Cadmium compounds with one dimension (1D) nanostructures have attracted attention for their excellent electrical and optical properties. In this study, vertically aligned CdTe-Si nanostructures with high density were synthesized by several simple chemical reactions. First, l D Te nanostructures were synthesized by silver assisted chemical Si wafer etching followed by a galvanic displacement reaction of the etched Si nanowires. Nanowire length was controlled from 1 to 25 μm by adjusting etching time. The Si nanowire galvanic displacement reaction in HTeO2 + electrolyte created hybrid 1D Te-branched Si nanostructures. The sequential topochemical reaction resulted in Ag2Te-Si nanostructures, and the cation exchange reaction with the hybrid 1D Te-branched Si nanostructures resulted in CdTe-Si nanostructures. Wet chemical processes including metal assisted etching, galvanic displacement, topochemical and cation exchange reactions are proposed as simple routes to fabricate large scale, vertically aligned CdTe-Si hybrid nanostructures with high density.
In this work, one dimension In2O3 nanostructures as detecting materials for indoor toxic gases were synthesized by an electrospinning process. The morphology of electrospun In2O3 nanofibers was controlled by electrolyte composition, applied voltage and working distance between a nozzle and a substrate. The synthesized In2O3 nanofibers-based paste with/without carbon black additives was prepared for the integration on a sensor device. The integration of In2O3 sensing materials was conducted by a hand-printing of the paste into the interdigit Au electrodes patterned on Si wafer. Gas sensing properties on CO and HCHO gases were characterized at 300℃. The evaluated sensing properties such as sensitivity, response time and recovery time were improved in In2O3 nanofiber pastes with carbon black, compared to the paste without carbon black.