This review offers a critical overview of recent developments in lead-free piezoelectric materials and flexible device architectures for self-powered wearable and Internet of Things systems. It examines the scientific and technological rationale for replacing conventional battery-dependent power sources with ambient mechanical energy harvesters, and it evaluates the relative merits of inorganic ceramics, organic polymers, and composite systems in achieving efficient electromechanical conversion under practical operating conditions. The discussion further considers compositional tuning, phase boundary engineering, microstructural optimization, and device-level integration as key strategies for improving piezoelectric output, mechanical compliance, durability, and manufacturability. By connecting fundamental materials design with application-driven device requirements, the review identifies the principal challenges and emerging directions necessary for the realization of reliable, scalable, and sustainable electronic platforms.
Renewable energy harvesting technologies, which convert ambient resources such as wind into electrical energy, have attracted significant attention as sustainable power sources for self-powered systems. However, the long-term applicability of wind energy harvesters in remote or extreme environments has not yet been fully discussed, particularly in terms of structural robustness and environmental adaptability. In this study, we designed a double-clamped flutter-type triboelectric generator (DFTEG) for efficient wind energy harvesting and evaluated its output performance under various simulated outdoor conditions. The DFTEG features a modular acrylic frame with a magnet-based assembly for easy maintenance and film replacement, utilizing PTFE films and aluminum electrodes to maximize the charge density difference according to the triboelectric series. Structural optimization revealed that a single-film configuration with a length of 110 mm produced the most stable flutter vibration and a large effective contact area, achieving a maximum open-circuit voltage of 42.28 V and a short-circuit current of 2.89 μA. Furthermore, performance evaluations under various environmental variables, including relative humidity, temperature, and sand particles interference, confirmed consistent electrical output across diverse environmental conditions. These results demonstrate the potential of the proposed DFTEG as an environmentadaptive independent power source capable of stable operation under complex environmental factors.
The expansion of smart healthcare and wearable electronics has intensified the need for fabric-based sensors that integrate conformally with the human body for continuous bio signal monitoring. However, the heavy reliance of conventional devices on external batteries remains a major obstacle to commercialization, necessitating the development of flexible piezoelectric energy harvesters that convert biomechanical energy into sustainable power. Here, we present a highly flexible and wearable piezoelectric energy harvester (PEH) fabricated by a screen-printing of BaTiO3 nanoparticlePDMS composites onto a fabric substrate. An optimized piezo-ceramic filler concentration of 70 wt% yielded a peak output voltage of 0.52 V and a current of 40 nA under the mechanical bending deformations. The fabricated PEH demonstrated exceptional mechanical and electrical stability, showing no performance degradation of over 5,000 repetitive bending cycles. These results indicate that a PEH can function as a stable self-powered source within complex clothing environments, offering a promising pathway for next-generation autonomous wearable sensor systems.
Metamaterials, as artificially engineered structures with unconventional mechanical and acoustic properties, have recently emerged as a transformative platform for enhancing the capabilities of triboelectric nanogenerator (TENG) systems. Since the invention of TENG devices, extensive efforts have been devoted to improving charge density, output stability, and overall performance. Conventional performance optimization strategies mainly rely on device-level improvements such as surface chemistry modification, microstructuring, and nanopatterning. However, limited emphasis has been given to system-level development of smart self-powered intelligent systems. The integration of metamaterials into TENG devices opens a new era by enabling frequency-selective localization, mechanical impedance matching, and controllable deformation pathways. These engineered mechanical structures not only improve energy harvesting efficiency but also introduce new functionalities into the system. This review systematically summarizes recent advances in metamaterial-integrated TENG systems across four major application domains: (i) energy harvesting, (ii) acoustic telecommunication and acoustic-to-electric conversion, (iii) self-powered sensing, and (iv) vibration suppression and monitoring. Overall, the integration of metamaterials into TENG systems will pave the way for next-generation sustainable, intelligent, self-powered devices with diverse functionalities.
