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"Growth mechanism"

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"Growth mechanism"

Nano Materials and Devices : Synthesis of Au Nanowires Using S-L-S Mechanism
Jin Woo Cho, Sung Hyun Kim, Paik Kyun Shin, Im Jun No
J Korean Inst Electr Electron Mater Eng 2012;25(11):922-925.   Published online November 1, 2012
DOI: https://doi.org/10.4313/JKEM.2012.25.11.922
Single crystalline Au nanowires were successfully synthesized in a tube-type furnace. The Au nanowires were grown by vapor phase synthesis technique using solid-liquid-solid (SLS) mechanism on substrates of corning glass and Si wafer. Prior to Au nanowire synthesis, Au thin film served as both catalyst and source for Au nanowire was prepared by sputtering process. Average length of the grown Au nanowires was approximately 1 μm on both the corning glass and Si wafer substrates, while the diameter and the density of which were dependent on the thickness of the Au thin film. To induce a super-saturated states for the Au particle catalyst and Au molecules during the Au nanowire synthesis, thickness of the Au catalyst thin film was fixed to 10 nm or 20 nm. Additionally, synthesis of the Au nanowires was carried out without introducing carrier gas in the tube furnace, and synthesis temperature was varied to investigate the temperature effect on the resulting Au nanowire characteristics.
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Regular Paper : Thermoelectric Properties of Bi2Te3 Films Grown by Modified MOCVD with Substrate Temperatures
Hyun Woo You, O Jong Kwon, Kwang Chon Kim, Won Chel Choi, Chan Park, Jin Sang Kim
J Korean Inst Electr Electron Mater Eng 2011;24(4):340-344.   Published online April 1, 2011
DOI: https://doi.org/10.4313/JKEM.2011.24.4.340
Thermoelectric bismuth telluride (Bi2Te3) films were deposited on 4° off oriented (001) GaAs substrates using a modified metal organic chemical vapor deposition (MOCVD) system. The effects of substrate temperature on surface morphologies, crystallinity, electrical properties and thermoelctric properties were investigated. Two dimensional growth mode (2D) was observed at substrate temperature lower than 400℃. However, three dimensional growth mode (3D) was observed at substrate temperature higher than 400℃. Change of growth mechanism from 2D to 3D was confirmed with environmental scanning electron microscope (E-SEM) and X-ray diffraction analysis. Seebeck coefficients of all samples have negative values. This result indicates that Bi2Te3 films grown by modified MOCVD are n-type. The maximum value of Seebeck coefficient was -225 μV/K and the power factor was 1.86×10-3 W/mK2 at the substrate temperature of 400℃. Bi2Te3 films deposited using modified MOCVD can be used to fabricate high-performance thermoelectric devices.
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