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Volume 29(8); August 2016

Study on Improving Surface Structure with Changing RF Power Conditions in RIE (reactive ion etching)
Seok Gi Park, Jeong In Lee, Min Gu Kang, Gi Hwan Kang, Hee Eun Song, Hyo Sik Chang
J Electr Electron Mater 2016;29(8):455-460.   Published online August 1, 2016
A textured front surface is required in high efficiency silicon solar cells to reduce reflectance and to improve light trapping. Wet etching with alkaline solution is usually applied for mono crystalline silicon solar cells. However, alkali texturing method is not appropriate for multi-crystalline silicon wafers due to grain boundary of random crystallographic orientation. Accordingly, acid texturing method is generally used for multi-crystalline silicon wafers to reduce the surface reflectance. To reduce reflectivity of multi-crystalline silicon wafers, double texturing method with combination of acid and reactive ion etching is an attractive technical solution. In this paper, we have studied to optimize RIE condition by different RF power condition (100, 150, 200, 250, 300 W).
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Analysis of Contact Properties by Varying the Firing Condition of AgAl Electrode for n-type Crystalline Silicon Solar Cell
Dong Hyun Oh, Sung Youn Chung, Min Han Jeon, Ji Woon Kang, Gyeong Bae Shim, Cheol Min Park, Hyun Hoo Kim, Jun Sin Yi
J Electr Electron Mater 2016;29(8):461-465.   Published online August 1, 2016
n-type silicon shows the better tolerance towards metal impurities with a higher minority carrier lifetime compared to p-type silicon substrate. Due to better lifetime stability as compared to p-type during illumination made the photovoltaic community to switch toward n-type wafers for high efficiency silicon solar cells. We fabricated the front electrode of the n-type solar cell with AgAl paste. The electrodes characteristics of the AgAl paste depend on the contact junction depth that is closely related to the firing temperature. Metal contact depth with p+ emitter, with optimized depth is important as it influence the resistance. In this study, we optimize the firing condition for the effective formation of the metal depth by varying the firing condition. The firing was carried out at temperatures below 670℃ with low contact depth and high contact resistance. It was noted that the contact resistance was reduced with the increase of firing temperature. The contact resistance of 5.99 mΩ㎠ was shown for the optimum firing temperature of 865℃. Over 900℃, contact junction is bonded to the Si through the emitter, resulting the contact resistance to shunt. we obtained photovoltaic parameter such as fill factor of 76.68%, short-circuit current of 40.2 mA/cm2, open-circuit voltage of 620 mV and convert efficiency of 19.11%.
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Dielectric and Piezoelectric Properties of Pb(Zn,Ni,Nb)O3-Pb(Zr,Ti)O3 Ceramics for AE Sensor
Jong Dae Han, Ju Hyun Yoo, Hoy Seung Jeong, Dong Hir Seo
J Electr Electron Mater 2016;29(8):466-469.   Published online August 1, 2016
In this study, in order to develop composition ceramics for Acoustic Emission (abbreviated as AE) sensor application, the PZT system ceramics was fabricated by conventional solid state reaction method. When x=0.48, the density, electromechanical coupling factor(kp), piezoelectric coefficient d33 and piezoelectric voltage constant g33 of the maximum values of 7.857 g/cm3, 0.51, 190[pC/N], 52[10-3mV/N] were obtained, respectively, suitable for AE sensor.
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Structural and Electrical Properties of Zn-Mn-O System Ceramics for the Application of Temperature Sensors
Kyeong Min Kim, Sung Gap Lee, Dong Jin Lee, Mi Ri Park, Min Soo Kwon
J Electr Electron Mater 2016;29(8):470-475.   Published online August 1, 2016
In this study, ZnxMn3-xO4 (x=0.95~1.20) specimens were prepared by using a conventional mixed oxide method. All specimens were sintered in air at 1,200℃ for 12 h and cooled at a rate of 2℃/min to 800℃, subsequently quenching to room temperature. We investigated the structural and electrical properties of ZnxMn3-xO4 specimens with variation of ZnO amount for the application of NTC thermistors. As results of X-ray diffraction patterns, all specimens showed the formation of a complete solid solution with tetragonal spinel phase. And, the second phase was observed by the solubility limit of Zn ions in x≥1.10 composition. The average grain size was increased from 2.72 μm to 4.18 μm with increasing the compositional ratio of Zn ion from x=0.95 to 1.20, respectively. Zn1.10 Mn1.90 O4 specimen showed the minimum electrical resistance of 57.5 kΩ at room temperature and activation energy of 0.392 eV.
