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"Gradient shell"

Luminescence Properties of Cd-Free InZnP/ZnSe/ZnS Core/Shell Quantum Dots
Young-ki Lee, Min-Sang Lee, Jeong-mi Lee, Dae-Hee Won, Jong-man Kim
J Electr Electron Mater 2021;34(6):454-460.   Published online November 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.6.9
In this work, we synthesized alloy-core InZnP quantum dots, which are more efficient than single-core InP quantum dots, using a solution process method. The effect of synthesis conditions of alloy core on optical properties was investigated. We also investigated the conditions that make up the gradient shell to minimize defects caused by lattice mismatch between the InZnP core and ZnS is 7.7%. The stable synthesis temperature of the InZnP alloy core was 200℃. Quantum dots consisting of three layered ZnSe gradient shell and single layered ZnS exhibited the best optical property. The properties of quantum dots synthesized in 100 ml and in 2,000 ml flasks were almost equal.
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