The rapid evolution of wearable technology has driven a surge in demand for sustainable, self-powered electronic devices. Flexible thermoelectric materials, capable of converting body heat into electricity, have emerged as a promising solution for powering next-generation wearables. This review comprehensively examines recent progress in organic (polymer-based) and hybrid thermoelectric materials, focusing on their design, fabrication, and integration into flexible architectures suitable for conformal contact with human skin. Key developments include advanced doping strategies, post-treatment techniques, and composite engineering, particularly in conductive polymers such as PEDOT: PSS and P3HT, which have significantly enhanced power factors and mechanical flexibility. Additionally, the integration of high-performance inorganic materials into stretchable systems has further elevated device efficiency and durability. The review highlights breakthroughs, ongoing challenges, and future opportunities in realizing practical, scalable, and high-efficiency wearable thermoelectric generators for sustainable energy harvesting applications.
Abstract In this study, to develop composition ceramics for energy harvesting devices, Pb(Ni1/3Nb2/3)O₃-Pb(Zr Ti)O₃ system ceramics substituted with Pb(Mg1/2W1/2)O₃ were manufactured by conventional mixed oxide method using Li₂CO₃ and Na₂CO₃ (LNCO) as sintering aids. Their microstructure and piezoelectric properties were also investigated. At the specimen sintered at 930℃, high values of piezoelectric properties appeared: the dielectric constant (εr) of 2,522 planar electromechanical coupling factor kp of 0.602, and k31 of 0.385, d31 = 229 [pC/N], g31 = 10.13 [mV.m/N], Qm of 70, respectively. These values were suitable for the application of devices such as energy harvesting devices and ultrasonic devices.
Energy harvesting technology offers an innovative solution for providing self-sustaining power to wearable and implantable electronic devices. However, traditional energy harvesters face limitations in operating within electrolytic environments or at low motion speeds. To overcome these challenges, a mechano-electrochemical energy harvester using carbon nanotubes has been developed. This technology relies on electrochemical ion movement to induce changes in electrochemical double-layer capacitance, enabling operation within electrolytes and optimizing performance at low deformation speeds. This environmentally friendly and sustainable energy solution is expected to play a crucial role in the advancement of future smart systems and wearable technologies.
Energy harvesting technology, which converts wasted energy sources in everyday life into usable electric energy, is gaining attention as a solution to the challenges of charging and managing batteries for the driving of IoT sensors, which are one of the key technologies in the era of the fourth industrial revolution. Hybrid energy harvesting technology involves integrating two or more energy harvesting technologies to generate electric energy from multiple energy conversion mechanisms. In this study, a hybrid energy harvesting device called TMPPEG (thermo-magneto-piezoelectric-pyroelectric energy generator), which utilizes low-grade waste heat, was developed by incorporating PVDF polymer piezoelectric components and optimizing the system. The variations in piezoelectric output and thermoelectric output were examined based on the spacing of the clamps, and it was found that the device exhibited the highest energy output when the clamp spacing was 2 mm. The voltage and energy output characteristics of the TMPPEG were evaluated, demonstrating its potential as an efficient hybrid energy harvesting component that effectively harnesses low-grade waste heat.
Stretchable piezoelectric energy harvester (S-PEHs) based on composite materials are considered one of the potential candidates for realizing wearable self-powered devices for smart clothing and electronic skin. However, low energy conversion performance and expensive stretchable electrodes are major bottlenecks hindering the development and application of S-PEHs. Here, we fabricated the S-PEH by adopting the piezoelectric composites with enhanced stress transfer properties and kirigamipatterned textile electrodes. The optimum contents of piezoelectric BaTiO3 nanoparticles inside the carbon nanotube/ecoflex composite were selected as 30 wt% considering the trade-off between stretchability and energy harvesting performance of the device. The final S-PEH shows an output voltage and mechanical stability of ~5 V and ~3,000 cycles under repeated 150% of tensile strain, respectively. This work presents a cost-effective and scalable way to fabricate stretchable piezoelectric devices for self-powered wearable electronic systems.
