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발광층 내의 스페이서가 인광 OLED의 효율 및 발광특성에 미치는 영향

서유석, 문대규

Effects of Spacer Inserted Inside the Emission Layer on the Efficiency and Emission Characteristics of Phosphorescent Organic Light-emitting Diodes

Yu Seok Seo, Dae Gyu Moon
J Electr Electron Mater 2014;27(6):377-382.
Published online: June 1, 2014
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본 연구에서는 청색 도핑층과 적색 도핑층 사이에 놓인 스페이서 층이 인광 OLED의 발광 및 효율 특성에 미치는 영향을 조사하였다. 호스트 층으로 N,N``-di-carbazolyl-3,5-benzene (mCP)를 사용하였으며, Iridium(III)bis[(4,6-di-fluorophenyl)-pyridinato-N,C2``]picolinate (FIrpic)와 tris(1-phenyl-isoquinolinato-C2,N)iridium(III) [Ir(piq)3]를 청색 및 적색 도판트로 사용하였다. 발광층의 구조는 mCP (1-x) nm/mCP:Ir(piq)3 (5 nm, 10%)/mCP (x nm)/mCP:FIrpic (5 nm, 10%)였다. mCP 스페이서의 두께는 0 nm에서 15 nm까지 변화시켰다. mCP 호스트와 FIrpic 으로부터의 에너지 전달과 mCP 호스트로부터의 삼중항 여기자 확산이 Ir(piq)3로부터의 발광 및 소자의 효율을 결정하는 중요한 요인이었다.

We have investigated the effects of spacer layer inserted between blue and red doped emissionlayers on the emission and efficiency characteristics of phosphorescent OLEDs. N,N``-di-carbazolyl-3,5-benzene(mCP) was used as a host layer. Iridium(III)bis[(4,6-di-fluorophenyl)- pyridinato-N,C2``]picolinate (FIrpic) andtris(1-phenyl-isoquinolinato-C2,N)iridium(III) [Ir(piq)3] were used as blue and red dopants, respectively. Theemission layer structure was mCP (1-x) nm/mCP:Ir(piq)3 (5 nm, 10%)/mCP (x nm)/mCP:FIrpic (5 nm, 10%). The thickness of mCP spacer layer was varied from 0 to 15 nm. The emission from Ir(piq)3 and theefficiency of the device were dominated by energy transfer from mCP host and FIrpic molecules, and bydiffusion of mCP host triplet excitons.

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Effects of Spacer Inserted Inside the Emission Layer on the Efficiency and Emission Characteristics of Phosphorescent Organic Light-emitting Diodes
J Electr Electron Mater. 2014;27(6):377-382.   Published online June 1, 2014
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Effects of Spacer Inserted Inside the Emission Layer on the Efficiency and Emission Characteristics of Phosphorescent Organic Light-emitting Diodes
J Electr Electron Mater. 2014;27(6):377-382.   Published online June 1, 2014
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