang, Heungjin Ju, Seungkil Choi
J Electr Electron Mater 2022;35(3):232-240.   Published online May 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.3.4
A variable vacuum capacitor (VVC), which is a variable element, is used to match impedance in plasma that changes with various impedance values, and its use is expanding with the rapid growth of the semiconductor business. Since VVCs have to secure insulation performance and vary capacitance within a compact size, electrode design and manufacturing are very important; thus, various technologies such as part design and manufacturing technology and vacuum brazing technology are required. In this study, based on the model of an advanced foreign company that is widely used for impedance matching in the manufacture of semiconductors and displays, a VVC that can realize the same performance was developed. The electrode part was designed, the consistency was confirmed through analysis, and the precision of capacitance was improved by designing a cup-type electrode to secure the concentricity of the electrode. As a result of the evaluation, all requirements was satisfied. We believe that self-development will be possible if satisfactory responses are received through evaluation by VVC consumers in the future.
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A Study on the Exothermic Properties of ITO/Ag/ITO Multilayer Transparent Electrode Depending on Metal Layer Thickness
Hye-jin Min, Ye-jina Kang, Hye-won Son, So-hyun Sin, Min-ho Hwang, Hyun-yong Lee
J Electr Electron Mater 2022;35(1):37-43.   Published online January 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.1.6
In this study, we investigated the optical, electrical and exothermic characteristics of ITO/Ag/ITO multilayer structures prepared with various Ag thicknesses on quartz and PI substrates. The transparent conducting properties of the ITO/Ag/ITO multilayer films depended on the thickness of the mid-layer metal film. The ITO/Ag (14 nm)/ITO showed the highest Haccke’s figure of merit (FOM) of approximately 19.3×10-3 Ω-1. In addition, the exothermic property depended on the substrate. For an applied voltage of 3.7 V, the ITO/Ag (14 nm)/ITO multilayers on quartz and PI substrates were heated up to 110℃ and 200℃, respectively. The bending tests demonstrated a comparable flexibility of the ITO/Ag/IT multilayer to other transparent electrodes, indicating the potential of ITO/Ag/ITO multilayer as a flexible transparent conducting heater.
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Condition Monitoring Technique for Heating Cables by Detecting Discharge Signal
Dong-eon Kim, Nam-hoon Kim, Seung-hyun Lim, Gyung-suk Kil
J Electr Electron Mater 2021;34(2):136-141.   Published online March 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.2.10
Heating cables, widely used in office buildings, factories, streets and railways, deteriorate in electrical insulation during operation. The insulation deterioration of heating cables leads to electric discharges that can cause electrical fires. With this background, this paper dealt with a condition monitoring technique for heating cables by the analysis of discharge signals to prevent electrical fires. Insulation deterioration was simulated using an arc generator specified in UL1699 under AC operation, and the characteristic and propagation of discharge signals were analyzed on a 100 meter-long heating cable. Discharge signals produced by insulation deterioration were detected as a voltage pulse because they are as small as a few mV and they are attenuated through propagation path.The frequency spectrum of discharge signals mainly existed in the range from 70 kHz to 110 kHz, and the maximum attenuation of the signal was 84.8% at 100 meters away from the discharge point. Based on the experimental results, a monitoring device, which is composed of a high pass filter with the cut-off frequency of 70 kHz, a comparator, a wave shaper and a microprocessor, was designed and fabricated. Also, an algorithm was designed to discriminate the discharge signal in the presence of noise, compared with the pulse repetition period and the number of pulse counts per 100ms. In the experiment, the result showed that the prototype monitoring device could detect and discriminate the discharge signals produced at every discharge point on a heating cable.
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PLC Optical Sensor for Contamination Monitoring on the Flow-Cell in the Water Quality Measurement System
Seung Heon Han, Tae Un Kim, Haeng Yun Jung, Hyun Chul Ki, Doo Gun Kim, Seon Hoon Kim
J Electr Electron Mater 2019;32(6):472-476.   Published online November 1, 2019
We have proposed a novel planar lightwave circuit (PLC) optical sensor to monitor the contamination in a flow-cell where water is continuously supplied through a water quality measurement system. We designed a PLC chip with a V-shape waveguide and the simulated its function as a sensor for monitoring contamination in a flow-cell using a numerical the FDTD (finite-difference time-domain) analysis. A novel cross type of waveguide was introduced to make the PLC chip of the V-shaped waveguide. The fabricated PLC was cut into the cross waveguide. A change in the optical propagation loss of the PLC sensor was observed after immersing the PLC sensor into city water. It was determined that the propagation loss of the PLC sensor was 3 dB at a wavelength of 1.55 μm in the city water for 15 days.