Triboelectric devices are attracting attention from researchers as self-powered electronic systems that can instantly convert mechanical input into electrical energy output. To improve triboelectric energy harvesting performance, increasing the number of contacts as well as the contact area has been carried out by numerous researchers. In this study, we design a shaker-type energy harvester which is called as maracas triboelectric generator (M-TEG), inspired by the structure of maracas, one of the musical percussion instruments. A tripod frame is inserted to the inside of a cylindrical case, which is a device with the electrodes of aluminum and copper. Then, the triboelectric energy harvesting characteristics between polypropylene (PP) balls and the electrodes are measured. The M-TEG with the frame generates the energy harvesting signals up to ~100 V and ~2.5 μA due to larger contact area and numbers, which enhances the voltage and current output by 250% and 610% compared to that without the frame, respectively. This study presents the feasibility of self-powered sensors and toys using improved triboelectric energy performance with a low-cost and simple manufacturing process in the interesting structure.
Chang Min Baek, Min Woo Kim, Ji Won Lee, Hyun Ah Kim, Ji Yun Jung, Jun Hyeon Yoon, Hyo Il Kim, Ye Jin Park, Gi Hun Kim, So Hwa Kim, Seung Heon Kim, Jeong Min Kim, Hye Seon Lee, Jeong Won Jang, Min Gyo Jeong, Jin Hyeok Choi, Seung Yun Ha, Seungah Lee, Han Seung Choi, Jungho Ryu
J Electr Electron Mater 2022;35(6):639-646. Published online November 1, 2022
Energy harvesting technologies that can convert wasted various energy into usable electrical energy have been widely investigated to overcome the limitation of batteries for the powering of IoT sensors and small electronic devices. Hybrid energy harvesting is known as a technology that enhances the output power of single energy harvesting device by housing two or more various energy harvesting mechanisms. In this study, we introduce a hybrid MME (Magneto-Mechano-Electric) generator coupled with the triboelectric effect. Through FEA modeling, four triboelectric materials, including PI (Polyimide), PFA(Teflon), Cu, and Al, were selected and compared with the expected triboelectric potentials. The effect of surface morphology was investigated as well. Among various combination of triboelectric materials and surface morphologies, PFA-Al combination with the surface morphology having nano-scale square projections showed highest output potential under triboelectrification. It is also experimentally confirmed that output voltage and power of the hybrid MME generator with triboelectric material combinations.
Recent advancement of Internet of Things (IoT) and energy harvesting technology enable realization of flexible thermoelectric energy harvester (f-TEH), with technological prowess for use in biomedical monitoring system integrated applications. To expand a flexible thermoelectric energy harvesting platform, the f-TEH must be required for optimized flexible thermoelectric materials and device structure. In response to these demands related to thermoelectric energy harvesting, many research groups have investigated various f-TEHs applied as a power source for wearable electronics. As a key member of the f-TEH, film-based f-TEHs possess significant applicability in research to realize self-powered wearable electronics, owing to their excellent flexibility, low thermal conductivity, and convenient fabrication process. Thus, based on the rapid growth of thermoelectric film technology, this review aims to overview comprehensively the f-TEH made of various inorganic/organic thermoelectric materials including developed fabrication methods, high thermoelectric performance, and wide-range applications.
Liquid-based Triboelectric nanogenerator (L-TENG) is one of the alternatives to solid-based Triboelectric nanogenerator (S-TENG) because of the absence of surface damage which can decrease the durability of the generator. However, the L-TENG also has an obvious drawback of significantly lower output than that of S-TENG. This article produces water-sloshing-based electricity generating device (W-ED) with a new design of L-TENG that improves electrical output in portable form. The dual-electrode system, consisting of closed-loop circuit and inner electrode which enables water to contact directly in the bottle, can generate the open-circuit voltage and the short-circuit current of up to 348 V and 5.1 mA, respectively. By investigating the motion of water for each frequency, we propose that W-ED is suitable device for a variety of human motions. We expect that W-ED can be applied in small electrical devices or sensors in daily-use items.
