Multilayer ceramic batteries (MLCBs) have attracted increasing attention as compact all-solid-state energy-storage devices that can be manufactured using multilayer ceramic processing technologies. In this study, an MLCC-compatible fabrication process for oxide-based MLCBs was developed using Li₁₊ₓAlₓTi₂₋ₓ(PO₄)₃ (LATP) solid electrolytes, Li₃V₂(PO₄)₃ (LVP) cathodes, and Cu current collectors. Commercial LATP powders were evaluated in terms of particle-size distribution, phase purity, thermal stability, and ionic conductivity. The selected LATP powder was subsequently employed for tape-cast green-sheet fabrication, and the effects of polyvinyl butyral (PVB) binder content on slurry rheology and sheet microstructure were investigated. An optimized binder composition containing 11 wt% PVB (BM-2/BH-3 = 3:7) provided improved processability and microstructural uniformity. Drying conditions during sequential electrode printing were also optimized to suppress sheet warpage and improve multilayer registration. Thermogravimetric and differential thermal analyses (TG–DTA) were used to establish an optimized two-step debinding and co-firing process under a controlled reducing atmosphere. The resulting multilayer structures exhibited uniform densification without significant blistering, delamination, or interfacial defects. Charge–discharge measurements confirmed that electrochemical functionality was retained after the complete manufacturing process, yielding a discharge capacity of approximately 2.5–2.7 μAh.

The effects of BaZrO₃ addition on the structural and electrical properties of BaTiO₃-based base-metal-electrode (BME) multilayer ceramic capacitor (MLCC) ceramics were investigated. Dielectric compositions containing 0–9 wt% BaZrO₃ were fabricated using a conventional MLCC process, and their crystal structure, dielectric behavior, temperature stability, frequency stability, and insulation resistance were evaluated. X-ray diffraction and Rietveld refinement confirmed the formation of a single-phase perovskite structure for all compositions. Increasing BaZrO₃ content resulted in a systematic shift of diffraction peaks toward lower angles and an increase in unit-cell volume from 64.61 to 66.05 ų, indicating successful Zr incorporation into the BaTiO₃ lattice. The dielectric permittivity increased with BaZrO₃ addition and reached a maximum value of approximately 2,110 at 6 wt%, while dielectric loss decreased significantly. Capacitance stability against temperature and frequency variations was markedly improved with increasing BaZrO₃ content. In addition, insulation resistance increased substantially over the investigated temperature range, demonstrating enhanced electrical reliability.