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Research Article

Regular Paper

Effect of APS Dip-Coating Time on Interfacial Charge Transport in Dye-Sensitized Solar Cells
Jin Wook Lee, Minjae Shin, Byungyou Hong, Hyung Jin Kim
J Electr Electron Mater 2026;39(4):387-393.   Published online July 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.4.8
Dye-sensitized solar cells (DSSCs) suffer from efficiency limitations due to interfacial charge recombination at the TiO₂/dye/electrolyte interface. In this study, aminopropyltrimethoxysilane (APS) was introduced onto nanoporous TiO₂ photoelectrodes via a dip-coating process with controlled coating times to investigate the effect of silanization time on interfacial charge transport behavior. Unlike concentration-driven structural modification, this work focuses on the evolution of the APS-modified interface governed by reaction time. The DSSC with 30 min APS treatment exhibited the highest power conversion efficiency of 5.34%, representing a 19% enhancement compared to the untreated device (4.49%), mainly due to increased short-circuit current density and open-circuit voltage. However, prolonged coating times (2 h and 24 h) resulted in a significant decrease in photocurrent density, leading to reduced device performance despite partial improvement in recombination resistance. These results are attributed to the time-dependent evolution of the APS interfacial layer. At moderate coating time, APS provides effective surface functionalization, enhancing dye adsorption and suppressing interfacial recombination. In contrast, prolonged coating is expected to induce increased surface coverage and silane condensation, which can hinder electron injection and increase charge transport resistance. Therefore, the photovoltaic performance is governed by a trade-off between recombination suppression and charge injection efficiency, controlled by the silanization time. This study highlights the critical role of interfacial reaction kinetics in determining charge transport behavior and provides an effective strategy for optimizing DSSC performance through time-dependent interface engineering.
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Review Paper

Tutorial Status Report

Wearable temperature sensors are becoming increasingly important for continuous health monitoring, personalized healthcare, and biointegrated electronic systems. However, conventional temperature-sensing platforms often suffer from limited thermal sensitivity, insufficient mechanical compliance, and unstable performance under repeated deformation, making it difficult to detect subtle physiological temperature variations in real time. Here, this tutorial status report presents a fabrication strategy for highly sensitive wearable temperature sensors based on gold-doped crystalline silicon nanomembranes. Gold diffusion into crystalline silicon introduces deep-level impurity states that modulate the Fermi level and shift the freeze-out region toward the physiological temperature range, enabling an ultrahigh negative temperature coefficient of resistance. By integrating the gold-doped silicon nanomembrane with a polyimide-supported ultrathin platform, neutral mechanical plane design, and serpentine mesh interconnects, the resulting device can provide high thermal sensitivity, fast response, conformal skin attachment, and stable operation under mechanical deformation. This fabrication approach is expected to broaden the use of impurity-engineered silicon nanomembranes in next-generation wearable sensors, flexible bioelectronics, and multifunctional healthcare monitoring systems.
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Research Article

Regular Paper

Enhanced Photoluminescence of CsPbBr3 via Improved Optical Transparency of Thermally Treated GaN Nanowires
Kwang Jae Lee, Jungwook Min
J Electr Electron Mater 2026;39(3):272-280.
Published online May 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.3.6
GaN nanowire (NW)-based hybrid structures have attracted attention for optoelectronic applications due to their high surface area and efficient carrier transport. However, the optical transparency of GaN NWs is often limited by unintended residual species accumulated on the surface and in the inter-wire regions, as well as defect-related absorption, leading to reduced light transmission. In this work, we demonstrate that thermal annealing significantly improves the optical transparency of GaN NWs grown on indium tin oxide (ITO)/glass substrates. The transmittance increased from 47.9% to 78.5% at 550 nm after rapid thermal annealing at 800oC for 3 min, while a comparable value (~75.5%) was achieved at 600oC for 5 min. PbBr3 was deposited onto the GaN NWs to form hybrid structures, and temperature-dependent photoluminescence (TDPL) measurements revealed enhanced emission stability with suppressed peak shift and reduced spectral broadening. Arrhenius analysis based on a two-channel model revealed that the activation energy of the dominant non-radiative recombination pathway increased from 62 meV in the as-grown sample to 85 meV after thermal annealing, while its relative contribution remained nearly unchanged. In contrast, the shallow trap-assisted pathway exhibited a similar activation energy of approximately 6 meV in both samples, but its contribution decreased from 0.35 to 0.17 after annealing. As a result, the internal quantum efficiency (IQE) improved from 75.9% to 87.4%. These results show that thermal annealing improves optical transparency by removing residuals and suppresses defect-related recombination, leading to enhanced carrier dynamics and improved optical performance of PbBr3-based hybrid structures.