Piezoelectric energy harvesting technologies, which can be used to convert the electricity from the mechanical energy, have been developed in order to assist or power the wearable electronics. To realize non-toxic and biocompatible electronics, the lead-free (Ba0.85Ca0.15)(Ti0.90Zr0.10)O3 (BCTZ) nanoparticles (NPs) are being studied with a great attention as flexible energy harvesting device. Herein, piezoelectric hybrid nanocomposites were fabricated using BCTZ NPs-embedded poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] matrix to improve the performance of flexible energy harvester. Output performance of the fabricated energy device was investigated by the well-optimized measurement system during the periodically bending and releasing motions. The generated open-circuit voltage and the short-circuit current of the piezoelectric hybrid nanocomposite-based energy harvester reached up to ~15 V and ~1.1 μA, respectively; moreover, the instantaneous power of 3.5 μW is determined from load voltage and current at the external load of 20 MΩ. This research is expected to cultivate a new approach to high-performance wearable self-powering electronics.
Hyeon Yeong Lee, Kwangwon Kim, Jiwon Ye, Suhyeon Woo, Geon Lee, Seungah Lee, Seong Rok Jeong, Seon Hye Jeong, Ho Seong Kim, Ga Hyeon Nam, Yun Yeong Jo, Han Seung Choi, Jungho Ryu
J Electr Electron Mater 2021;34(6):495-504. Published online November 1, 2021
Energy Harvesting is a technology that can convert wasted energy such as vibration, heat, light, electromagnetic energy, etc. into usable electrical energy. Among them, vibration-based piezoelectric energy harvesting (PEH) has high energy conversion efficiency with a small volume; thus, it is expected to be used in various autonomous powering devices, such as implantable medical devices, wearable devices, and energy harvesting from road or automobiles. In this study, wasted vibration energy in an automobile is converted into electrical energy by high-power piezoelectric materials, and the generated electrical energy is found to be an auxiliary power source for the operation of wireless sensor nodes, LEDs, etc. inside an automobile. In order to properly install the PEH in an automobile, vibration characteristics includes frequency and amplitude at several positions in the automobile is monitored initially and the cantilever structured PEH was designed accordingly. The harvesting properties of fabricated PEH is characterized and installed into the engine part of the automobile, where the vibration amplitude is stable and strong. The feasibility of PEH is confirmed by operating electric components (LEDs) that can be used in practice.
Piezoelectric generators use direct piezoelectric effects that convert mechanical energy into electrical energy. Many studies were attempted to fabricate piezoelectric generators using piezoelectrics such as ZnO, PZT, PVDF. However, these various inorganic/organic piezoelectric materials are not suitable for bio-implantable devices due to problems such as brittleness, toxicity, bio-incompatibility, bio-degradation. Thus, in this paper, piezoelectric generators were prepared using a silk fibroin film which is bio-compatible by dip-coating method. The silk fibroin films are a mixed state of silk I and silk II having stable β- sheet type structures and shows the d33 value of 8~10 pC/N. There was a difference in output voltages according to the thickness. The silk fibroin generators, coated 10 times and 20 times, revealed the power density of 16.07 μW/㎠ and 35.31 μW/㎠ using pushing tester, respectively. The silk fibroin generators are sensitive to various pressure levels, which may arise from body motions such as finger tapping, foot pressing, wrist shaking, etc. The silk fibroin piezoelectric generators with bio-compatibility shows the applicability as a low-power implantable piezoelectric generator, healthcare monitoring service, and biotherapy devices.
The internet of things (IoT) technology is a key component for the advent of 4th industrial revolution, which is the network of home appliances, infrastructures, and vehicles to remotely investigate these systems. For the operation of compact IoT devices, batteries are widely used as electric power, and the limited lifetime of batteries inevitably leads to periodic replacement. Magneto-mechano-electric (MME) generators may be alternatives to batteries inside the IoT devices by converting stray magnetic field into electric energy, since we are always surrounded by ambient alternating current (AC) magnetic fields induced from electric power transmission lines everywhere. This article reviews the recent domestic research progress in high-performance MME generators and their application field for IoT and electronic devices.