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Characteristics of PMN-PZ-PT Thick Film Ceramic by Low-Temperature Sintering Aids
Myungwon Jung, Dae Woo Jeon, Jin Ho Kim, Youngjin Lee
J Electr Electron Mater 2016;29(8):476-482.   Published online August 1, 2016
Convectional PZT based piezoelectric ceramics have to sinter at high temperature about 1,200℃ for their suitable electrical properties. However, some issues: low temperature sintering piezoelectric ceramic composition and reliable internal electrode, have recently attracted a great deal of interest as a highly efficient multi-layered piezoelectric ceramics. In order to optimize low temperature sintering conditions of thick-film PMN-PZ-PT ceramic, it was investigated sintering and piezoelectric properties according to the change of LiBiO2contents. Thus, the superior piezoelectric properties were found at the pallet type PMN-PZ-PT optimized with low sintering processing at 925℃ including 7 wt% LiBiO2sintering aid. Consequentially, we successfully manufactured thick-film PMN-PZ-PT ceramics, which had superior piezoelectric and dielectric properties, with 5 wt% of LiBiO2sintering aid at temperature of 900℃.
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Modified Piezoelectric Ceramics for Portable Ultrasonic Medical Probe Application
Dong Heon Kang, Mi Na Chae, Se Won Hong
J Electr Electron Mater 2016;29(8):483-488.   Published online August 1, 2016
Ultrasound imaging by using piezoelectric materials, such as lead zirconium titanate (PZT) has been oneof the most preferred modes of imaging in the medical field due to its simple, low cost and non-ionizing radiation in comparison to other imaging techniques. Recently, the market demand for portable ultrasound is becoming larger with applications in developing countries, disaster area, military, and emergency purposes. However, most of ultrasound probes used is bulky and high power consumable, so unsuitable for such applications. In this study, the 3 layered ceramic specimen consisted of 128 pitches of 420 μm in width and 450 μm in thickness were prepared by using the Ti-rich PZT compositions co-fired at 1,050℃. Their electrical and ultrasound pulse-echo properties were investigated and compared to the single layer specimen. The 3 layered ultrasound probe showed 1.584 V of Vp-p, which is 3.2 times higher than single layered one, implying that it would allow effectively such a portable ultrasound probe system. The result were discussed in terms of higher capacitance, lower impedance and higher dielectric coefficient of the 3 layered ultrasound probe.
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Effect of V2O5 Content and Pre-Sintering Atmosphere on Adhesive Property of Glass Frit for Laser Sealing of OLED
Hyeonjin Jeong, Mijai Lee, Youngjin Lee, Jin Ho Kim, Dae Woo Jeon, Jonghee Hwang, Jungsoo Lee, Yunsung Yang, Sookyung Youk, Tae Ho Park, Yun Gon Moon
J Electr Electron Mater 2016;29(8):489-493.   Published online August 1, 2016
In this study, the effect of vanadium oxide (V2O5) content and pre-sintering atmosphere on sealing property of glass frit that consisted of V2O5-BaO-ZnO-P2O5-TeO2-CuO-Fe2O3 SeO2 was investigated by XPS (X-ray photoelectron spectroscopy). The content of V2O5 was changed to 15, 30, and 45 mol%, and the pre-sintering was carried out in air and N2 condition, respectively. XPS analysis conducted before and after laser irradiation with identical sample. Before laser treatment, glass frits that were pre-sintered at air condition showed both V4+and V5+, but the valence state was changed to V5+ after laser irradiation when the glass frits contained 30 and 45 mol% V2O5; this change led to non-adhesive property. On the other hand, glass frits that were pre-sintered at N2 condition exhibited only V4+ and it showed fine adhesion irrespective of the V2O5 content. As a result, the existence of V4+ seems to be a major factor for controlling the adhesive property of glass frit for laser sealing.
