The activation energy of a material is an important factor that significantly affects the lifetime and can be used to develop a degradation model. In this study, a thermal analysis was carried out to evaluate and collect quantitative data on the degradation of insulation materials like EPR and CSP used for nuclear power plant cables. The activation energy was determined from the relationship between log β and 1/T based on the Flynn-Wall-Ozawa method, by a TGA test. The activation energy was also derived from the relationship between ln(t) and 1/T based on isothermal analysis, by an OIT test. The activation energy of EPR derived from thermal analysis was used to calculate the accelerated aging time corresponding to the number of years of use, employing the Arrhenius equation, and determine the elongation corresponding to the accelerated aging time.
Dye sensitized solar cells (DSSCs), which is one of the contending renewable energy sources, have the problem of low efficiency. To improve the efficiency, the fast electron transport and long electron lifetime are required. In this study, one-dimensional sodium hexatitanate, which is expected to have an advantageous structure for electron transports, was synthesized and the feasibility of the material on DSSC was tested. Its physical properties were characterized by the SEM, XRD, and BET method. The dye adsorption and solar cell properties were also characterized. In addition to the expectation of fast electron transport, sodium hexatitanate showed longer electron lifetime: This means sodium hexatitanate can improve the DSSC efficiency. However, it showed low current and voltage because of the low surface area leading to the low amount of dye adsorbed. Therefore, it should be mixed with titanium oxide with high surface area for the optimal performance.