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3D-Printed Liquid Metal Electrodes for Deformable Electronic Circuit
Jong Jun Jung, Sang Yoon Park, Se Jin Choi, Yu Jin Ko, Haneol Lee
J Electr Electron Mater 2026;39(1):103-109.   Published online January 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.1.13
Flexible and wearable electronics, which require stable operation under mechanical deformation, are increasingly utilizing Eutectic Gallium-Indium (EGaIn) for their conductive components. This study presents a systematic approach to fabricating highly reliable, deformable electrodes via a direct-ink-writing (DIW) 3D printing process using EGaIn as the functional ink. We conducted a thorough optimization of key printing parameters, specifically the extrusion pressure and printing speed, to achieve stable and uniform conductive lines. Through this optimization, we successfully established an optimal process window, achieving a stable line width of approximately 130 μm at an extrusion pressure of 300 kPa and a printing speed of 16 mm/s. The fabricated flexible electrodes exhibited exceptional electromechanical stability, maintaining negligible resistance change (< 0.82%) both under severe bending (3 mm radius) and after 100 repetitive bending cycles. This work demonstrates that the 3D printing of EGaIn is a viable and effective method for creating robust, high-performance electrodes for the next generation of deformable and wearable electronic devices.
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Cathodoluminescence (CL) spectroscopy provides valuable insights into the optical and electronic properties of materials by analyzing photon emission induced by electron beam excitation. In this study, we present a novel CL detection system integrated into a transmission electron microscope (TEM) specimen stage, enabling high-resolution optical analysis of internal microstructures. The system features a parabolic mirror, a focusing lens, and a UV-VIS range optical fiber to maximize light collection and transmission efficiency, with performance further enhanced by a liquid nitrogen cooling setup. Using this system, we successfully performed CL mapping of InGaN/GaN multiple quantum wells (MQWs) and GaN thin films. The results revealed that threading dislocations act as non-radiative centers in GaN and locally increase the bandgap energy in InGaN MQWs, causing a blue-shift in CL emission. These findings support a model in which dislocations induce carrier delocalization, preserving high radiative efficiency despite high dislocation densities. This work demonstrates the effectiveness of the TEM-integrated CL system for nanoscale optical characterization, offering a new pathway for studying defect-related phenomena in semiconductor materials.
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The mounting demand for sustainable, self-powered biomedical devices, particularly those engineered for extreme environments, has established triboelectric nanogenerators (TENGs) as a prominent technology in energy harvesting research. This review examines state-of-the-art biomaterial synthesis strategies essential for developing high-performance bioelectronic TENGs that can operate reliably under harsh conditions, including elevated temperatures, extreme humidity, and mechanical strain. It begins with a comprehensive overview of the fundamental principles of triboelectricity and subsequently addresses the pivotal challenges associated with efficient charge generation and retention in such challenging settings. The content places particular emphasis on recent advancements in composite material engineering and structure design for high-efficiency mechanisms, with a particular focus on biocompatible and environmentally resilient materials. The integration of TENGs into wearable sensors, implantable devices, and self-powered monitoring systems is also investigated, demonstrating their transformative potential for bioelectronic applications. Our goal subsequently underscores persistent limitations to overcome, including those pertaining to fabrication scalability and long-term operational stability, while concurrently proposing prospective research directions. Consequently, this work underscores how innovative biomaterial synthesis and bioelectronic devices can enable the development of next-generation, high-performance, self-powered devices suited for extreme biomedical environments.
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Deformable Heat-Dissipation Materials for Smart E-Skin
Lee Kyung Bae, Moon Kee Choi
J Electr Electron Mater 2025;38(1):21-32.   Published online January 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.1.3
Smart electronic skin (E-skin) is an emerging technology that integrates electronic devices with human skin, enhancing human-machine interactions. One critical challenge in its development is effective thermal management to ensure device reliability, longevity, and user comfort. This review highlights passive cooling techniques - thermal conduction, convection, radiation, and phase-change materials - as key strategies to address this challenge without additional power consumption. These integrated mechanisms have demonstrated the ability to efficiently dissipate heat, preventing thermal buildup and maintaining optimal performance in E-skin devices. Recent advancements indicate that combining these methods can significantly enhance the thermal management of flexible electronics. Future research should focus on refining these materials and techniques to overcome challenges related to cost, durability, and environmental stability, thereby advancing the practical application of E-skin technology.
