We investigated the effect of etching time on the surface roughness, and electrical and optical properties of ZnO and 2 wt% Al-doped ZnO (AZO) films. The ZnO and AZO films were deposited on glass substrates by RF magnetron sputtering technique. The etching experiment was carried out using a solution of 5% HCl at room temperature. The surface roughness was characterized by Atomic Force Microscopy. The electrical property was measured by Hall measurement system and 4-point probe. The optical property was characterized by UV-vis spectroscopy. After the wet chemical etching, the surface textures were obtained on the surface of the ZnO and AZO films. With the increase of etching time, the surface roughness (RMS) of the films increased and the transmittance of the films was observed to decrease. For the AZO film, a low resistivity of 1.0×10-3 Ω·cm was achieved even after the etching.

Citations

• Electrochemical Etching of Fluorine-Doped Tin Oxide (FTO): Effects on Morphological, Electrical, Physical and Optical Properties
  Biniam Ademe, Yekitwork Abebe Temitmie, Getachew Tizazu, Atakilt Abebe, Christoph Ulbricht, Bekele Hailegnaw, Markus Scharber, Munise Cobet, Cigdem Yumusak, Niyazi Serdar Sariciftci, Lukas Schmidt-Mende, Amare Benor
  ACS Applied Optical Materials.2026; 4(6): 1621.     CrossRef