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"Ti(1-x)Nb(x)O2"

Properties of Nb-doped TiO2 Transparent Conducting Oxide Film Fabricated by RF Magnetron Sputtering
Min Young Kim, Mun Seong Cho, Dong Gun Lim, Jae Hwan Park
J Electr Electron Mater 2012;25(3):204-208.   Published online March 1, 2012
TiO2 (Ti(1-x)Nb(x)O2, x= 0.04~0.06) transparent conducting oxide film was fabricated by RF magnetron sputtering process and their electrical, optical, stability properties were studied. When the Nb 4 at% sputtering target was used with RF power 120 W, pressure 8 mTorr, post-annealing temperature 60 0℃, the resistivity of TNO film was 4×10(-4) Ω-cm. The optical transmittance in the visible wavelength was ca. 86%. TNO films require heat treatment during or after the deposition process. When the film was deposited at room temperature and post-annealed at 600℃, the lowest resistivity was obtained. When the TNO film was exposed to high temperature and humidity, the resistivity of the film was rather decreased. The stability to temperature and humidity implies that the TNO film could be a appropriate candidate for In-free, ZnO-free transparent conducting oxide materials.
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