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"Lattice mismatch"

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"Lattice mismatch"

Effect of Pre-Treatment of Alpha-Ga2O3 Grown on Sapphire by Halide Vapor Phase Epitaxy
Ye-ji Choi, Hoki Son, Yong-ho Ra, Young-jin Lee, Jin-ho Kim, Jonghee Hwang, Sun Woog Kim, Tae-young Lim, Dae-woo Jeon
J Electr Electron Mater 2019;32(5):426-431.   Published online September 1, 2019
In this study, we report the effect of pre-treatment of alpha-Ga2O3 grown on a sapphire substrate by halide vapor phase epitaxy (HVPE). During the pre-treatment process, 10 sccm of GaCl gas was injected to the sapphire substrate at 470℃. The surface morphologies of the alpha-Ga2O3 layers grown with various pre-treatment time (3, 5, and 10 min) were flat and crack-free. The transmittance of the alpha-Ga2O3 epi-layers was measured to analyze their optical properties. The transmittance was over 80% within the range of visible light. The strain in the alpha-Ga2O3 grown with a pre-treat 5 min was measured, and was found to be close to the theoretical XRD peak position. This can be explained by the reduction of strain having caused a lattice mismatch between the alpha-Ga2O3 layer and sapphire substrate. The calculated dislocation density of the screw and edge were 2.5×105 cm-2 and 8.8×109 cm-2, respectively.
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Energy Materials : Precipitation Behaviors of HgTe Nanoinclusions Formed in Thermoelectric PbTe: Initial Induced Lattice Mismatch, Theoretical Calculation and Experimental Verification
Kyung Ho Kim, Tae Hyung Kwon, Su Han Park, Hyung Keun Ahn, Man Jong Lee
J Electr Electron Mater 2011;24(7):599-604.   Published online July 1, 2011
A highly strained nanostructure comprising crystallographically aligned HgTe nanoinclusions and a surrounding PbTe matrix has been synthesized using a precipitation process of supersaturated HgTe-PbTe alloys. From the early precipitation stage, HgTe nanoinclusions take disk shape, which is transformed from initial HgTe nuclei, although there is no lattice constant difference of the two end components at standard state. As a primary reason for the morphological transformation of the initial spherical HgTe nuclei to HgTe nanodisks, the induced lattice mismatch is suggested. On the condition that the HgTe nanodisks maintain perfect coherent nature with PbTe matrix, the stress-free lattice constant of constrained HgTe nanodisks has been calculated based on the defined concept of the strain-induced tetragonality, the linear elasticity and the actual measurement in HRTEM images.
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