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Volume 30(3); March 2017

Evaluation on the Phase-Change Properties in W-doped Ge8Sb2Te11 Thin Films for Amorphous-to-Crystalline Reversible Phase-Change Device
Cheol-jin Park, Jong-bin Yeo, Heon Kong, Hyun-yong Lee
J Electr Electron Mater 2017;30(3):133-138.   Published online March 1, 2017
We evaluated the structural, electrical and optical properties of tungsten (W)-doped Ge8Sb2Te11 thin films. In a previous work, GeSbTe alloys were doped with different materials in an attempt to improve thermal stability. 200 mm thick Ge8Sb2Te11 and W-doped Ge8Sb2Te11 films were deposited on p-type Si (100) and glass substrates using a magnetron co-sputtering system at room temperature. The fabricated films were annealed in a furnace in the 0~400℃ temperature range. The structural properties were analyzed using X-ray diffraction (X`pert PRO, Phillips). The results showed increased crystallization temperature (Tc) leading to thermal stability in the amorphous state. The optical properties were analyzed using an UV-Vis-IR spectrophotometer (Shimadzu, U-3501, range : 300~3,000 nm). The results showed an increase in the crystalline material optical energy band gap (Eop) and an increase in the Eop difference (△Eop). This is a good effect to reduce memory device noise. The electrical properties were analyzed using a 4-point probe (CNT-series). This showed increased sheet resistance (Rs), which reduces programming current in the memory device.
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Boron Diffused Layer Formation Process and Characteristics for High Efficiency N-type Crystalline Silicon Solar Cell Applications
Gyeongbae Shim, Cheolmin Park, Junsin Yi
J Electr Electron Mater 2017;30(3):139-143.   Published online March 1, 2017
N-type crystalline silicon solar cells have high metal impurity tolerance and higher minority carrier lifetime that increases conversion efficiency. However, junction quality between the boron diffused layer and the n-type substrate is more important for increased efficiency. In this paper, the current status and prospects for boron diffused layers in N-type crystalline silicon solar cell applications are described. Boron diffused layer formation methods (thermal diffusion and co-diffusion using a-SiOX:B), boron rich layer (BRL) and boron silicate glass (BSG) reactions, and analysis of the effects to improve junction characteristics are discussed. In-situ oxidation is performed to remove the boron rich layer. The oxidation process after diffusion shows a lower B-O peak than before the Oxidation process was changed into SiO2 phase by FTIR and BRL. The a-SiOX:B layer is deposited by PECVD using SiH4, B2H6, H2, CO2 gases in N-type wafer and annealed by thermal tube furnace for performing the P+ layer. MCLT (minority carrier lifetime) is improved by increasing SiH4 and B2H6. When a-SiOX:B is removed, the Si-O peak decreases and the B-H peak declines a little, but MCLT is improved by hydrogen passivated inactive boron atoms. In this paper, we focused on the boron emitter for N-type crystalline solar cells.
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A Study on the Electrical Properties of MIM Structures Based on Ge2Sb2Te5 and Ge8Sb2Te11 Thin Films for ReRAM
Hwi-jong Jang, Heon Kong, Jong-bin Yeo, Hyun-yong Lee
J Electr Electron Mater 2017;30(3):144-147.   Published online March 1, 2017
In this study, Ge2Sb2Te5 and Ge8Sb2Te11 were used as an insulator layer to fabricate ReRAM devices. The resistance change is correlated to the appearance or disappearance of a conductivity filament at the surface of the GeSbTe layer. Changes in the electrical properties of ITO/GeSbTe/Ag devices were measured using a I-V-L measurement system. As a result, compared to the ITO/Ge8Sb2Te11/Ag device, this ITO/Ge2Sb2Te5/Ag ReRAM device exhibits highly uniform bipolar resistive switching characteristics, such as the operating voltages, and the resistance values.
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The Optimal Design of Field Ring for Reliability and Realization of 3.3 kV Power Devices
Ey Goo Kang
J Electr Electron Mater 2017;30(3):148-151.   Published online March 1, 2017
This research concerns field rings for 3.3kV planar gate power insulated-gate bipolar transistors (IGBTs). We design an optimal field ring for a 3.3kV power IGBT and analyze its electrical characteristics according to field ring parameters. Based on this background, we obtained 3.3kV high breakdown voltage and a 2.9V on state voltage drop. To obtain high breakdown voltage, we confirmed that the field ring count was 23, and we obtained optimal parameters. The gap distance between field rings 13㎛ and the field ring width was 5㎛. This design technology will be adapted to field stop IGBTs and super junction IGBTs. The thyristor device for a power conversion switch will be replaced with a super high voltage power IGBT.
