Mg/Al layered double hydroxide with two-dimensional (2D) nanostructures was synthesized by a hydrothermal technique. The morphology and aspect ratio of Mg₄Al₂(OH)₁₄3H₂O were controlled by the concentration and kinds of the hydrolysis agent, and temperature. The aspect ratio of Mg₄Al₂(OH)₁₄3H₂O layered double hydroxides with the 2D hexagonal crystal structure was tailored from about 12.6 to about 45.7. The intercalated CO₃^2- anions of the synthesized 2D Mg₄Al₂(OH)₁₄3H₂O layered double hydroxides were exchanged to NO₃^- anions. The bulk 2D Mg₄Al₂(OH)₁₄3H₂O layered double hydroxides with the increased space between two layers due to the anion exchange were exfoliated in a formamide solution. The aspect ratio of the exfoliated 2D Mg₄Al₂(OH)₁₄3H₂O layered double hydroxides increased to 570.3.

We investigated the variation of anion exchange membrane of hydrogen generator of alkaline electrolysis. We detected the variation of elements and change of anion exchange membrane using EDS and FE-SEM. We detected two different sites of membrane because of different structure of membrane. Sp2 shows that the distribution ratio of C, 0, Al is 98% very higher than Sp2 of 78%. Especially, the main elements of STS316 which is P. S. Fe, Ni were more detected at Sp2 than Sp,. We think that this result depends on the structure of membrane. This also affect the resistance, lifetime of membrane and decrease the efficiency of hydrogen production. We hope that this article is a foundation of developing of hydrogen production technology.