The aim of this investigation is to detect specific waveforms in a distribution line prior to the occurrence of a fault. Conditions were introduced such that a feeder remote terminal unit (FRTU) of the distribution automation system selects and stores fault waveforms from the different waveforms detected in the distribution line. In addition, an algorithm was developed to detect specific waveforms from the fault waveforms stored using the FRTU. This algorithm exploits the duration and periodicity of harmonic changes in voltage and current. The efficacy of the algorithm was confirmed based on the measurements of fault waveforms in an actual distribution line. The results indicated that faults in a distribution line can be predicted via experimental measurements.