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Piezoelectric and Dielectric Properties of PMN-PNN-PZT Ceramics for Ultrasonic Generator with Calcination Temperature
Ju-hyun Yoo, Seung-won Kim, Dong-hi Seo, Eun-sup Lee, Nak-gu Choi, Hoy-seung Jeong
J Electr Electron Mater 2017;30(3):152-156.   Published online March 1, 2017
In this paper, Pb(Mn1/3Nb2/3)0.07(Ni1/3Nb2/3)0.10(Zr0.5Ti0.5)0.83O3 ceramics were fabricated by the conventional solid state method to obtain excellent dielectric properties for ultrasonic generators. The effects of 2nd calcination temperature on their microstructure and piezoelectric properties were systematically investigated. The tetragonality increased in the ceramics when 2nd calcination temperature increased to the optimized temperature at 750℃. At that temperature, excellent physical properties (d33= 352 pC/N, εr= 1,687, kp= 0.570, Qm= 1,640) were obtained for ultrasonic generator application.
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Effect of LaFeO3 Doping on the Ferroelectric and Piezoelectric Properties of Bi0.5(Na0.78K0.22)0.5TiO3 Lead-Free Piezoceramics
Chun-kil Park, Ji-ho Lim, Jung-soo Park
J Electr Electron Mater 2017;30(3):157-161.   Published online March 1, 2017
(1-x)Bi0.5(Na0.78K0.22)0.5TiO3-xLaFeO3 ceramics were fabricated using a solid state reaction method. The microstructural, ferroelectric and piezoelectric properties were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), and polarization hysteresis loops (P-E). XRD results indicated that BNKT ceramic crystal structure modified by LaFeO3 was transformed from a ferroelectric tetragonal to a non-polar pesudo-cubic phase with increased LaFeO3 content. The improved piezoelectric properties resulted from the addition of LaFeO3 up to 3 mol%. The LaFeO3 3mol% sample showed markedly improved piezoelectric and strain behaviors in comparison with pure BNKT ceramic.
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A Study on the Optimization of the ITO/Ag/ITO Multilayer Transparent Electrode by Using In-line Magnetron Sputtering
Seung Yong Lee, Yeo Tak Yoon, Eou Sik Cho, Sang Jik Kwon
J Electr Electron Mater 2017;30(3):162-169.   Published online March 1, 2017
Indium tin oxide (ITO) thin films show a low sheet resistance and high transmittance in the visible range of the spectrum. Therefore, they play an important role as transparent electrodes for flat panel displays. However, their resistivity is rather high for use as a transparent electrode in large displays. One way to improve electrical and optical properties in large displays is to use ITO/Ag/ITO multilayer films. ITO/Ag/ITO multilayer films have lower sheet resistance than single layer ITO films with the same thickness. Prior to the ITO/Ag/ITO multilayer experiments, optimal condition for thickness change are necessary. Their thicknesses were deposited differently in order to analyze electrical and optical properties. However, when optimal single film characteristics are applied to ITO/Ag/ITO multilayer films, other phenomena appeared. After analyzing the electrical and optical properties by changing ITO and Ag film thickness, ITO/Ag/ITO multilayer films were optimized. By combining ITO film at 586 Å and Ag film at 10 nm, the ITO/Ag/ITO multilayer films showed optimized high optical transmittance of 87.65%, and the low sheet resistance of 5.5 Ω/sq.
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A Study on Improvement of Optical Characteristics by Packaging Methods in Three Electrode-Type Reflective Display
Sang-hyun Park, Young-cho Kim
J Electr Electron Mater 2017;30(3):170-174.   Published online March 1, 2017
In 3 electrode reflective displays using a plastic substrate, unstable packaging induces particle clumping and optical degradation due to external air inflow and electronic ink evaporation. In this work, we fabricate 3 electrode electronic paper using glass wafer, ITO/plastic film, and ITO/glass/gas barrier film as an upper substrate after injecting electronic ink onto the lower substrate. Then, we studied its properties. After operating under stress conditions for 336 hours at 85℃ and 75% humidity, the reflectivity of driven e-paper panels with white color was 25.5% for the panels using glass wafer, 22.5% for plastic film including a gas barrier layer, and 16% for plastic film only. From these optical properties, we conclude that gas barrier film improves upper film isolation as a desirable packaging method.
