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"Mullite"

Effect of Cr2O3-MgO-Y2O3 Addition on Mechanical Properties of Mullite Ceramics
Jin-hyeon Lim, Shi Yeon Kim, Dong-hun Yeo, Hyo-soon Shin, Dae-yong Jeong
J Electr Electron Mater 2017;30(12):762-767.   Published online December 1, 2017
Mullite (3Al2O3·2SiO2) has emerged as a promising candidate for high-temperature structural materials due to its erosion resistance, chemical and thermal stabilities, relatively low thermal expansion coefficient, excellent thermal shock and creep resistances, and low dielectric constant. However, since the pure mullite sintering temperature is as high as 1,600~1,700℃, there is an increasing need for a sintering additive capable of improving the strength characteristics while lowering the sintering temperature. Herein we have tried to obtain the optimal sintering additive composition by adding MgO, Cr2O3, and Y2O3 to mullite, followed by sintering at 1,325~1,550℃ for 2 h. With additives of 2 wt% of MgO, 2 wt% of Cr2O3, 4 wt% of Y2O3, A density of 3.23 g/cm³ was obtained for the sintered body at 1,350℃ upon using 2 wt% MgO, 2 wt% Cr2O3, and 4 wt% Y2O3 as additives. The three-point flexural strength of that was 275 MPa and the coefficient of thermal expansion (CTE) was 4.15 ppm/℃.
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