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"Cure kinetics"

Optimization of Curing Pressure for Automatic Pressure Gelation Molding Process of Ultra High Voltage Insulating Spacers
Chanyong Lee, Hangoo Cho, Jaehyeong Lee
J Electr Electron Mater 2024;37(1):56-62.   Published online January 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.1.7
By introducing curing kinetics and chemo-rheology for the epoxy resin formulation for ultra-high voltage gas insulated switchgear (GIS) Insulating Spacers, a study was conducted to simulate the curing behavior, flow and warpage analysis for optimization of the molding process in automatic pressure gelation. The curing rate equation and chemo-rheology equation were set as fixed values for various factors and other physical property values, and the APG molding process conditions were entered into the Moldflow software to perform optimization numerical simulations of the three-phase insulating spacer. Changes in curing shrinkage according to pack pressure were observed under the optimized process conditions. As a result, it was confirmed that the residence time in the solid state was shortened due to the lowest curing reaction when the curing holding pressure was 3 bar, and the occurrence of deformation due to internal residual stress was minimized.
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