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Improvement of the Light Emission Efficiency on Nonpolar a-plane GaN LEDs with SiO2 Current Blocking Layer
Seong Joo Hwang, Joon Seop Kwak
J Electr Electron Mater 2017;30(3):175-179.   Published online March 1, 2017
In this study, we investigate the SiO2 current blocking layer (CBL) to improve light output power efficiency in nonpolar a-plane (11-20) GaN LEDs on a r-plane sapphire substrate. The SiO2 CBL was produced under the p-pad layer using plasma enhanced chemical vapor deposition (PECVD). The results show that nonpolar GaN LED light output power with the SiO2 CBL is considerably enhanced compared without the SiO2 CBL. This can be attributed to reduced light absorption at the p-pad due to current blocking to the active layer by the SiO2 CBL.
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Annealing Effects on Ambipolar Characteristics of Diketopyrrolopyrrole-Based Polymer Thin-Film Transistors
Gyu Bok Yoon, Jiyoul Lee
J Electr Electron Mater 2017;30(3):180-184.   Published online March 1, 2017
In this study, we examine the electrical properties of diketopyrrolopyrrole (DPP) containing polymer semiconductors that have been reported to show high performance with ambipolar characteristics. We prepared three different DPP based polymer semiconductors (PDPPTPT, PDPP3T, and PDPP2T-TT) and fabricated organic thin film transistors (OTFTs) with ambipolar polymer semiconductors as an active layer. All three DPP polymers showed only p-type properties at initial measurements. However, after annealing in vacuum oven for 24 hours, it was found that the DPP based polymers have both p-type and n-type properties. It is speculated that the residual impurities supposedly regarded as a strong electron trap source were eliminated during the vacuum process.
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Facile Synthesis of Vertically Aligned CdTe-Si Nanostructures with High Density
Jinho Im, Sung-hwan Hwang, Hyunsung Jung
J Electr Electron Mater 2017;30(3):185-191.   Published online March 1, 2017
Cadmium compounds with one dimension (1D) nanostructures have attracted attention for their excellent electrical and optical properties. In this study, vertically aligned CdTe-Si nanostructures with high density were synthesized by several simple chemical reactions. First, l D Te nanostructures were synthesized by silver assisted chemical Si wafer etching followed by a galvanic displacement reaction of the etched Si nanowires. Nanowire length was controlled from 1 to 25 μm by adjusting etching time. The Si nanowire galvanic displacement reaction in HTeO2 + electrolyte created hybrid 1D Te-branched Si nanostructures. The sequential topochemical reaction resulted in Ag2Te-Si nanostructures, and the cation exchange reaction with the hybrid 1D Te-branched Si nanostructures resulted in CdTe-Si nanostructures. Wet chemical processes including metal assisted etching, galvanic displacement, topochemical and cation exchange reactions are proposed as simple routes to fabricate large scale, vertically aligned CdTe-Si hybrid nanostructures with high density.
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A Study on the Selective Hole Carrier Extraction Layer for Application of Amorphous/crystalline Silicon Heterojunction Solar Cell
Yongjun Kim, Sunbo Kim, Youngkuk Kim, Young Hyun Cho, Chang-kyun Park, Junsin Yi
J Electr Electron Mater 2017;30(3):192-197.   Published online March 1, 2017
Hydrogenated Amorphous Silicon (a-Si:H) is used as an emitter layer in HIT (heterojunction with Intrinsic Thin layer) solar cells. Its low band gap and low optical properties (low transmittance and high absorption) cause parasitic absorption on the front side of a solar cell that significantly reduces the solar cell blue response. To overcome this, research on CSC (carrier Selective Contacts) is being actively carried out to reduce carrier recombination and improve carrier transportation as a means to approach the theoretical efficiency of silicon solar cells. Among CSC materials, molybdenum oxide (MoOx) is most commonly used for the hole transport layer (HTL) of a solar cell due to its high work function and wide band gap. This paper analyzes the electrical and optical properties of MoOx thin films for use in the HTL of HIT solar cells. The optical properties of MoOx show better performance than a-Si:H and μc-SiOx:H.
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