Piezoelectric ceramic fiber composite (PCFC) was fabricated using a planar electrode printed piezoelectric ceramic fiber driven in transverse mode for small-scale wind energy harvester applications. The PCFC consisted of an epoxy matrix material and piezoelectric ceramic fibers sandwiched by interdigitated electrode (IDE) patterned polyimide films. The PCFC showed an excellent mechanical performance under a continuous stress. For the fabrication of PCB cantilever harvester, five -PCFCs were vertically attached onto a flexible printed circuit board (PCB) substrate, and then PCFCs were serially connected through a printed Cu circuit. The energy harvesting performance was evaluated applying an inverted structure, which imples its free leading edge located at an open end but the trailing edge at a clamped end, to enhance strain energy in a wind tunnel. The output voltage of the PCB cantilever harvester was increased as the wind speed increased. The maximum output power was 17.2 μW at a resistance load of 200 kΩ and wind speed of 9 m/s. It is considered that the PCB cantilever energy harvester reveals a potential use for wind energy harvester applications.
We modeled the helical turbine and three modified helical turbines for the structure of the hydraulic turbine for discharge water energy harvesting. A structure that can reduce the load applied to the blade by placing a center plate is our basic concept. The shape was reduced to 1/5, fixed to a size of 240 mm in height and 247 mm in diameter, and modeled by changing the width and the angle of the hydraulic turbine blade. The pipe inner diameter of the simulation pipeline equipment is 309.5 mm, and the simulation section was 4 m in the entire section. The flow velocity was measured for two cases, 1.82 m/s and 2.51 m/s, with the parameters being the amount of power generation, hydraulic turbine’s torque, and hydraulic turbine’s rotation speed. The measurement results confirmed that the flow velocity at the center, which has no pipe surface resistance, has a great influence on the amount of power generation; therefore, the friction area of the turbine blade should be increased in the center area. In addition, if the center plate is placed on the helical turbine, durability can be improved as it reduces the stress on the blade.
A piezoelectric ceramic fiber composite (PCFC) was successfully fabricated using 0.69Pb(Zr0.47Ti0.53)O3-0.31[Pb(Zn0.4Ni0.6)1/3Nb2/3]O3 (PZT-PZNN) for use in small-scale wind energy harvesters. The PCFC was formed using an epoxy matrix material and an array of Ag/Pd-coated PZT-PZNN piezo-ceramic fibers sandwiched by Cu interdigitated electrode patterned polyethylene terephthalate film. The energy harvesting performance was evaluated in a custom-made wind tunnel while varying the wind speed and resistive load with two types of flutter wind energy harvesters. One had a five-PCFC array vertically clamped with a supporting acrylic rod while the other used the same structure but with a five-PCFC cantilever array. Stainless steel (thickness: 50 ㎛) was attached onto one side of the PCFC to form the PZT-PZNN cantilever. The output power, in general, increased with an increase in the wind speed from 2 m/s to 10 m/s for both energy harvesters. The highest output power of 15.1 ㎼ at 14 kΩ was obtained at a wind speed of 10 m/s for the flutter wind energy harvester with the PZT-PZNN cantilever array. The results presented here reveal the strong potential for wind energy harvester applications to supply sustainable power to various IoT micro-devices.
The piezoelectric energy harvesting characteristics of a trapezoidal cantilever generator with lead zirconate titanate (PZT) laminate were investigated with various Ag inner electrodes. The piezoelectric mode of operation was a transverse mode by using a planar electrode pattern. The piezoelectric cantilever generator was fabricated using trapezoidal cofired-PZT/Ag laminates by five specimens of 2, 3, 4, 7, and 13 layers of Ag. As the number of Ag electrodes increased, impedance and output voltage at resonant frequency significantly decreased, and capacitance and output current showed an increasing tendency. A maximum output power density of 7.60 mW/cm3 was realized for the specimen with seven Ag layers in the optimal condition of acceleration (1.2 g) and resistive load (600 Ω), which corresponds to a normalized power factor of 5.28 mW/g2·cm3.