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A Review of Electronic Devices Based on Halide Perovskite Materials
Hyeong Gi Park, Jungyup Yang
J Electr Electron Mater 2024;37(5):519-526.   Published online September 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.5.8
This review examines the use of halide perovskite materials in electronic devices, highlighting their exceptional optoelectronic properties and the challenges associated with them. Despite their potential for high-performance devices, practical applications are limited by sensitivity to environmental factors such as moisture and oxygen, etc. We discuss advances in enhancing stability and operational reliability, featuring innovative synthesis methods and device engineering strategies that help mitigate degradation. Furthermore, we explore the integration of perovskites in applications such as field-effect transistors and LEDs, emphasizing their transformative potential. This review also outlines future research directions, stressing the need for ongoing improvements in material stability and device integration to fully realize the commercial potential of perovskites.
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Development of Three-Dimensional Deformable Flexible Printed Circuit Boards Using Ag Flake-Based Conductors and Thermoplastic Polyamide Substrates
Aram Lee, Minji Kang, Do Young Kim, Hee Yoon Jang, Ji-won Park, Tae-wook Kim, Jae-min Hong, Seoung-ki Lee
J Electr Electron Mater 2024;37(4):420-426.   Published online July 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.4.9
This study proposes an innovative methodology for developing flexible printed circuit boards (FPCBs) capable of conforming to three-dimensional shapes, meeting the increasing demand for electronic circuits in diverse and complex product designs. By integrating a traditional flat plate-based fabrication process with a subsequent three-dimensional thermal deformation technique, we have successfully demonstrated an FPCB that maintains stable electrical characteristics despite significant shape deformations. Using a modified polyimide substrate along with Ag flake-based conductive ink, we identified optimized process variables that enable substrate thermal deformation at lower temperatures (~130℃) and enhance the stretchability of the conductive ink (ε ~30%). The application of this novel FPCB in a prototype 3D-shaped sensor device, incorporating photosensors and temperature sensors, illustrates its potential for creating multifunctional, shape-adaptable electronic devices. The sensor can detect external light sources and measure ambient temperature, demonstrating stable operation even after transitioning from a planar to a three-dimensional configuration. This research lays the foundation for next-generation FPCBs that can be seamlessly integrated into various products, ushering in a new era of electronic device design and functionality.
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Solution-Processed Indium-Gallium Oxide Thin-Film Transistors for Power Electronic Applications
Se-hyun Kim, Jeong Min Lee, Daniel Kofi Azati, Min-kyu Kim, Yujin Jung, Kang-jun Baeg
J Electr Electron Mater 2024;37(4):400-406.   Published online July 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.4.6
Next-generation wide-bandgap semiconductors such as SiC, GaN, and Ga2O3 are being considered as potential replacements for current silicon-based power devices due to their high mobility, larger size, and production of high-quality wafers at a moderate cost. In this study, we investigate the gradual modulation of chemical composition in multi-stacked metal oxide semiconductor thin films to enhance the performance and bias stability of thin-film transistors (TFTs). It demonstrates that adjusting the Ga ratio in the indium gallium oxide (IGO) semiconductor allows for precise control over the threshold voltage and enhances device stability. Moreover, employing multiple deposition techniques addresses the inherent limitations of solution-processed amorphous oxide semiconductor TFTs by mitigating porosity induced by solvent evaporation. It is anticipated that solution-processed indium gallium oxide (IGO) semiconductors, with a Ga ratio exceeding 50%, can be utilized in the production of oxide semiconductors with wide band gaps. These materials hold promise for power electronic applications necessitating high voltage and current capabilities.
