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"Precursor"

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"Precursor"

Physical Properties of Mg0.05Zn0.95O Thin Films Grown by Sol-Gel Method According to Types of Indium Precursors
Hyo Jin Choi, Min Sang Lee, Hong Seung Kim, Hyung Soo Ahn, Nak Won Jang
J Electr Electron Mater 2021;34(4):256-261.   Published online July 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.4.6
Indium-doped Mg0.05Zn0.95O thin films were deposited on glass substrates by a sol-gel method. Three types of indium precursors such as indium chloride, indium acetate, and indium nitrate were used as doping sources. Physical properties of fabricated thin films were analyzed through XRD (x-ray diffraction), UV-vis spectrophotometer, Hall effect measurement, and EDS (energy dispersive x-ray spectroscopy). All In-doped thin films grown in this study exhibited a preferred orientation of (002) with over 80% transmittance. The results showed that the Mg0.05Zn0.95O thin film from indium chloride as the indium precursor has higher crystallinity and transmittance with lower resistivity when compared with those from other indium precursors.
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Growth of Organic/Inorganic MAPbI3 Perovskite Thin Films via Chemical Vapor Deposition
Jang-su Jung, Jiho Eom, S. V. N Pammi, Soon-gil Yoon
J Electr Electron Mater 2020;33(4):315-320.   Published online July 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.4.12
Methylammonium lead iodide (MAPbI3) thin films were grown at low temperatures on glass substrates via 3-zone chemical vapor deposition. Lead iodide (PbI2) and lead bis (dipivaloylmethanate) [Pb(dpm)2] precursors were used as lead sources. Due to the high sublimation temperature (~400℃) of the PbI2 precursor, a low substrate temperature could not be constantly maintained. Therefore, MAPbI3 thin films degraded into the PbI2 phase. In contrast, for the Pb(dpm)2 precursor, a substrate temperature of ~120℃ was maintained because the sublimation temperature of Pb(dpm)2 is as low as 130℃ at a high vapor pressure. As a result, high-quality MAPbI3 thin films were successfully grown on glass substrates using Pb(dpm)2. The rms (root-mean-square) roughness of MAPbI3 thin films formed from Pb(dpm)2 was as low as ~19.2 nm, while it was ~22.7 nm for those formed using PbI2. The grain size of the films formed from Pb(dpm)2 was as large as approximately 350 nm.
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The Effect of Mg Precursors on Optical and Structural Characteristics of Sol-Gel Processed Mg0.3Zn0.7O Thin Films
Ahram Yeom, Hong Seung Kim, Nak Won Jang, Young Yun, Hyung Soo Ahn
J Electr Electron Mater 2020;33(3):214-218.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.10
In this study, MgxZn1-xO thin films, which can be applied not only to active layers of light-emitting devices (LEDs), such as UV-LEDs, but also to solar cells, high mobility field-effect transistors, and power semiconductor devices, are fabricated using the sol-gel method. ZnO and Mg0.3Zn0.7O solution synthesized by the sol-gel method and the thin film were grown by spin coating on a Si (100) substrate and sapphire substrate. The solutions are synthesized by dissolving precursor materials in 2-methoxyethanol (2-ME) solvent, and then monoethanolamine (MEA) was added to the mixed solution as a sol stabilizer. Zinc acetate dihydrate is used as a ZnO precursor, while Mg nitrate hexahydrate and Mg acetate tetrahydrate are used as an MgO precursor. Then, the optical and structural characteristics of the fabricated thin films are compared. The molar concentration of the Zn precursor in the solvent is fixed at 0.3 M, and the amount of the Mg precursor is 30% of Mg2+/Zn2+. The optical characteristics are measured using an UV-vis spectrophotometer, and the transmittance of each wavelength is measured. Structural characteristics are measured using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Composition analyses are performed using energy dispersive X-ray spectroscopy (EDS). The Mg0.3Zn0.7O thin film was well formed at the ratio of the Mg precursor added regardless of the type of Mg precursor, and the c-axis of the thin film was decreased, while the band gap was increased to 3.56 eV.
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Synthesis and Characterization of Rod-Shaped Ni-Zn Ferrite Particles
Seung-yeop Chun, Jin-ah Hwang, Myoung-pyo Chun
J Electr Electron Mater 2018;31(5):300-306.   Published online July 1, 2018
The rod-shaped Ni0.5Zn0.5Fe2O4 particles were synthesized via a topotactic reaction, in which goethite (α-FeOOH) particles are the main constituents. The phases, microstructures and magnetic properties of these particles were studied using XRD, FE-SEM and VSM. The precursor solution consisted of NiSO4·xH2O, ZnSO4·xH2O, goethite and D.I. water werereacted at four different temperatures (50, 70, 90, 100℃) to generate four differently precipitated particles respectively. During the co-precipitation reaction, the pH of the solution was maintained at 8.0 using NaOH. The particles coprecipitated and calcined at a temperature of 700℃, exhibited a rod-shape similar to its original goethite, which means that the shape of Ni-Zn ferrite particles can be topotactically controlled by the goethite. The particles synthesized at 70 and 90℃ have a saturation magnetization of 29 and 35 emu/g respectively; representing better values than the ones synthesized at the 50 and 100℃, in which some second phases such as Fe2O3 were observed.
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Characterization of LiNi(1/3)Co(1/3)Mn(1/)3O2 Cathode Materials Prepared from Different Precursors in Lithium Rechargeable Batteries
Sung Keun Kim, Sung Wan Hong, Kyeong Sik Han, Hong Ki Lee, Joong Pyo Shim
J Electr Electron Mater 2008;21(11):1029-1035.   Published online November 1, 2008
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Properties of SiOCH Thin Film Dielectric constant by BTMSM/O2 Flow Rates
Jong Wook Kim, Chang Su Hwang, Hong Bae Kim
J Electr Electron Mater 2008;21(4):362-367.   Published online April 1, 2008
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Influence of Precursor Solution Coating Parameters on Ferroelectric Properties of Pb(Zr(0.7),Ti(0.3))O3 Thick Films
J Electr Electron Mater 2006;19(12):1092-1098.   Published online December 1, 2006
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Effect of Composition and Coating of Precursor Solution on a Micro Structural Properties of PZT Thick Films
J Electr Electron Mater 2006;19(11):1014-1019.   Published online November 1, 2006
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