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A Study on Technologies for Measuring Static Condition of Rigid Conductor System in Railway Electrification
Kyung Min Na, Kiwon Lee, Young Park
J Electr Electron Mater 2019;32(6):507-511.   Published online November 1, 2019
The purpose of an electric railway system contact wire is to supply electric energy to trains through a contacted pantograph. This energy is then converted into mechanical energy. Recent developments in overhead contact lines include the increase in the tension force up to 34 kN according to train speeds that reach up to 400 km/h with a verified safety. Rigid conductor catenary (R-Bar) for high speeds of up to 250 km/h have been developed in tunnels to save on construction costs. This is significant because minor defects in R-bars in aspects, such as height and stagger affect installation conditions. In this study, we propose the use of a detector that measures the static characteristics to reduce the R-bar installation errors. This detector has been developed to measure the height and stagger of the contact wire using video images.
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Investigation on the Excitonic Luminescence Properties of ZnO Bulk Crystal
Jun Seck Choi, Dong Wan Ko, Min Ji Jeong, Sang Tae Lee, Ji Ho Chang
J Electr Electron Mater 2019;32(3):196-200.   Published online May 1, 2019
In this study, photoluminescence (PL) analysis was performed to evaluate the optical properties of commercial ZnO substrates. Particular attention was paid to the bound exciton (BX) luminescence, which is usually the strongest emission intensity of commercial substrates. At 15 K, PL analysis revealed that the BX peak due to donor-type impurities (donor-bound-exciton; DX) dominated, while two-electron satellite (TES) emission, donor-accepter pair (DAP) emission, and LO-phonon replica emission were also observed. The impurity concentration of the ZnO substrate was determined to be 1015 to 1016/cm3 by examination of the temperature variation of DAP, while the half width and intensity change of the luminescence revealed that the temperature change of BX can be interpreted almost the same as the analysis of free-exciton emission.
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Metal Oxide-Based Heterojunction Broadband Photodetector
Sang-eun Lee, Gyeong-nam Lee, Sang-cheol Ye, Sung-ho Lee, Joondong Kim
J Electr Electron Mater 2018;31(3):165-170.   Published online March 1, 2018
In this study, double-layered TCO (transparent conductive oxide) films were produced by depositing two distinct TCO materials: SnO2 works as an n-type layer and ITO (indium-doped tin oxide) serves as a transparent conductor. Both transparent conductive oxide-films were sequentially deposited by sputtering. The electrical and optical properties of single-layered TCO films (SnO2) and double-layered TCO (ITO/SnO2) films were investigated. A TCO-embedding photodetector was realized through the formation of an ITO/SnO2/p-Si/Al layered structure. The remarkably high rectifying ratio of 400.64 was achieved with the double-layered TCO device, compared to 1.72 with the single-layered TCO device. This result was attributed to the enhanced electrical properties of the double-layered TCO device. With respect to the photoresponses, the photocurrent of the double-layered TCO photodetector was significantly improved: 1,500% of that of the single-layered TCO device. This study suggests that, due to the electrical and optical benefits, double-layered TCO films are effective for enhancing the photoresponses of TCO photodetectors. This provides a useful approach for the design of photoelectric devices, including solar cells and photosensors.
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Si Based Photoelectric Device with ITO/AZO Double Layer
Hee-joon Jang, Han-joon Yoon, Gyeong-nam Lee, Joondong Kim
J Electr Electron Mater 2018;31(2):85-89.   Published online February 1, 2018
In this study, functional transparent conducting layers were investigated for Si-based photoelectric applications. Double transparent conductive oxide (TCO) films were deposited on a Si substrate in the sequence of indium tin oxide (ITO) followed by aluminum-doped zinc oxide (AZO). First, we observed that the conductivity and transparency of AZO dominate the overall performance of the double TCO layers. Secondly, the double layered TCO film (consisting of AZO/ITO) deposited by sputtering was compared to a AZO-only film in terms of their optical and electrical properties. We prepared three different AZO films: ITO:3min/AZO:10min, ITO:5min/AZO:7min, and ITO:7min/AZO:4min. The results show that the optical properties (transmittance, absorbance, and reflection) can be controlled by the film composition. This may provide a significant pathway for the manipulation of the optical and electrical properties of photoelectric devices.
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