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"Bandgap"

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"Bandgap"

Fabrication and Characterization of Sn-Doped β-Ga2O3 Thin Films
Jihyeong Kim, Kyunghwan Kim, Jeongsoo Hong
J Electr Electron Mater 2025;38(1):72-77.   Published online January 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.1.9
In this study, the effect of thickness on the Sn-doped β-Ga2O3 thin films was investigated. β-Ga2O3 is a next-generation material for power semiconductors and optoelectronics owing to its remarkable properties, such as an ultra-wide bandgap, excellent thermal and chemical stability, and large breakdown voltage. However, its inherently low conductivity can be limiting in applications that require high conductivity; therefore, improving the conductivity of β-Ga2O3 is important. In this study, Sn-doped β-Ga2O3 thin films with various thicknesses were deposited on β-Ga2O3 substrates. All the fabricated samples exhibited β-phase with a uniform and dense surface and transmittance of above 80% in the visible region. In particular, the 100 nm samples showed the highest carrier concentration and mobility and the lowest resistivity. Thus, these findings are expected to play an important role in improving the performance of devices by controlling the thickness of thin films.
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A Study on Improved Open-Circuit Voltage Characteristics Through Bi-Layer Structure in Heterojunction Solar Cells
Hongrae Kim, Sungjin Jeong, Jaewoong Cho, Sungheon Kim, Seungyong Han, Suresh Kumar Dhungel, Junsin Yi
J Electr Electron Mater 2022;35(6):603-609.   Published online November 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.6.9
Passivation quality is mainly governed by epitaxial growth of crystalline silicon wafer surface. Void-rich intrinsic a- Si:H interfacial layer could offer higher resistivity of the c-Si surface and hence a better device efficiency as well. To reduce the resistivity of the contact area, a modification of void-rich intrinsic layer of a-Si:H towards more ordered state with a higher density is adopted by adapting its thickness and reducing its series resistance significantly, but it slightly decreases passivation quality. Higher resistance is not dominated by asymmetric effects like different band offsets for electrons or holes. In this study, multilayer of intrinsic a-Si:H layers were used. The first one with a void-rich was a-Si:H(I1) and the next one a-SiOx:H(I2) were used, where a-SiOx:H(I2) had relatively larger band gap of ~2.07 eV than that of a-Si:H (I1). Using a-SiOx:H as I2 layer was expected to increase transparency, which could lead to an easy carrier transport. Also, higher implied voltage than the conventional structure was expected. This means that the a-SiOx:H could be a promising material for a high-quality passivation of c-Si. In addition, the i-a-SiOx:H microstructure can help the carrier transportation through tunneling and thermal emission.
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Bandgap Control of (AlxGa1-x)2O3 Epilayers by Controlling Aqueous Precursor Mixing Ratio in Mist Chemical Vapor Deposition System
Kyoung-ho Kim, Yun-ji Shin, Seong-min Jeong, Si-young Bae
J Electr Electron Mater 2019;32(6):528-533.   Published online November 1, 2019
We investigated the growth of AlxGa1-x)2O3 thin films on c-plane sapphire substrates that were grown by mist chemical vapor deposition (mist CVD). The precursor solution was prepared by mixing and dissolving source materials such as gallium acetylacetonate and aluminum acetylacetonate in deionized water. The [Al]/[Ga] mixing ratio (MR) of the precursor solution was adjusted in the range of 0~4.0. The Al contents of (AlxGa1-x)2O3 thin films were increased from 8 to 13% with the increase of the MR of Al. As a result, the optical bandgap of the grown thin films changed from 5.18 to 5.38 eV. Therefore, it was determined that the optical bandgap of grown (AlxGa1-x)2O3 thin films could be effectively engineered by controlling Al content.
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The Formation of Microcrystalline SiGe Film Using a Remote Plasma Enhanced Chemical Vapor Deposition
Doyoung Kim
J Electr Electron Mater 2018;31(5):320-323.   Published online July 1, 2018
SiGe thin films were deposited by remote plasma enhanced chemical vapor deposition (RPE-CVD) at 400℃ using SiH4 or SiCl4 and GeCl4 as the source of Si and Ge, respectively. The growth rate and the degree of crystallinity of the fabricated films were characterized by scanning electron microscopy and Raman analysis, respectively. The optical and electrical properties of SiGe films fabricated using SiCl4 and SiH4 source were comparatively studied. SiGe films deposited using SiCl4 source showed a lower growth rate and higher crystallinity than those deposited using SiH4 source. Ultraviolet and visible spectroscopy measurement showed that the optical band gap of SiGe is in the range of 0.88~1.22 eV.
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Effect of O2/Ar Gas Ratios on the Characteristics of Amorphous Tellurium Oxide Thin Films
Heon Kong, Gun-hong Jung, Jong-bin Yeo, Hyun-yong Lee
J Electr Electron Mater 2017;30(5):294-300.   Published online May 1, 2017
TeOx thin films were deposited at various O2/Ar gas-flow ratios by a reactive RFmagneton sputtering technique from TeO2 and Te targets. X-ray diffraction (XRD) results revealed that the TeOx thin films were amorphous. The structure and chemical composition of the TeOx thin films were investigated by fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). The optical characteristics of the TeOx thin films were investigated by an Ellipsometer and a UV-VIS-NIR spectrophotometer. According to the O2/Ar gas-flow ratios, the atomic composition ratio of TeOx thin films was divided into two regions(x=1-2, 2-3). Different optical characteristics were shown in each region. With an increasing O2/Ar gas-flow ratio, the refractive index of the TeOx thin films decreased and the optical bandgap of the films increased.