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Formation of Metal Mesh Electrodes via Laser Plasmonic Annealing of Metal Nanoparticles for Application in Flexible Touch Sensors
Seongmin Jeong, Yun Sik Hwang, Yu Mi Woo, Yong Jun Cho, Chan Hyeok Kim, Min Gi An, Ho Seok Seo, Chan Hyeon Yang, Kwi-il Park, Jung Hwan Park
J Electr Electron Mater 2024;37(2):223-229.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.15
Laser-induced plasmonic sintering of metal nanoparticles (NPs) holds significant promise as a technology for producing flexible conducting electrodes. This method offers immediate, straightforward, and scalable manufacturing approaches, eliminating the need for expensive facilities and intricate processes. Nevertheless, the metal NPs come at a high cost due to the intricate synthesis procedures required to ensure long-term reliability in terms of chemical stability and the prevention of NP aggregation. Herein, we induced the self-generation of metal nanoparticles from Ag organometallic ink, and fabricated highly conductive electrodes on flexible substrates through laser-assisted plasmonic annealing. To demonstrate the practicality of the fabricated flexible electrode, it was configured in a mesh pattern, realizing multi-touchable flexible touch screen panel.
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Flash Lamp Annealing of Ag Organometallic Ink for High-Performance Flexible Electrode
Yu Mi Woo, Dong Gyu Lee, Yun Sik Hwang, Jae Chan Heo, Seongmin Jeong, Yong Jun Cho, Kwi-il Park, Jung Hwan Park
J Electr Electron Mater 2023;36(5):454-462.   Published online September 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.5.4
Flash lamp annealing (FLA) of metal nanoparticle (NP) ink has provided powerful strategies to fabricate highperformance electrodes on a flexible substrate because of its rapid processing capability (in milliseconds), low-temperature process, and compatibility with to roll-to-roll process. However, metal NPs [e.g., gold (Au), silver (Ag), copper (Cu), etc.] have limitations such as difficulty in synthesizing fine metal NPs (diameter less than 10 nm), high price, and degradation during ink storage and FLA processing. In this regard, organometallic ink has been proposed as a material that can replace metal NPs due to their low-cost (usually 1/100 times cheaper than metal nano inks), low-temperature processability, and high material stability. Despite these advantages, the fabrication of flexible electrodes through FLA treatment of organometallic compounds has not been extensively researched. In this paper, we experimentally guide how to determine the optimal conditions for forming electrodes on flexible substrates by considering material parameters, and flashlight processing parameters (energy density, pulse duration, etc) to minimize the difficulties that may arise during the FLA of organometallic ink.
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Introduction to Cathodoluminescence Spectroscopy Using Scanning Transmission Electron Microscopy
Sung-dae Kim
J Electr Electron Mater 2023;36(4):326-331.   Published online July 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.4.2
The utilization of scanning transmission electron microscopy (STEM) in conjunction with cathodoluminescence (CL) has emerged as a valuable tool for the investigation of material optical properties. In recent years, this technique has facilitated significant advancements in the fields of plasmonics and quantum emitters by surpassing prior technical restrictions. The review commences by providing an outline of the diverse STEM-CL operating modes and technical aspects of the instrumentation. The review explains the fundamental physics of light production under electron beam irradiation and the physical basis for interpreting STEM-CL experiments for different types of excitations. Additionally, the review compares STEM-CL to other related techniques such as scanning electron microscope CL, photoluminescence, and electron energy-loss spectroscopy.
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Laser-Induced Recrystallization of Perovskite Materials for High-Performance Flexible Light-Emitting Diode
Jae Chan Heo, Ji Eun Kim, Dong Gyu Lee, Yun Sik Hwang, Yu Mi Woo, Han Eol Lee, Jung Hwan Park
J Electr Electron Mater 2023;36(3):286-291.   Published online May 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.3.12
Perovskite materials are promising candidates for next-generation optoelectronic devices owing to their outstanding external quantum efficiency, high color purity, and ability to tune the light emission wavelength. However, conventional thermal annealing processes caused the degradation of perovskite, resulting in poor optoelectronic properties and a short lifetime. Herein, we propose a laser-induced recrystallization of perovskite thin film to enhance its light-emitting properties. Laser-induced recrystallization process was performed using rapid and instantaneous laser heating, which successfully induced grain growth of the perovskite material. The laser processing conditions were thoroughly optimized based on theoretical calculations and various material analyses such as x-ray diffraction, scanning electron microscope, and photoluminescence spectroscopy.