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Rigorous Analysis of Viewing Zone for 3D Display with Electric-field-driven Liquid Crystal Lens
Tae Hyeon Kim, Bong Sik Kim, Woo Sang Park
J Electr Electron Mater 2016;29(8):494-498.   Published online August 1, 2016
In this paper, we proposed the 3-dimenstional (3D) analysis for calculating the optical characteristics of an autostereoscopic display with electric field driven liquid crystal (ELC) lens. From 3D analysis considering the slanting of lens, we calculate the cross-talk of each images and the distortion of viewing zone. Using geometric opics and extended Jones matrix method (EJMM), phase retardation of ELC lens according to position is calculated and then optical path difference in 3D space considering tilt and azimuth angle of incident light is gotten. Then, intensity distribution is presented in the space. Through camparing the intensity distribution using ideal lens with the ELC lens, we identify the noise and image distortion of ELC lens. As a result, this analysis is expected to provide optimum design conditions for realistic and rigorous 3D display with ELC lens.
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Study on Transient Current Limiting Operational Characteristics of Transformer Type SFCL with Two Peak Current Limiting Function
Tae Hee Han, Sung Hun Lim
J Electr Electron Mater 2016;29(8):499-504.   Published online August 1, 2016
In this paper, we analyzed the operational characteristics of the fault current limiting according to the amplitude of the fault current for the transformer type superconducting fault current limiter (SFCL). If the fault current happens, the superconducting element connected to the secondary coil is occurred quench and the fault current is limited. When the larger fault current occurs, the superconducting element connected to the third coil is occurred additional quench and the peak fault current is limited. We found that the fault current can be more effectively controlled through the analysis of the fault current limiting and the short-circuit tests.
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The Effect of Barrier Layer on Thin-film Silicon Solar Cell Using Graphite Substrates
Young Joon Cho, Lee Dong Won, Jun Sik Cho, Hyo Sik Chang
J Electr Electron Mater 2016;29(8):505-509.   Published online August 1, 2016
We have investigated the characteristics of amorphous silicon (a-Si) thin-film solar cell by inserting barrier layer. The conversion efficiency of a-Si thin-film solar cells on graphite substrate shows nearly zero because of the surface roughness of the graphite substrate. To enhance the performance of solar cells, the surface morphology of the back side were modified by changing the barrier layer on graphite. The surface roughness of graphite substrate with the barrier layer grown by plasma enhanced chemical vapor deposition (PECVD) reduced from ~2 um to ~75 nm. In this study, the combination of the barrier layer on graphite substrate is important to increase solar cell efficiency. We achieved ~ 7.8% cell efficiency for an a-Si thin-film solar cell on graphite substrate with SiNx/SiOx stack barrier layer.
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The Electrochemical Property of the Single-Chamber Solid Oxide Fuel Cell Based on a Zirconia Electrolyte
Hee Jung Park, Jong Hoon Joo, Jae Kyo Yang, Yun Ho Jin, Kyu Hyoung Lee
J Electr Electron Mater 2016;29(8):510-515.   Published online August 1, 2016
Single-chamber solid oxide fuel cells (SC-SOFCs) consist of only one gas chamber, in which both the anode and the cathode are exposed to the same fuel-oxidant mixture. Thus, this configuration shows good thermal and mechanical resistance and allows rapid start-up and -down. In this study, the unit cell consisting of La0.8Sr0.2MnO3 (cathode) / Zr0.84Y0.16O2-x (electrolyte) / Ni-Zr0.84Y 0.16O2-x (anode) was fabricated and its electrochemical property was investigated as a function of temperature and the volume ratio of fuel and oxidant for SC-SOFCs. Impedance spectra were also investigated in order to figure out the electrical characteristics of the cell. As a result, the cell performance was governed by the polarization resistances of the electrodes. The cell exhibited an acceptable cell-performance of 86 mW/cm2 at 800℃ and stable performance for 3 hs under 0.7 V.
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Thermal Property of Mo-5~20 wt%. Cu Alloys Synthesized by Planetary Ball Milling and Spark Plasma Sintering Method
Han Chan Lee, Kyoung Il Moon, Paik Kyun Shin
J Electr Electron Mater 2016;29(8):516-521.   Published online August 1, 2016
Mo-Cu alloys have been widely used for heat sink materials, vacuum technology, automobile, and many other applications due to their excellent physical and electric properties. Especially, Mo-Cu composites with 5 ~ 20 wt.% copper are widely used for the heavy duty service contacts due to their excellent properties like low coefficient of thermal expansion, wear resistance, high temperature strength, and prominent electrical and thermal conductivity. In most of the applications, highly-dense Mo-Cu materials with homogeneous microstructure are required for better performance. In this study, Mo-Cu alloys were prepared by PBM (planetary ball milling) and SPS (spark plasma sintering). The effect of Cu with contents of 5~20 wt.% on the microstructure and thermal properties of Mo-Cu alloys was investigated.
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