The effect of lead free glass frit compositions on the properties of thick film conductor and resistor pastes were investigated. Two types lead free frits, HBF-A(without Bi2O3) and HBF-B(with Bi2O3) were made from SiO2, B2O3, Al2O3, CaO, MgO, Na2O, K2O, ZnO, MnO, ZrO2, Bi2O3. And Ag based conductor pastes and RuO2 based resistor paste were prepared by mixed with these frits and functional phase(Ag and RuO2), and organic vehicle. The properties of thick film conductor and resistor sintered at 850℃ were studied after printing on Al2O3 substrate. The morphology of the sintered films surface were SEM and EDS were carried out to analysis the chemical composition on resistor surface and state of Ru atom in frit matrix.