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Frequency Analysis and Reduction of Electronic Noise in ESS
Bong Man Ahn, Byoung Sung Han, Un Ki Han, Young Kwan Lee, Hyun Jin An
J Electr Electron Mater 2022;35(6):568-575.   Published online November 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.6.5
This paper is a study on frequency analysis and electronic noise reduction of energy storage system (ESS). We acquired 4 necessary data for about 2 minutes and 4 seconds using a sampling frequency of 10,000 Hz in ESS. Fast Fourier transform (FFT) was used for electronic noise analysis from the acquired data. As a result, it was confirmed that DC component, fundamental wave, second and higher harmonic component exist. For the attenuation of harmonics, low-pass filter (LPF) was applied. We confirmed that an attenuation of approximately 59.3% appears from the second harmonic. The presence of many harmonic components in the data of the ESS was expected to occur due to the insufficiency of optimization among the modules inside the ESS. Therefore, we propose that a national certification system for ESS should be introduced to settle down the issue properly.
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Synthesis and Characterization of Triptycene-Based Triphenylamine Electron Donor Molecules
Youngjun Ryu, Byeong-kwan An
J Electr Electron Mater 2022;35(4):359-365.   Published online July 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.4.7
The development of efficient electron donor (or hole-transporting) molecules that can be used in various optoelectronic device fields is highly demanded. In this work, a novel class of triptycene-based three-dimensional (3D) triphenylamine (TI-TPA) derivatives with different end substituents was designed and prepared for transparent electron donor materials. Owing to the rigid 3D triptycene framework, the obtained TI-TPA derivatives had an amorphous morphology with high thermal decomposition temperature. The oxidation potential of these TI-TPA derivatives decreased as the electron donating strength of the end substituent increased. Among TI-TPA derivatives, TI-TPA-OMe exhibited the highest HOMO level (-5.31 eV) which is similar to that of Spiro-OMeTAD (-5.22 eV). In addition, TI-TPA-OMe was found to form a strong charge transfer complex with the triptycene-based acceptor TI-BQ, leading to a new absorption band at around 640 nm. These results can be applied for developing efficient electron donor materials that can mimic the advantages of the spiro-linked structure and TPA units of Spiro-OMeTAD.
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Design and Fabrication of an Electronic Voltage Transformer (EVT) Embedded in a Spacer of Gas Insulated Switchgears
Seung-hyun Lim, Nam-Hoon Kim, Dong-eon Kim, Seon-gyu Kim, Gyung-suk Kil
J Electr Electron Mater 2022;35(4):353-358.   Published online July 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.4.6
Bulky iron-core potential transformers (PT) are installed in a tank of gas insulated switchgears (GIS) for a system voltage measurement in power substations. In this paper, we studied an electronic voltage transformer (EVT) embedded in a spacer for miniaturization, eco-friendliness, and performance improvement of GIS. The prototype EVT consists of a capacitive probe (CP) that can be embedded in a spacer and a voltage Follower with a high input and a low output impedance. The CP was fabricated in the form of a Flexible-PCB to acquire the insulation performance and to withstand vibration and shock during operation. Voltage ratio of the prototype EVT is about 42,270, and the frequency bandwidth of -3 dB ranges from 0.33 Hz to 3.9 MHz. The voltage ratio error evaluated at about 6%, 12% and 18% of the rated voltage of 170 kV was 0.32%, and the phase error was 12.9 minutes. These results were within the accuracy for the class 0.5 specified in IEC 60044-7 and satisfy even in ranges from 80% to 120% of the rated voltage. If the prototype EVT replaces the conventional iron-core potential transformer, it is expected that the height of the GIS could be reduced by 11% and the amount of SF6 will be reduced by at least 10%.
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Practical Guide to X-ray Spectroscopic Data Analysis
Jae-hyeon Cho, Wook Jo
J Electr Electron Mater 2022;35(3):223-231.   Published online May 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.3.3
Spectroscopies are the most widely used for understanding the crystallographic, chemical, and physical aspects of materials; therefore, numerous commercial and non-commercial software have been introduced to help researchers better handling their spectroscopic data. However, not many researchers, especially early-stage ones, have a proper background knowledge on the choice of fitting functions and a technique for actual fitting, although the essence of such data analysis is peak fitting. In this regard, we present a practical guide for peak fitting for data analysis. We start with a basic-level theoretical background why and how a certain protocol for peak fitting works, followed by a step-by-step visualized demonstration how an actual fitting is performed. We expect that this contribution is sure to help many active researchers in the discipline of materials science better handle their spectroscopic data.