Energy harvesting characteristics of trapezoidal piezoelectric cantilever generator, which has a lead zirconate titanate (PZT) laminate film, were compared by longitudinal (3-3) and transverse (3-1) modes. The PZT laminate film, fabricated by a conventional tape casting process, was cofired with Ag electrode at 850℃ for 2 h. A multi-layered Ag electrode by a planar pattern and an interdigitated pattern was applied to the PZT laminate to implement the 3-3 and 3-1 modes, respectively. The energy harvesting performance of the 3-3 mode trapezoidal piezoelectric cantilever generator was better than that of the 3-1 mode. An extremely high output power density of 26.7 mW/cm3 for the 3-3 mode was obtained at a resonant frequency of 145 Hz under a load resistance of 50 ㏀ and acceleration of 1.3 G, which is ~3-times higher than that for the 3-1 mode. Therefore, the 3-3 mode is considered significantly efficient for application to high-performance piezoelectric cantilever generator.
In this study, to increase output of road piezoelectric energy harvester, it was made into rack type in which many piezoelectric materials can be installed and load transfer device of the leverage type to transfer vehicle load was made. By paving it in the road, the output characteristics depending on vehicle load and speed were evaluated. Changing vehicle load, harvester output characteristics depending on speed changes were evaluated at the interval of 10 km/h from 10 km/h to 100 km/h. Also, by making a wireless switch and sending wireless signal with output of rack type harvester, whether to receive it was evaluated by distance. It was checked that all switches work up to front-to-back 100 m from harvester.
A road energy harvester was designed and fabricated to convert mechanical energy from the vehicle load to electrical energy. The road energy harvester is composed of 20 piezoelectric materials. This study attempted to evaluate output depending on pavement materials when paving road piezoelectric energy harvester in the road. Harvester is the bender type and is the method of supporting the both ends of piezoelectric material and applying the load in the middle part. Harvester was paved in the type paved with asphalt, type paved with cement and in the exposed type not covering the top of harvester. The output characteristics were compared and evaluated depending on changes in vehicle load and vehicle speed changes. As vehicles, truck (11.9 ton), SUV(1.6 ton) and sedan (1.5 ton) were used and the output characteristics when driving at the interval of 10 km/h from 10 km/h to 100 km/h were evaluated.
Recently, energy harvesting technology is increasing due to the fossil fuel shortages. Energy harvesting is generating electrical energy from wasted energies as sunlight, wind, waves, pressure, and vibration etc. Energy harvesting is one of the alternatives of fossil fuel. One of the energy harvesting technologies, the piezoelectric energy harvesting has been actively studied. Piezoelectric generating uses a positive piezoelectric effect which produces electrical energy when mechanical vibration is applied to the piezoelectric device. Piezoelectric energy harvesting has an advantage in that it is relatively not affected by weather, area and place. Also, stable and sustainable energy generation is possible. However, the output power is relatively low, so in this paper, newly designed honeycomb shaped piezoelectric energy harvesting device for increasing a generating efficiency. The output characteristics of the piezoelectric harvesting device were analyzed according to the change of parameters by using the finite element method analysis program. One model which has high output voltage was selected and a prototype of the honeycomb shaped piezoelectric harvesting device was fabricated. Experimental results from the fabricated device were compared to the analyzed results. After the AC-DC converting, the power of one honeycomb shaped piezoelectric energy harvesting device was measured 2.3[mW] at road resistance 5.1[KΩ]. And output power was increased the number of harvesting device when piezoelectric energy harvesting device were connected in series and parallel.