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Enhancing Solar Cell Properties of Heterojunction Solar Cell in Amorphous Silicon Carbide
Hyun Sung Kim, Sang Ho Kim, Young Seok Lee, Yong Jun Kim, Vinh Ai Dao, Jun Sin Yi
J Electr Electron Mater 2016;29(6):376-379.   Published online June 1, 2016
In this paper, the efficiency improvement of the heterojunction with intrinsic thin layer (HIT) solar cells is obtained by optimization process of p-type a-SiC:H as emitter. The optoelectronic of p-type a-SiC:H layers including the optical band-gap and conductivity under the methane gas content variation is conducted in detail. A significant increase in the Jsc by 1 mA/cm2 and Voc by 30 mV are attributed to enhanced photon-absorption due to broader band-gap of p-a-SiC:H and reduced band-offsets at p-side interface, respectively of HIT solar cells.
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Regular Paper : The Structural and Optical Characteristics of Mg0.3Zn0.7O Thin Films Deposited on PES Substrate According to Oxygen Pressure
Hyun Min Lee, Sang Hyun Kim, Na Kwon Jang, Hong Seung Kim
J Electr Electron Mater 2014;27(11):760-765.   Published online November 1, 2014
MgZnO has attracted a lot of attention for flexible device. In the flexible substrate, the crystalstructure of the thin films as well as the surface morphology is not good. Therefore, in this study, westudied on the effects of the oxygen pressure on the structure and crystallinity of Mg0.3Zn0.7O thin films deposited on PES substrate by using pulsed laser deposition. We used X-ray diffraction and atomic forcemicroscopy in order to observe the structural characteristics of Mg0.3Zn0.7O thin films. The crystallinity ofMg0.3Zn0.7O thin films with increasing temperature was improved, Grain size and RMS of the films wereincreased. UV-visible spectrophotometer was used to get the band gap energy and transmittance. Mg0.3Zn0.7O thin films showed high transmittance over 90% in the visible region. As increased workingpressure from 30 mTorr to 200 mTorr, the bandgap energy of Mg0.3Zn0.7O thin film were decreased from3.59 eV to 3.50 eV.
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Effects of Substrate Temperature on Properties of (Ga,Ge)-Codoped ZnO Thin Films Prepared by RF Magnetron Sputtering
Il Hyun Jung
J Electr Electron Mater 2011;24(7):584-588.   Published online July 1, 2011
The ZnO thin films doped with Ga and Ge (GZO:Ge) were prepared on glass substrate using RF sputtering system. Structural, morphological and optical properties of the films deposited in different temperatures were studied. Proportion of the element of using target was 97 wt% ZnO, 2.5 wt% Ga and 0.5 wt% Ge with 99.99% highly purity. Structural properties of the samples deposited in different temperatures with 200 w RF power were investigated by field emission scanning electron microscopy, FE-SEM images and x-ray diffraction XRD analysis. Atomic force microscopy, AFM images were able to show the grain scales and surface roughness of each film rather clearly than SEM images. it was showed that increasing temperature have better surface smoothness by FE-SEM and AFM images. Transmittance study using UV-Vis spectrometer showed that all the samples have highly transparent in visible region (300∼800 nm). In addition, it can be able to calculate bandgap energy from absorbance data obtained with transmittance. The hall resistivity, mobility, and optical band gap energy are influenced by the temperature.
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Regular Paper : A Study on the Electrical Characteristics with Design Parameters in GaN Power Static Induction Transistor
Ju Hyun Oh, Sung Min Yang, Eun Sik Jung, Man Young Sung
J Electr Electron Mater 2010;23(9):671-675.   Published online September 1, 2010
Gallium nitride (GaN), wide bandgap semiconductor, has attracted much attention because they are projected to have much better performance than silicon. In this paper, effects of design parameters change of GaN power static induction transistor (SIT) on the electrical characteristics (breakdown voltage, on resistance) were analyzed by computer simulation. According to the analyzed results, the optimization was performed to get power GaN SIT that has 600 V class breakdown voltage. As a result, we could get optimized 600 V class power GaN SIT that has higher breakdown voltage and lower On resistance with a thin (a several micro-meters) thickness of the channel layer.
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Effects of Deposition Temperature on the Properties of InN Thin Films Grown by Radio-frequency Reactive Magnetron Sputtering
Shin Ho Cho
J Electr Electron Mater 2009;22(10):808-813.   Published online October 1, 2009
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Characteristics of the Photonic Bandgaps in Two-dimensional Photonic Crystals with a Square Lattice by FDTD Simulation
Jong Bin Yeo, Hoe Young Yang, Hyun Yong Lee
J Electr Electron Mater 2009;22(1):61-66.   Published online January 1, 2009
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Properties of ZnO Thin Films Grown by Radio-frequency Magnetron Sputtering in terms of O2/Ar Mixture Flow Ratio
J Electr Electron Mater 2007;20(11):932-938.   Published online November 1, 2007
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