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Recent Progress of Light-Stimulated Synapse and Neuromorphic Devices
Seungho Song, Jeehoon Kim, Yong-hoon Kim
J Electr Electron Mater 2022;35(3):215-222.   Published online May 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.3.2
Artificial neuromorphic devices are considered the key component in realizing energy-efficient and brain-inspired computing systems. For the artificial neuromorphic devices, various material candidates and device architectures have been reported, including two-dimensional materials, metal-oxide semiconductors, organic semiconductors, and halide perovskite materials. In addition to conventional electrical neuromorphic devices, optoelectronic neuromorphic devices, which operate under a light stimulus, have received significant interest due to their potential advantages such as low power consumption, parallel processing, and high bandwidth. This article reviews the recent progress in optoelectronic neuromorphic devices using various active materials such as two-dimensional materials, metal-oxide semiconductors, organic semiconductors, and halide perovskites
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Fabrication of the Solution-Derived BiAlO Thin Film by Using Brush Coating Process for Liquid Crystal Device
Ju Hwan Lee, Dai-hyun Kim
J Electr Electron Mater 2021;34(5):321-326.   Published online September 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.5.7
We fabricated BiAlO thin film by a solution process with a brush coating to be used as liquid crystal (LC) alignment layer. Solution-processed BiAlO was coated on the glass substrate by brush process. Prepared thin films were annealed at different temperatures of 80℃, 180℃, and 280℃. To verify whether the BiAlO film was formed properly, X-ray photoelectron spectroscopy analysis was performed on Bi and Al. Using a crystal rotation method by polarized optical microscopy, LC alignment state was evaluated. At the annealing temperature of 280℃, the uniform homogenous LC alignment was achieved. To reveal the mechanism of LC alignment by brush coating, field emission scanning electron microscope was used. Through this analysis, spin-coated and brush coated film surface were compared. It was revealed that physical anisotropy was induced by brush coating at a high annealing temperature. Particles were aligned in one direction along which brush coating was made, resulting in a physical anisotropy that affects a uniform LC alignment. Therefore, it was confirmed that brush coating combined with BiAlO thin film annealed at high temperature has a significant potential for LC alignment.
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A Study on Dielectric Properties of Flame-Retardant Silicone Rubber Due to Silica Amount Change
Sung Ill Lee
J Electr Electron Mater 2021;34(5):364-370.   Published online September 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.5.14
In this study, the dielectric properties of flame retardant silicone rubber mixed with the amount of silica 50~65 phr were measured at frequencies ranging from 1 to 2.7 MHz and temperature ranges from 30℃ to 160℃. The permittivity decreased with higher frequencies and higher temperatures, and tanδ are thought to have decreased due to the increased heat oxidation of the methyl group bound to Si, which increased the hardness of silicone rubber. FT-IR analysis of specimen mixed with SiO2 of 50~65 phr showed oscillations of OH groups bound to SiO2 between wavenumber 3,600 and 3,300. As a result of analyzing surface components by Energy Dispersive X-ray (EDX) on all specimens mixed with SiO2 of 50 to 65 phr, all specimens contained Si, and the analysis by field emission scanning electron (FE-SEM) confirmed that about 1~5 μm particles were distributed regularly on the surface of the specimens.
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Next-Generation Biomedical Devices via MicroLEDs
Han Eol Lee
J Electr Electron Mater 2021;34(4):221-228.   Published online July 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.4.1
With the advent of the IoT (internet of things) era, there has been discussion on how to efficiently use various information from daily life. In academic and industrial society, various smart devices such as smart watches, smart phones, and smart glasses have been developed and commercialized for narrowing the physical/psychological distance with user information. According to recent developments of smart devices, the contemporary people have desired to check their body information and treat disease by themselves. According to the needs of the time, biological researches by phototherapy/monitoring have been actively conducted. Among various light sources, microLEDs have been spotlighted due to their superior optoelectric properties and stability. In this paper, we would like to review the state-of-the research results on the next-generation biological therapy devices via microLEDs.