ZnO nanowires were grown by hydrothermal synthesis process and piezoelectric poly vinylidenefluoride (PVDF) was then coated on top of the ZnO-nanowires by spray-coating technique. Thecomposite layer of ZnO-nanowires/PVDF was applied to an energy harvesting device based onpiezoelectric-conversion mechanism. A defined mechanical force was given to the nanogenerator device toevaluate their electric power generation characteristics, where output current density and voltage wereexamined. Electric power generation property of the ZnO-nanowires/PVDF based nanogenerator devicewas compared to that of the nanogenerator device with ZnO-nanowires as single active layer. Effect ofthe ZnO-nanowires on improvement of power generation was discussed to examine its feasibility for thenanogenerator device.
In this paper, PZT piezoelectric ceramic specimens with 4 compositions (Zr/Ti=50/50, 53/47, 56/44, 58/42) in Pb(Zr,Ti)O3 system were fabricated. We studied effects of poling strength and thermal aging on the temperature characteristics of eletromechanical coupling factor k31 of the specimens, which were poled with the DC electric fields, 1.5, 2.5 and 3.5 kV/mm respectively and thermally aged for an hour at 200℃. The eletromechanical coupling factor k31 of the specimen with the composition Zr/Ti=53/47, nearest to the morphotropic phase boundary decreased the most greatly, irrelevant to the intensity of poling field, due to 1st thermal aging. And the temperature coefficient of eletromechaical coupling factor k31 was(-) in the ereragonal phase composition and (+) in the rhombohedral phase composition, which is reverse in the temperature coefficient of resonance frequency. It is interesting that eletromechanical coupling factor k31 of PZT ceramics is shown to be able to be able to increase as temperature increase in the interval -20~80℃.
In this study, we fabricated a micro Pb(Zr,Ti)O3 (PZT) film piezoelectric cantilever with a Si proof mass and dual beams through MEMS process. The size of the beam and the integrated Si proof mass were about 4,320 μm × 290 μm × 12 μm and 1,380 μm × 880 μm × 450 μm each. To reduce the air damping and have the larger displacement of dual beams was used for design. After mounting micro PZT film piezoelectric cantilever on shaker, we measured the resonance frequency and a output voltage while making resonant frequency changed. The resonant frequency and the highest average power of the cantilever device were 110.2 Hz and 0.36 μW each, at 0.8 g acceleration and 23.7 kΩ load resistance,respectively.
A new water energy harvester module, which is composed of piezoelectric bimorph cantilevers, harvesting circuit and a shaft with 16 impellers at a center axis, was fabricated for energy harvesting application. High energy density Pb(Zr0.54Ti0.46)O3 + 0.2 wt% Cr2O3 + 1.0 wt% Nb2O5 (PZT-CN) thick film obtained by tape casting method was used for the bimorph cantilever. The PZT-CN bimorph cantilever with a proof mass of 49 g exhibited extremely high output power of 22.5 mW (24 mW//cm3) at resonance frequency of 11 Hz. In addition, the fabricated water energy harvester has a cylindrical structure with 48 bimorph cantilevers clamped at inner surface. A significantly high output power of 433 mW was obtained at a rotation speed of 120 rpm with a resistive load of 500 Ω for the water energy harvester.
We fabricated piezoelectric unimorph cantilever generators (UCG) using Pb(Zr0.54Ti0.46)O3 + 0.2 wt% Cr2O3 + 1.0 wt% Nb2O5 (PZCN) piezoelectric thick films, which were produced by a tape casting method. The PZCN thick films were tailored with same width and thickness but different lengths from 7.7 to 57.7 mm in order to evaluate optimized UCG for energy harvesting device applications. When the length of PZCN film was increased, the resonance frequency of UCG was slightly increased from 7 Hz to 8 Hz, which could be due to enlarged area of the highly stiff piezo-ceramic film. However, the output power was proportionally increased with the length of PZCT film and it reached 4.68 mW (1.221 mW/cm3) when the film`s length was 57.7 mm under 25 g of tip mass at 8 Hz, which is sufficient for micro-scale device applications.
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