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In this study, solder joints mixed with graphene-nanosheets (GNSs) were investigated for the manufacture of highly reliable electronic devices. In order to analyze the effect of adding GNSs, experiments were performed by adding various amounts of GNSs (0.01, 0.05, 0.1, 0.3, 0.5 wt%). To compare and analyze the properties of the solder joints to which GNSs were added, shear forces were measured, and cross-sectional observation was performed. The bonding strength of the solder joints containing 0.05% GNSs was the highest, and the bonding strength of the solder joints with higher GNSs contents did not increase. This is because, as the content of GNSs increases, the viscosity of the solder paste also increases; therefore, the solder paste detachability from the metal mask was lowered and a sufficient amount was not applied. In addition, due to the high content of GNSs, the fluidity of solder powder and paste decreased, resulting in defects in the shape of the solder joint. Therefore, the optimal GNSs content in this study was 0.05%, and studies for optimal viscosity should be continued.
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For electronic paper displays using electrophoresis, the response time and reflectivity of the image panel fabricated by filtering are analyzed. For the filtering process, a square wave and ramp wave are applied to white charged particles with a unique q/m value. We divide the sample panels into #1 to #4 according to the applied waveform in the filtering process. Step waves comprising two steps are used to drive the panel; therefore, we divide the driving conditions into D1~D4. The applied voltage at the first stage of the half cycle of the driving waveform moves the charged particles attached via the image force from the electrode, and the applied voltage at the second stage moves the floating charged particles by detaching. As mentioned, four types of driving conditions (D1 to D4) classified according to the half cycle of the driving waveform are applied to the samples #1 to #4), which are classified according to four types of filtering process. When driving condition D1 is applied to the four types of sample panels, the rise time of #1 is 1.59s, #2 is 1.706s, #3 is 1.853s, and #4 is 1.235s, resulting in #4 being relatively faster compared with other sample panels, and showing the same trend in other driving conditions. As a result, we confirm that applying the driving condition D1 causes abrupt movement of the white charged particles injected into the cell. When the same driving waveform (D1) is applied to each sample, reflectivities of 32.1% for #1, 31.4% for #2, 27.9% for #3, and 63.4% for #4 are measured. From the experiment, we confirm that the driving condition D1 (1s of 3.5 V, 9s of 3.0 V) and ramp wave #4 in filtering are desirable for good reflectivity and response time. Our research is expected to contribute to the improvement of the filtering process and optimization of the driving waveform.
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Analysis on Current Characteristics According to Injection Method and Driving Waveform in Electrophoretic-Type E-Paper Display
Joo-won Lee, Young-cho Kim
J Electr Electron Mater 2020;33(5):386-392.   Published online September 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.5.9
In this study, the drift current characteristics of charged particles are analyzed for panels fabricated by varying the waveform biasing of the active particle loading method (APLM), which is a method driven by the electrophoretic principle of loading charged particles into a cell of a barrier rib-type electronic paper. We prepare 3 panels using APLM and 1 panel without APLM. The waveform of APLM uses square wave and ramp wave, and the step voltage wave is applied to the driving voltage. The drift currents measured from the square wave and ramp wave with the same period applied by APLM are 4.872 μC and 5.464 μC, respectively, and the ramp wave is shown to be relatively advantageous for loading charged particles that have a large q/m. The time–current curve results confirm that the abrupt movement of charged particles is occurring. When the step form wave signal with a short time of 1s is first applied, initial large movement of the charged particles is confirmed to occur in all samples, which is understood as the effect of applying the voltage necessary to remove the imaging force. The results of this study are expected to improve the loading of charged particles into the electronic paper cell, driven by the electrophoretic principle and optimization of the driving conditions.
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Focused Electron Beam-Controlled Graphene Field-Effect Transistor
Songkil Kim
J Electr Electron Mater 2020;33(5):360-366.   Published online September 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.5.5
Focused electron beams with high energy acceleration are versatile probes. Focused electron beams can be used for high-resolution imaging and multi-mode nanofabrication, in combination with, molecular precursor delivery, in an electron microscopy environment. A high degree of control with atomic-to-microscale resolution, a focused electron beam allows for precise engineering of a graphene-based field-effect transistor (FET). In this study, the effect of electron irradiation on a graphene FET was systematically investigated. A separate evaluation of the electron beam induced transport properties at the graphene channel and the graphene-metal contacts was conducted. This provided on-demand strategies for tuning transfer characteristics of graphene FETs by focused electron beam irradiation.
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Research for Hot Carrier Degradation in N-Type Bulk FinFETs
Jinsu Park, Sanchari Showdhury, Geonju Yoon, Jaemin Kim, Keewon Kwon, Sangwoo Bae, Jinseok Kim, Junsin Yi
J Electr Electron Mater 2020;33(3):169-172.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.2
In this paper, the effect of hot carrier injection on an n-bulk fin field-effect transistor (FinFET) is analyzed. The hot carrier injection method is applied to determine the performance change after injection in two ways, channel hot electron (CHE) and drain avalanche hot carrier (DAHC), which have the greatest effect at room temperature. The optimum condition for CHE injection is VG=VD, and the optimal condition for DAHC injection can be indirectly confirmed by measuring the peak value of the substrate current. Deterioration by DAHC injection affects not only hot electrons formed by impact ionization, but also hot holes, which has a greater impact on reliability than CHE. Further, we test the amount of drain voltage that can be withstood, and extracted the lifetime of the device. Under CHE injection conditions, the drain voltage was able to maintain a lifetime of more than 10 years at a maximum of 1.25 V, while DAHC was able to achieve a lifetime exceeding 10 years at a 1.05-V drain voltage, which is 0.2 V lower than that of CHE injection conditions.
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Analysis on Current and Optical Characteristics by Electronic Ink Loading Method in Charged Particles Type Display
Hyeong-jin An, Young-cho Kim
J Electr Electron Mater 2020;33(2):123-129.   Published online March 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.2.9
We analyzed the drift current by charged particles according to the loading methods applied into a closed cell by electronic ink at a reflective-type display panel using an electrophoretic mechanism. For this experiment, various panels were fabricated with injection voltages for electronic ink taking values in the range -4~0 V. The size of each cell was 220 μm × 220 μm and height of the barrier rib was 54.28 μm. The electronic ink was fabricated by mixing electrically neutral fluid and single-charge white particles. Drift current was measured by moving charged particles. A biasing voltage of 6 V was applied to the display panel. As a result, the drift current was proportional to the injection voltage for electronic ink, but it decreased in case of an injection voltage above -3 V. Our experimentation ascertained that the concentration of charged particles injected into closed cells is controlled by the injection voltage and the selective injection of charged particles above movable q/m is possible.
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Current Properties and Evaluation of Electronic Ink in Electrophoretic Display
Hyeong-jin An, Young-cho Kim
J Electr Electron Mater 2020;33(1):31-36.   Published online January 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.1.7
An investigation was conducted to determine whether the ratio of the fluid to the charged particles affects the panel reflexibility rate and the drifting current flowing in the panel, in electrophoretic-based electronic paper. In this regard, three panels were produced in this study with the ratio of the charged particles to the fluid set as 1:5, 1:1, and 5:1. Each sample was driven using an identical input pulse, for which the current flowing in the panel and the output voltage of the photodiode were measured for the panel reflexibility rate. Consequently, the drifting current initially exhibited a peak value and a saturated value at a later point. This value was proportional to the ratio of the charged particles, and it was similar to this ratio when it is higher than 1:1. The output voltage of the photodiode due to the panel reflexibility rate was proportional to the ratio of the charged particles. However, the response speed decreased if the ratio was higher than 1:1. It is expected that the results of this study will contribute to the analysis of the charging of charged particles in electrophoretic-based electronic paper, and the selection of an appropriate concentration.
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Electromagnetic Property of a Heavy Fermion CePd2Si2
Tae Seong Jeong
J Electr Electron Mater 2019;32(5):399-402.   Published online September 1, 2019
The electromagnetic properties of heavy fermion CePd2Si2 are investigated using density functional theory using the local density approximation (LDA) and LDA+U methods. The Ce f-bands are located near the Fermi energy and hybridized with the Pd-3d states. This hybridization plays an important role in generating the physical characteristics of this compound. The magnetic moment of CePd2Si2 calculated within the LDA scheme does not match with the experimental result because of the strong correlation interaction between the f orbitals. The calculation shows that the specific heat coefficient underestimates the experimental value by a factor of 5.98. This discrepancy is attributed to the formation of quasiparticles. The exchange interaction between the local f electrons and the conduction d electrons is the reason for the formation of quasiparticles. The exchange interaction is significant in CePd2Si2, which makes the quasiparticle mass increase. This enhances the specific heat coefficient.
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